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DNA-decorated carbon nanotubes for chemical sensing

Cristian Staii·Michelle Chen·Alan Gelperin·Alan T. Johnson Jr
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Abstract

We demonstrate a new, versatile class of nanoscale chemical sensors based on single-stranded DNA (ss-DNA) as the chemical sensors recognition site and single-walled carbon nanotube field effect transistors (swCN-FET) as the electronic read-out component. swCN-FETs with a nanoscale coating of ss-DNA respond to gas odors that do not cause a detectable conductivity change in bare devices. Responses of ss-DNA/swCN-FETs differ in sign and magnitude for different gases, and can be tuned by choosing the base sequence of the ss-DNA. ss-DNA/swCN-FET sensors detect a variety of odors, with rapid response and recovery times on the scale of seconds. The sensor surface is self-regenerating: samples maintain a constant response with no need for sensor refreshing through at least 50 gas exposure cycles. This very remarkable set of attributes makes sensors based on ss-DNA decorated nanotubes very promising for "electronic nose" and "electronic tongue" applications ranging from homeland security to disease diagnosis.

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Cristian Staii, Michelle Chen, Alan Gelperin, Alan T. Johnson Jr. 2005-09-02. DNA-decorated carbon nanotubes for chemical sensing. https://doi.org/10.1021/nl051261f

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