Phase Transition in Size- and Charge-Asymmetric Model Electrolytes

A. L. Khomkin; I. A. Mulenko

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Phase Transition in Size- and Charge-Asymmetric Model Electrolytes

A. L. Khomkin·I. A. Mulenko

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Abstract

A theoretical model of vapor-liquid phase transition in a system of charged hard cores of different diameters is suggested (with the parameters of the transition obtained in a number of studies using the Monte Carlo method). The model is based on the assumption that, in the neighborhood of the critical point, the system of charged cores is a mixture of multipolarly interacting neutral complexes.

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A. L. Khomkin, I. A. Mulenko. 2003-09-24. Phase Transition in Size- and Charge-Asymmetric Model Electrolytes. https://arxiv.org/abs/physics/0309100

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