Lennard-Jones binary mixture: a thermodynamical approach to glass transition

B. Coluzzi; G. Parisi; P. Verrocchio

doi:10.1063/1.480866

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arXiv · cond-mat/9904124

Lennard-Jones binary mixture: a thermodynamical approach to glass transition

B. Coluzzi·G. Parisi·P. Verrocchio

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Abstract

We study the liquid-glass transition of the Lennard-Jones binary mixture introduced by Kob and Andersen from a thermodynamic point of view. By means of the replica approach, translating the problem in the study of a molecular liquid, we study the phase transition due to the entropy crisis and we find that the Kauzmann's temperature $\tk$ is $\sim 0.32$. At the end we compare analytical predictions with numerical results.

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B. Coluzzi, G. Parisi, P. Verrocchio. 1999-11-13. Lennard-Jones binary mixture: a thermodynamical approach to glass transition. https://doi.org/10.1063/1.480866

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