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Complete homochirality induced by the nonlinear autocatalysis and recycling

Yukio Saito·Hiroyuki Hyuga
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Abstract

A nonlinear autocatalysis of a chiral substance is shown to achieve homochirality in a closed system, if the back-reaction is included. Asymmetry in the concentration of two enantiomers or the enantiometric excess increases due to the nonlinear autocatalysis. Furthermore, when the back-reaction is taken into account, the reactant supplied by the decomposition of the enantiomers is recycled to produce more and more the dominant one, and eventually the homochirality is established.

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Yukio Saito, Hiroyuki Hyuga. 2003-10-29. Complete homochirality induced by the nonlinear autocatalysis and recycling. https://doi.org/10.1143/jpsj.73.33

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