Ortho-Para Conversion in CH3F. Self-Consistent Theoretical Model

Pavel L. Chapovsky

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Ortho-Para Conversion in CH3F. Self-Consistent Theoretical Model

Pavel L. Chapovsky

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Abstract

A complete theoretical model of the nuclear spin conversion in 13CH3F induced by intramolecular ortho-para state mixing is proposed. The model contains parameters determined from the level-crossing spectra of the 13CH3F spin conversion. This set of parameters includes the ortho-para decoherence rate, the magnitude of the hyperfine spin-spin interaction between the molecular nuclei and the energy gap between the mixed ortho and para states. These parameters are found to be in a good agreement with their theoretical estimates.

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Pavel L. Chapovsky. 2000-03-21. Ortho-Para Conversion in CH3F. Self-Consistent Theoretical Model. https://arxiv.org/abs/physics/0003046

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