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The role of doping and dimensionality in the superconductivity of NaxCoO2

M. Banobre-Lopez·F. Rivadulla·R. Caudillo·M. A. Lopez-Quintela·J. Rivas·J. B. Goodenough
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Abstract

We report a complete analysis of the formal oxidation state of Co in NaxCoO2, in the interval 0.31<x<0.67. Iodometric titration and thermoelectric power confirm that a direct relationship between the Na content and the amount of Co 3 + cannot be established in this system. Creation of a significant amount of oxygen vacancies accompanies Na-ion deintercalation, keeping the formal Co valence at 3.45 + for x<0.45. To the light of new thermoelectric power data which reveals important differences between the hydrated (superconducting) and non-hydrated (non-superconducting) samples, we propose here that water plays an important chemical role beyond that of a spacer between the CoO2 layers.

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M. Banobre-Lopez, F. Rivadulla, R. Caudillo, M. A. Lopez-Quintela, J. Rivas, J. B. Goodenough. 2004-09-23. The role of doping and dimensionality in the superconductivity of NaxCoO2. https://arxiv.org/abs/cond-mat/0409606

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