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Bright-Exciton Fine Structure and Anisotropic Exchange in CdSe Nanocrystal Quantum Dots

M. Furis·H. Htoon·M. A. Petruska·T. Barrick·V. I. Klimov·S. A. Crooker
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Abstract

We report on polarization-resolved resonant photoluminescence (PL) spectroscopy of bright (spin-1) and dark (spin-2) excitons in colloidal CdSe nanocrystal quantum dots. Using high magnetic fields to 33 T, we resonantly excite (and selectively analyze PL from) spin-up or spin-down excitons. At low temperatures (<4K) and above ~10 T, the spectra develop a narrow, circularly polarized peak due to spin-flipped bright excitons. Its evolution with magnetic field directly reveals a large (1-2 meV), intrinsic fine structure splitting of bright excitons, due to anisotropic exchange. These findings are supported by time-resolved PL studies and polarization-resolved PL from single nanocrystals.

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M. Furis, H. Htoon, M. A. Petruska, T. Barrick, V. I. Klimov, S. A. Crooker. 2006-05-25. Bright-Exciton Fine Structure and Anisotropic Exchange in CdSe Nanocrystal Quantum Dots. https://doi.org/10.1103/physrevb.73.241313

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