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Hyperfine spectra of CH3F nuclear spin conversion

Pavel L. Chapovsky
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Abstract

A theoretical model of hyperfine spectra of nuclear spin conversion of molecular isomers has been developed. The model takes into account the nuclear spin-spin and spin-rotation interactions, as well as the saturation of intramolecular mixing of molecular ortho and para states. The model has been applied to hyperfine spectra of nuclear spin conversion in ^{13}CH3F molecules subjected to an external electric field. Conditions under which the hyperfine structure in the spectra can be resolved have been determined.

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Pavel L. Chapovsky. 2000-04-19. Hyperfine spectra of CH3F nuclear spin conversion. https://doi.org/10.1088/0953-4075/33/5/314

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