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Smearing of phase transition due to surface effect in ferroelectric nanostructures

A. M. Bratkovsky·A. P. Levanyuk
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Abstract

The boundary conditions, customarily used in the Landau-type approach to ferroelectric thin films and nanostructures, have to be modified to take into account that a surface of a ferroelectric (FE) is a defect of a ``field'' type. The surface (interface) field is coupled to a normal component of polarization and, as a result, the second order phase transitions are generally suppressed and anomalies in response are washed out, as observed experimentally.

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A. M. Bratkovsky, A. P. Levanyuk. 2004-12-21. Smearing of phase transition due to surface effect in ferroelectric nanostructures. https://arxiv.org/abs/cond-mat/0410263

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