Ion-induced nucleation in polar one-component fluids

Hikaru Kitamura; Akira Onuki

doi:10.1063/1.2039078

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Ion-induced nucleation in polar one-component fluids

Hikaru Kitamura·Akira Onuki

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Abstract

We present a Ginzburg-Landau theory of ion-induced nucleation in a gas phase of polar one-component fluids, where a liquid droplet grows with an ion at its center. By calculating the density profile around an ion, we show that the solvation free energy is larger in gas than in liquid at the same temperature on the coexistence curve. This difference much reduces the nucleation barrier in a metastable gas.

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Hikaru Kitamura, Akira Onuki. 2005-08-01. Ion-induced nucleation in polar one-component fluids. https://doi.org/10.1063/1.2039078

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