arXiv · cond-mat/0409777
Comment on Phys. Stat. Sol. (b) 236 (2003) 281 paper by A. M. Oles "Orbital ordering and orbital fluctuations in transition metal oxides"
Abstract
We argue that the 3A2 state considered by Oles in Phys. Stat. Sol. (b) 236 (2003) 281 for the d2 system occurring in the V3+ ion in V2O3 and LaVO3 as well as in Ti2+ ion in TiO and in many other oxides is wrong. The proper ground state is 3T1g - its 9-fold degeneracy is further split in a crystal by intra-atomic spin-orbit interactions and lattice distortions.
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R. J. Radwanski, Z. Ropka. 2004-09-30. Comment on Phys. Stat. Sol. (b) 236 (2003) 281 paper by A. M. Oles "Orbital ordering and orbital fluctuations in transition metal oxides". https://arxiv.org/abs/cond-mat/0409777
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