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The inequivalence of thermodynamic ensembles

Parentani Renaud
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Abstract

The inequivalence of thermodynamical ensembles related by a Legendre transformation is manifest in self-gravitating systems and in black hole thermodynamics. Using the Poincare's method of the linear series, we describe the mathematical reasons which lead to this inequivalence which in turn induces a hierarchy of ensembles: the most stable ensemble describes the most isolated system. Moreover, we prove that one can obtain the degree of stability of all equilibrium configurations in any ensensemble related by Legendre transformations to the most stable if one knows the degree of stability in the most stable ensemble.

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Parentani Renaud. 1994-10-13. The inequivalence of thermodynamic ensembles. https://arxiv.org/abs/gr-qc/9410017

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