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Raman spectroscopy on cubic and hexagonal SrMnO$_3$

A. Sacchetti·M. Baldini·P. Postorino·C. Martin·A. Maignan
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Abstract

We report on the first optical characterization of both cubic and hexagonal SrMnO$_3$. Room-temperature Raman spectra collected by means of a micro-Raman spectrometer are shown. The spectrum of the cubic compound is characterized by weak and broad bands in agreement with group-theory which predicts no Raman-active phonons for this compound. On the other hand, the spectrum of the hexagonal compound shows six narrow peaks ascribed to one-phonon processes. A complete polarization analysis of the spectra collected from a single crystallite allows us to completely assign the symmetries of the six observed peaks. Atomic displacements for each phonon peaks are also proposed.

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A. Sacchetti, M. Baldini, P. Postorino, C. Martin, A. Maignan. 2005-09-19. Raman spectroscopy on cubic and hexagonal SrMnO$_3$. https://doi.org/10.1002/jrs.1484

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