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Two-time-scale relaxation towards thermal equilibrium of the enigmatic piston

C. Gruber·S. Pache·A. Lesne
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Abstract

We investigate the evolution of a system composed of $N$ non-interacting point particles of mass $m$ in a container divided into two chambers by a movable adiabatic piston of mass $M\gg m$. Using a two-time-scale perturbation approach in terms of the small parameter $α=2m/(M+m)$, we show that the evolution towards thermal equilibrium proceeds in two stages. The first stage is a fast, deterministic, adiabatic relaxation towards mechanical equilibrium. The second stage, which takes place at times ${\cal O}(M)$, is a slow fluctuation-driven, diathermic relaxation towards thermal equilibrium. A very simple equation is derived which shows that in the second stage, the position of the piston is given by $X_M(t)=L[1/2-ξ(αt)]$ where the function $ξ$ is independent of $M$. Numerical simulations support the assumptions underlying our analytical derivations and illustrate the large mass range in which the picture holds.

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C. Gruber, S. Pache, A. Lesne. 2003-12-13. Two-time-scale relaxation towards thermal equilibrium of the enigmatic piston. https://doi.org/10.1023/a%3A1024671710343

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