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arXiv · cond-mat/0606044

Model for the free-volume distributions of equilibrium fluids

William P. Krekelberg·Venkat Ganesan·Thomas M. Truskett
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Abstract

We introduce and test via molecular simulation a simple model for predicting the manner in which interparticle interactions and thermodynamic conditions impact the single-particle free-volume distributions of equilibrium fluids. The model suggests a scaling relationship for the density-dependent behavior of the hard-sphere system. It also predicts how the second virial coefficients of fluids with short-range attractions affect their free-volume distributions.

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William P. Krekelberg, Venkat Ganesan, Thomas M. Truskett. 2006-06-01. Model for the free-volume distributions of equilibrium fluids. https://doi.org/10.1063/1.2202354

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