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Fully retarded van der Waals interaction between dielectric nanoclusters

Hye-Young Kim·Jorge O. Sofo·Darrell Velegol·Milton W. Cole
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Abstract

The fully retarded dispersion interaction between an atom and a cluster or between two clusters is calculated. Results obtained with two different methods are compared. One is to consider a cluster as a collection of many atoms and evaluate the sum of two-body and three-body interatomic interactions, a common assumption. The other method, valid at large separation, is to consider each cluster as a point particle, characterized by a polarizability tensor, and evaluate the inter-cluster interaction. This method employs the static polarizability, evaluated by including all many-body (MB) intra-cluster atomic interactions self-consistently, which yields the full inter-cluster interaction, including all MB terms. A comparison of the results from the two methods reveals that the contribution of the higher-than-three-body MB interactions is always attractive and non-negligible, with a relative importance that varies with geometry. The procedure is quite general and is applicable to any shape or size of dielectric clusters, in principle. We present numerical results for clusters composed of atoms with polarizability consistent with silica, for which the higher-than-three-body MB correction term can be as high as 42% of the atomic pair-wise sum. The full result is quite sensitive to the anisotropic structure of the cluster, in contrast to the result found in the additive case, which is orientation independent. We also present a power law expansion of the total van der Waals (VDW) interaction as a series of n-body interaction terms.

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Hye-Young Kim, Jorge O. Sofo, Darrell Velegol, Milton W. Cole. 2006-03-20. Fully retarded van der Waals interaction between dielectric nanoclusters. https://doi.org/10.1063/1.2358681

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