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Apparent Rate Constant for Diffusion-Controlled Three molecular (catalytic) reaction

S. F. Burlatsky·M. Moreau
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Abstract

We present simple explicit estimates for the apparent reaction rate constant for three molecular reactions, which are important in catalysis. For small concentrations and $d> 1$, the apparent reaction rate constant depends only on the diffusion coefficients and sizes of the particles. For small concentrations and $d\le 1$, it is also time -- dependent. For large concentrations, it gains the dependence on concentrations.

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S. F. Burlatsky, M. Moreau. 1996-08-26. Apparent Rate Constant for Diffusion-Controlled Three molecular (catalytic) reaction. https://doi.org/10.1103/physreve.51.2363

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