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The role of the dopant in the superconductivity of diamond

Xavier Blase·Ch Adessi·Damien Connetable
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Abstract

We present an {\it ab initio} study of the recently discovered superconductivity of boron doped diamond within the framework of a phonon-mediated pairing mechanism. The role of the dopant, in substitutional position, is unconventional in that half of the coupling parameter $λ$ originates in strongly localized defect-related vibrational modes, yielding a very peaked Eliashberg $α^2F(ω)$ function. The electron-phonon coupling potential is found to be extremely large and T$_C$ is limited by the low value of the density of states at the Fermi level.

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Xavier Blase, Ch Adessi, Damien Connetable. 2004-07-22. The role of the dopant in the superconductivity of diamond. https://doi.org/10.1103/physrevlett.93.237004

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