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The slope equations: a universal relationship between local structure and glass transition temperature

Matthieu Micoulaut
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Abstract

In this article, we present a universal relationship between the glass transition temperature $T_g$ and the local glass structure. The derivation of the simplest expression of this relationship and some comparisons with experimental $T_g$ values have already been reported in a recent letter. We give here the analytical expression of the parameter $β$ of the Gibbs-Di Marzio equation and also new experimental probes for the validity of the relationship, especially in low modified binary glasses.

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Matthieu Micoulaut. 1998-05-12. The slope equations: a universal relationship between local structure and glass transition temperature. https://doi.org/10.1007/s100510050184

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