arXiv · nlin/0212046
The hydrogen atom in an electric field: Closed-orbit theory with bifurcating orbits
Abstract
Closed-orbit theory provides a general approach to the semiclassical description of photo-absorption spectra of arbitrary atoms in external fields, the simplest of which is the hydrogen atom in an electric field. Yet, despite its apparent simplicity, a semiclassical quantization of this system by means of closed-orbit theory has not been achieved so far. It is the aim of this paper to close that gap. We first present a detailed analytic study of the closed classical orbits and their bifurcations. We then derive a simple form of the uniform semiclassical approximation for the bifurcations that is suitable for an inclusion into a closed-orbit summation. By means of a generalized version of the semiclassical quantization by harmonic inversion, we succeed in calculating high-quality semiclassical spectra for the hydrogen atom in an electric field.
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T. Bartsch, J. Main, G. Wunner. 2002-12-20. The hydrogen atom in an electric field: Closed-orbit theory with bifurcating orbits. https://doi.org/10.1088/0953-4075%2F36%2F6%2F312
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