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Ferroelectricity of Ice Nanotubes inside Carbon Nanotubes

Chuanfu Luo·Wei Fa·Jinming Dong
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Abstract

We report that ice nanotubes with odd number of side faces inside carbon nanotubes exhibit spontaneous electric polarization along its axes direction by using molecular dynamics simulations. The mechanism of this nanoscale quasi-one-dimensional ferroelectricity is due to low dimensional confinement and the orientational order of hydrogen bonds. These ferroelectric fiber structural materials are different from traditional perovskite structural bulk materials.

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Chuanfu Luo, Wei Fa, Jinming Dong. 2007-03-27. Ferroelectricity of Ice Nanotubes inside Carbon Nanotubes. https://doi.org/10.1021/nl072642r

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