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Frenkel and charge transfer excitons in C60

M. Knupfer·J. Fink
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Abstract

We have studied the low energy electronic excitations of C60 using momentum dependent electron energy-loss spectroscopy in transmission. The momentum dependent intensity of the gap excitation allows the first direct experimental determination of the energy of the 1Hg excitation and thus also of the total width of the multiplet resulting from the gap transition. In addition, we could elucidate the nature of the following excitations - as either Frenkel or charge transfer excitons.

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M. Knupfer, J. Fink. 1999-07-19. Frenkel and charge transfer excitons in C60. https://doi.org/10.1103/physrevb.60.10731

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