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Oxygen stoichiometry, crystal structure, and magnetism in La$_{0.5}$Sr$_{0.5}$CoO$_{3-δ}$

Ryan P. Haggerty·Ram Seshadri
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Abstract

We have prepared a series of polycrystalline samples La$_{0.5}$Sr$_{0.5}$CoO$_{3-δ}$} with $0 < δ\le 0.21$ and characterized their oxygen content, crystal structure, and magnetic properties. While the fully oxygenated samples are good ferromagnets, samples with larger $δ$ values display increasingly broad magnetic transitions. The saturation magnetization at 5 K falls rapidly as $δ$ increases. First principles electronic structure calculations provide insights into the magnetic behavior of the fully oxygenated compound, and the manner in which ferromagnetic ordering is affected by increasing oxygen non-stoichiometry.

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Ryan P. Haggerty, Ram Seshadri. 2004-08-03. Oxygen stoichiometry, crystal structure, and magnetism in La$_{0.5}$Sr$_{0.5}$CoO$_{3-δ}$. https://doi.org/10.1088/0953-8984%2F16%2F36%2F013

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