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Dynamics of polymeric manifolds in melts: Hartree approximation

V. G. Rostiashvili·M. Rehkopf·T. A. Vilgis
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Abstract

The Martin-Siggia-Rose functional technique and the self-consistent Hartree approximation is applied to the dynamics of a D-dimensional manifold in a melt of similar manifolds.The generalized Rouse equation is derived and its static and dynamic properties are studied. The static upper critical dimension discriminate between Gaussian and non-Gaussian regimes, whereas its dynamic counterpart discriminates between Rouse- and renormalized-Rouse behavior. The dynamic exponents are calculated explicitly. The special case of linear chains shows agreement with MD- and MC-simulations.

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V. G. Rostiashvili, M. Rehkopf, T. A. Vilgis. 1998-09-25. Dynamics of polymeric manifolds in melts: Hartree approximation. https://doi.org/10.1007/s100510050576

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