arXiv · quant-ph/0505215
Microscopic origin of the second law of thermodynamics
Abstract
We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state. The uncertainty relation is a quantum-mechanics expression of the second law of thermodynamics originated in wave-particle duality. Formulas of mean square-deviations changes adjusted by random fluctuations under the minimal uncertainty relation are obtained. Finally, an assumption is made which is waiting for examination. We except phase transitions in our discussion.
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You-gang Feng. 2005-05-29. Microscopic origin of the second law of thermodynamics. https://arxiv.org/abs/quant-ph/0505215
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