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The physical determinants of the thickness of lamellar polymer crystals

Jonathan Doye·Daan Frenkel
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Abstract

Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum thermodynamically stable thickness. This description contrasts with those given by the two dominant theoretical approaches.

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Jonathan Doye, Daan Frenkel. 1998-03-13. The physical determinants of the thickness of lamellar polymer crystals. https://doi.org/10.1103/physrevlett.81.2160

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