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A geometrical approach to non-adiabatic transitions in quantum theory: applications to NMR, over-barrier reflection and parametric excitation of quantum oscillator

M. S. Marinov·E. Strahov
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Abstract

This article deals with non-adiabatic processes (i.e. processes excluded by the adiabatic theorem) from the geometrical (group-theoretical) point of view. An approximated formula for the probabilities of the non-adiabatic transitions is derived in the adiabatic regime for the case when the parameter-dependent Hamiltonian represents a smooth curve in the Lie algebra and the quantal dynamics is determined by the corresponding Lie group evolution operator. We treat the spin precession in a time-dependent magnetic field and the over-barrier reflection problem in a uniform way using the first-order dynamical equations on SU(2) and $SU(1.1)$ group manifolds correspondingly. A comparison with analytic solutions for simple solvable models is provided.

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M. S. Marinov, E. Strahov. 2000-11-30. A geometrical approach to non-adiabatic transitions in quantum theory: applications to NMR, over-barrier reflection and parametric excitation of quantum oscillator. https://doi.org/10.1088/0305-4470%2F34%2F8%2F317

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