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Semiclassical transmission across transition states

Stephen C. Creagh
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Abstract

It is shown that the probability of quantum-mechanical transmission across a phase space bottleneck can be compactly approximated using an operator derived from a complex Poincaré return map. This result uniformly incorporates tunnelling effects with classically-allowed transmission and generalises a result previously derived for a classically small region of phase space.

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Stephen C. Creagh. 2005-06-01. Semiclassical transmission across transition states. https://doi.org/10.1088/0951-7715%2F18%2F5%2F011

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