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The thermodynamical liquid-glass transition in a Lennard-Jones binary mixture

Barbara Coluzzi·Giorgio Parisi·Paolo Verrocchio
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Abstract

We use the results derived in the framework of the replica approach to study the liquid-glass thermodynamic transition. The main results are rederived without using replicas and applied to the study of the Lennard-Jones binary mixture introduced by Kob and Andersen. We find that there is a phase transition due to the entropy crisis. We compute both analytically and numerically the value of the phase transition point $T_{K}$ and the specific heat in the low temperature phase.

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Barbara Coluzzi, Giorgio Parisi, Paolo Verrocchio. 1999-11-29. The thermodynamical liquid-glass transition in a Lennard-Jones binary mixture. https://doi.org/10.1103/physrevlett.84.306

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