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Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential

J. C. Lopez V.·A. L. Rivera·Yu. F. Smirnov·A. Frank
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Abstract

The calculation of Franck-Condon factors between different one-dimensional Morse potential eigenstates using a formula derived from the Wigner function is discussed. Our numerical calculations using a very simple program written in Mathematica is compared with other calculations. We show that our results have a similar accuracy as the calculations performed with more sophisticated methods. We discuss the extension of our method to include non-Condon effects in the calculation.

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J. C. Lopez V., A. L. Rivera, Yu. F. Smirnov, A. Frank. 2001-09-06. Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential. https://arxiv.org/abs/physics/0109017

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