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Valence-bond states in dynamical Jahn-Teller molecular systems

Giuseppe Santoro·Leonardo Guidoni·Alberto Parola·Erio Tosatti
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Abstract

We discuss a hopping model of electrons between idealized molecular sites with local orbital degeneracy and dynamical Jahn-Teller effect, for crystal field environments of sufficiently high symmetry. For the Mott-insulating case (one electron per site and large Coulomb repulsions), in the simplest two-fold degenerate situation, we are led to consider a particular exchange hamiltonian, describing two isotropic spin-1/2 Heisenberg problems coupled by a quartic term on equivalent bonds. This twin-exchange hamiltonian applies to a physical regime in which the inter-orbital singlet is the lowest-energy intermediate state available for hopping. This regime is favored by a relatively strong electron-phonon coupling. Using variational arguments, a large-N limit, and exact diagonalization data, we find that the ground state, in the one dimensional case, is a solid valence bond state. The situation in the two dimensional case is less clear. Finally, the behavior of the system upon hole doping is studied in one dimension.

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Giuseppe Santoro, Leonardo Guidoni, Alberto Parola, Erio Tosatti. 1998-09-01. Valence-bond states in dynamical Jahn-Teller molecular systems. https://doi.org/10.1103/physrevb.55.16168

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