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A first principle computation of the thermodynamics of glasses

Marc Mezard·Giorgio Parisi
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Abstract

We propose a first principle computation of the equilibrium thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of m atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.

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Marc Mezard, Giorgio Parisi. 1999-03-22. A first principle computation of the thermodynamics of glasses. https://doi.org/10.1063/1.479193

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