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Density functional approach for inhomogeneous star polymers

A. Malijevsky·P. Bryk·S. Sokolowski
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Abstract

We propose microscopic density functional theory for inhomogeneous star polymers. Our approach is based on fundamental measure theory for hard spheres, and on Wertheim's first- and second-order perturbation theory for the interparticle connectivity. For simplicity we consider a model in which all the arms are of the same length, but our approach can be easily extended to the case of stars with arms of arbitrary lengths.

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A. Malijevsky, P. Bryk, S. Sokolowski. 2005-07-15. Density functional approach for inhomogeneous star polymers. https://doi.org/10.1103/physreve.72.032801

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