The two colors of MgB2

Abstract

We present the anisotropic optical conductivity of MgB$_{2}$ between 0.1 and 3.7 eV at room temperature obtained on single crystals of different purity by the spectroscopic ellipsometry and reflectance measurements. The bare (unscreened) plasma frequency $ω_{p}$ is almost isotropic and equal to 6.3 eV, which contrasts some earlier reports of a very small value of $ω_{p}$. The data suggests that the $σ$-bands are characterized by a stronger electron-phonon coupling $λ_ {tr}$ but smaller impurity scattering $γ_{imp}$, compared to the $π$-bands. The optical response along the boron planes is marked by an intense interband transition at 2.6 eV, due to which the reflectivity plasma edges along the a- and c-axes are shifted with respect to each other. As a result, the sample spectacularly changes color from a blueish-silver to the yellow as the polarization is rotated from the in-plane direction towards the c-axis. The optical spectra are in good agreement with the published {\it ab initio} calculations. The remaining discrepancies can be explained by the relative shift of $σ$-bands and $π$-bands by about 0.2 eV compared to the theoretical band structure, in agreement with the de Haas-van Alphen experiments. The widths of the Drude and the interband peaks are both very sensitive to the sample purity.