arXiv · cond-mat/9306009
Vibrations and Berry Phases of Charged Buckminsterfullerene
Abstract
A simple model of electron-vibron interactions in buckminsterfullerene ions is solved semiclassically. Electronic degeneracies of C$_{60}$$^{n-}$ induce dynamical Jahn-Teller distortions, which are unimodal for $n\!\ne\!3$ and bimodal for $n\!=\!3$. The quantization of motion along the Jahn-Teller manifold leads to a symmetric-top rotator Hamiltonian. I find Molecular Aharonov-Bohm effects where electronic Berry phases determine the vibrational spectra, zero point fluctuations, and electrons' pair binding energies. The latter are relevant to superconductivity in alkali-fullerenes.
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Assa Auerbach. 1993-06-03. Vibrations and Berry Phases of Charged Buckminsterfullerene. https://doi.org/10.1103/physrevlett.72.2931
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