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arXiv · cond-mat/9702139

Liquid-state theory of charged colloids

Yan Levin·Marcia C. Barbosa·M. N. Tamashiro
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Abstract

A simple theory of the fluid state of a charged colloidal suspension is proposed. The full free energy of a polyelectrolyte solution is calculated. It is found that the counterions condense onto the polyions forming clusters composed of one polyion and n counterions. The distribution of cluster sizes is determined explicitly. In agreement with the current experimental and Monte Carlo results, no liquid-gas phase separation was encountered.

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Yan Levin, Marcia C. Barbosa, M. N. Tamashiro. 1998-02-12. Liquid-state theory of charged colloids. https://doi.org/10.1209/epl%2Fi1998-00119-4

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