Molecular Traffic Control in a 3D network of single file channels and fast reactivity

Andreas Brzank; Sungchul Kwon; Gunter Schuetz

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Molecular Traffic Control in a 3D network of single file channels and fast reactivity

Andreas Brzank·Sungchul Kwon·Gunter Schuetz

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Abstract

We study the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC) as a function of grain size. We extend a recently introduced two dimensional model system to three dimensions. With dynamic Monte-Carlo simulations and analytical solution of the associated Master equation we obtain a quantitative description of the MTC effect in the limit of fast reactivity. The efficiency ratio (compared with a topologically and structurally similar reference system without MTC) is inversely proportional to the grain diameter.

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Andreas Brzank, Sungchul Kwon, Gunter Schuetz. 2005-06-28. Molecular Traffic Control in a 3D network of single file channels and fast reactivity. https://arxiv.org/abs/cond-mat/0506197

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