Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · cond-mat/9503125

Doping Effects and Electronic States in C60-Polymers

Kikuo Harigaya
View original source ↗Read source document ↗Export metadata ↓

Abstract

Band structures of C60-polymers are studied changing conjugation conditions and the electron number. We use a Su-Schrieffer-Heeger type semiempirical model. In the neutral C60-polymer, electronic structures change among direct-gap insulator and the metal, depending on the degree of conjugations. The C60-polymer doped with one electron per one molecule is always a metal. The energy difference between the highest-occupied state and the lowest-unoccupied state of the neutral system becomes smaller upon doping owing to the polaron effects. The C60-polymer doped with two electrons per one C60 changes from an indirect-gap insulator to the direct-gap insulator, as the conjugations become stronger.

Explore related subjects

cond-matchem-phmtrl-thsupr-con

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Kikuo Harigaya. 1996-03-25. Doping Effects and Electronic States in C60-Polymers. https://doi.org/10.1016/0009-2614(96)00292-8

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2017

Random-Matrix Theory of Quantum Size Effects on Nuclear Magnetic Resonance in Metal Particles

The distribution function of the local density of states is computed exactly for the Wigner-Dyson ensemble of random Hamiltonians. In the absence of time-reversal symmetry, precise agreement is obtained with the "supersymmetry" theory by Efetov and Prigodin of the NMR lineshape in disordered metal particles. Upon breaking time-reversal symmetry, the variance of the Knight shift in the smallest particles is reduced by a universal factor of 2/3. ***To be published in Physical Review B.****

cond-mat↗
arXiv2017

Andreev Reflection In Ferromagnet-Superconductor Junctions

The transport properties of a ferromagnet-superconductor (FS) junction are studied in a scattering formulation. Andreev reflection at the FS interface is strongly affected by the exchange interaction in the ferromagnet. The conductance G_FS of a ballistic point contact between F and S can be both larger or smaller than the value G_FN with the superconductor in the normal state, depending on the ratio of the exchange and Fermi energies. If the ferromagnet contains a tunnel barrier (I), the conductance G_FIFS exhibits resonances which do not vanish in linear response -- in contrast to the Tomasch oscillations for non-ferromagnetic materials.

cond-mat↗
arXiv2017

Long-Range Energy-Level Interaction in Small Metallic Particles

We consider the energy level statistics of non-interacting electrons which diffuse in a $ d $-dimensional disordered metallic conductor of characteristic Thouless energy $ E_c. $ We assume that the level distribution can be written as the Gibbs distribution of a classical one-dimensional gas of fictitious particles with a pairwise additive interaction potential $ f(\varepsilon ). $ We show that the interaction which is consistent with the known correlation function of pairs of energy levels is a logarithmic repulsion for level separations $ \varepsilon E_c, $ $ f(\varepsilon ) $ vanishes as a power law in $ \varepsilon /E_c $ with exponents $ -{1 \over 2},-2, $ and $ -{3 \over 2} $ for $ d=1,2, $ and 3, respectively. While for $ d=1,2 $ the energy-level interaction is always repulsive, in three dimensions there is long-range level attraction after the short-range logarithmic repulsion.

cond-mat↗