arXiv subjects

Á. López-Gallifa

Publications and source records attributed to Á. López-Gallifa.

12 recordsLinked to original sources

arXiv2026

CHemical Evolution in MassIve star-forming COres (CHEMICO). II. Molecular ions, electron fraction, and cosmic-ray ionisation rate

Molecular ions are crucial in initiating and regulating the formation of molecules in the interstellar medium, and are expected to be sensitive tracers of evolution in star-forming regions. Within the framework of the project `CHemical Evolution of MassIve star-forming COres' (CHEMICO), we investigate the temporal evolution of molecular ions towards three high-mass star-forming cores that represent three sequential evolutionary stages. CHEMICO is based on an unbiased spectral line survey of the bandwidth at 3, 2, and 1.2~mm carried out with the 30m telescope of the Insitut de Radioastronomie millimétrique. We detect 19 molecular ions, including isotopologues. From a local thermodynamic equilibrium analysis, we derive the following main results: (i) Overall, the physical parameters of sulphur-bearing ions are the most sensitive to evolution, whereas those of nitrogen-bearing ions are the least; (ii) The molecular abundances that exhibit the most pronounced temporal variations are those of SO+, DCO+, and N2D+; (iii) A simple analytic approach tailored for warm gas conditions provides cosmic-ray ionisation rates of H2 several orders of magnitude above the canonical values measured in the interstellar medium and with a marked increase with evolution; (iv) The abundance ratio of protonated-to-neutral species increases with the proton affinity of the neutral regardless of the evolutionary stage of the source, indicating that proton-transfer appears to proceed similarly in both cold and warm interstellar environments. Molecular ions exhibit distinct evolutionary trends in high-mass star-forming regions, with sulphur-bearing species and the abundances of N2D+, DCO+, and SO+ emerging as particularly sensitive tracers of evolution. Measured electron fractions and cosmic-ray ionisation rates are in line with an internal production of cosmic-rays that becomes increasingly efficient with time.

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arXiv2026

ALMAGAL IX. The chemical complexity of AG318.9477-00.1960: A line-identification template for ALMAGAL

We present a detailed molecular line analysis of one of the most chemically rich cores in the ALMAGAL sample, the high-mass core~9 in the AG318.9477-00.1960 clump (AG318-c9), located at a heliocentric distance of \sim 10.4\,\rm kpc. We further assessed whether the emission of selected COMs, that is, ethylene glycol ((CH_2OH)_2; EG), glycolaldehyde (CH_2(OH)CHO; GA), and methyl formate (CH_3OCHO; MF), can be used to trace the innermost regions of hot molecular cores (HMCs). We analysed ALMA Band~6 observations (\sim 217-221GHz). Spectral line identification and local thermodynamic equilibrium modelling were performed using the software MADCUBA. We derived the physical parameters, including the column density (N), excitation temperature (Tex), velocity, line width, and molecular abundances relative to H_2, for all detected species. The chemical inventory of AG318-c9 was compared with that of the HMC G31.41+0.31 (G31). In addition, we performed a pixel-by-pixel analysis of EG, GA, and MF to generate spatially resolved N and Tex maps and corresponding radial profiles.

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arXiv2026

The GUAPOS project -- VII: Physical structure and molecular environment of the G31.41+0.31 HII region

Ionised regions around OB-type stars are formed at an early stage of their evolution and are important to investigate the formation process of these objects. However, so far only few observations of their physical structure and interaction with the parental molecular cloud have been made. The high resolution and sensitivity of new instruments such as ALMA and the upgraded VLA allow us to fill this gap in our knowledge. We investigate the well known core-halo ultracompact HII region G31.41+0.31 and the surrounding molecular clump with the aim to determine the density and temperature of both the ionised and neutral gas, and possibly obtain a 3D picture of their spacial distribution. We take advantage of the full-band frequency coverage at 3 mm obtained with ALMA for the GUAPOS project to image the emission of a plethora of hydrogen recombination lines towards the G31.41+0.31 HII region as well as several molecular transitions which are tracers of medium-density ($\sim$$10^4$--$10^6$ cm$^{-3}$) gas. The line data are complemented by continuum measurements obtained with the VLA at 1 cm and 7 mm. By fitting these lines also using a model that takes into account non-LTE effects we can investigate the density and temperature structure and the velocity field of the region. Our findings, based on a model fit accounting for non-LTE effects, indicate that the electron temperature of the HII region is mostly spanning a range between 5000 and 6000 K, while the density varies between 2500 and 7500 cm$^{-3}$. All in all, the distribution of these parameters as well as the corresponding velocity field hint at a cometary shaped HII region expanding away from the observer to the NW. The molecular gas appears to be still infalling towards the peak of the UC HII region, and its density and temperature are consistent with pressure confinement of the ionised gas to the SE.

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arXiv2026

The GUAPOS project. VI: the chemical inventory of shocked gas

The study of the chemical composition of star-forming regions is key to understanding the chemical ingredients available during the formation of planetary systems. Because the chemical inventory of interstellar dust grains in prestellar phases might be altered by protostellar warming, an alternative to inferring the chemical composition of the grains might be to observe regions that are affected by shocks associated with molecular outflows. These shocks can desorb the molecules and might produce less chemical processing because the timescales are shorter. We present a detailed study of the chemical reservoir of a shocked region located in the G31.41+0.31 protocluster using data from the G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS). We report the detection of 30 molecular species (plus 18 isotopologs). We compared the molecular ratios in the shocked region with those derived toward the hot core of G31.41+0.31. They are poorly correlated, with the exception of N-bearing species. Our results confirm observationally that a different level of chemical alteration is present in hot cores and in shocks. While the former likely alter the molecular ratios by thermal processing during longer timescales, the latter might represent freshly desorbed material that constitutes a better proxy of the composition of the ice mantle. The similarity of the molecular ratios of the N-bearing species in the G31.41+0.31 shock and the hot core suggests that these species are predominantly formed at early evolutionary stages. Interestingly, the abundances in the G31.41+0.31 shock are better correlated with other shock-dominated regions (two protostellar outflows and a molecular cloud in the Galactic center). This suggests that gas-phase chemistry after shock-induced ejection from grains is negligible and that the composition of the ice mantle is similar regardless of the Galactic environment.

astro-ph.GA↗

arXiv2026

Expanding the C$_3$H$_6$O$_2$ Isomeric Interstellar Inventory: Discovery of Lactaldehyde and Methoxyacetaldehyde in G+0.693-0.027

The tentative detection of 3-hydroxypropanal (HO(CH$_2$)$_2$C(O)H) toward the Galactic center molecular cloud G+0.693-0.027 prompts a systematic survey in this source aimed at detecting all C$_3$H$_6$O$_2$ isomers with available spectroscopy. We use an ultra-deep broadband spectral survey of G+0.693-0.027, carried out with the Yebes 40 m and IRAM 30 m telescopes, to conduct the astronomical search. We report the first interstellar detection of lactaldehyde (CH$_3$CH(OH)C(O)H) and methoxyacetaldehyde (CH$_3$OCH$_2$C(O)H), together with the second detections (i.e., confirmation) of methyl acetate (CH$_3$C(O)OCH$_3$) and hydroxyacetone (CH$_3$C(O)CH$_2$OH), and new detections in this source of both $anti$- and $gauche$- conformers of ethyl formate (CH$_3$CH$_2$OC(O)H), the latter tentatively. In contrast, neither propionic acid, CH$_3$CH$_2$C(O)OH, nor glycidol, c-CH$_2$OCHCH$_2$OH (i.e., the most and the least stable species within the C$_3$H$_6$O$_2$ family, respectively) were detected, and we provide upper limits on their fractional abundances of $\leq$1.5 $\times$ 10$^{-10}$ and $\leq$3.7 $\times$ 10$^{-11}$. Interestingly, all C$_3$H$_6$O$_2$ isomers can be synthesized through radical-radical reactions on the surface of dust grains, ultimately tracing back to CO as the parent molecule. We suggest that formation of the detected isomers is mainly driven by successive hydrogenation of CO, producing CH$_3$OH and CH$_3$CH$_2$OH as the primary parent species. Conversely, propionic acid is thought to originate from the oxygenation of CO via the HOCO intermediate, which help us rationalize its non-detection. Overall, our findings notably expand the known chemical inventory of the interstellar medium and provide direct observational evidence that increasingly complex chemistry involving O-bearing species occurs in space.

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arXiv2025

Complex Organic Molecules towards the central molecular zone of NGC 253

Interstellar complex organic molecules (iCOMs) may have a link to prebiotic species, key building blocks for life. In Galactic star-forming (SF) regions, spatial variations of iCOMs emission could reflect the source physical structure or different chemical formation pathways. Investigating iCOMs in extragalactic SF regions may thus provide crucial information about these regions. As an active extragalactic SF region, the central molecular zone (CMZ) of the nearby galaxy NGC 253 provides an ideal template for studying iCOMs under more extreme conditions. We aim to investigate the emission of a few selected iCOMs and understand if a difference between the iCOMs could reflect on the source's chemical or physical structure. Using the high angular resolution ($\sim 27$ pc) observations from the ALCHEMI ALMA large program, we imaged the emission of selected iCOMs and precursors; CH$_3$CHO, C$_2$H$_5$OH, NH$_2$CHO, CH$_2$NH, and CH$_3$NH$_2$. We estimated the iCOMs gas temperatures and column densities using a rotational diagram analysis, and by performing a non-LTE analysis for CH$_2$NH.The iCOM emission concentrates mostly towards the inner part of the CMZ of NGC 253 and can be reproduced with two gas components. Different emission processes can explain iCOM emission towards the CMZ of NGC 253: at Giant Molecular Cloud (GMC) scales ($\sim 27$ pc), the iCOMs could trace large-scale shocks whilst at smaller scales (few pc), both shock and heating processes linked with ongoing star formation may be involved. Using column density correlation trends and known formation pathways, we find that more than one formation path could be involved to explain the iCOM emission. Finally, we found chemical differences between the GMCs, such as a decrease of abundance for the N-bearing species towards one of the GMCs or different excitation conditions for NH$_2$CHO and CH$_3$CHO towards two of the GMCs.

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arXiv2024

The GUAPOS project. V: The chemical ingredients of a massive stellar protocluster in the making

Most stars, including the Sun, are born in rich stellar clusters containing massive stars. Therefore, the study of the chemical reservoir of massive star-forming regions is crucial to understand the basic chemical ingredients available at the dawn of planetary systems. We present a detailed study of the molecular inventory of the hot molecular core G31.41+0.31 from the project GUAPOS (G31.41+0.31 Unbiased ALMA sPectral Observational Survey). We analyze 34 species for the first time plus 20 species analyzed in previous GUAPOS works, including oxygen, nitrogen, sulfur, phosphorus, and chlorine species. We compare the abundances derived in G31.41+0.31 with those observed in other chemically-rich sources that represent the initial and last stages of the formation of stars and planets: the hot corino in the Solar-like protostar IRAS 16293-2422 B, and the comets 67P/Churyumov-Gerasimenko and 46P/Wirtanen. The comparative analysis reveals that the chemical feedstock of the two star-forming regions are similar. The abundances of oxygen- and nitrogen-bearing molecules exhibit a good correlation for all pair of sources, including the two comets, suggesting a chemical heritage of these species during the process of star formation, and hence an early phase formation of the molecules. However, sulfur- and phosphorus-bearing species present worse correlations, being more abundant in comets. This suggests that while sulfur- and phosphorus-bearing species are predominantly trapped on the surface of icy grains in the hot close surroundings of protostars, they could be more easily released into gas phase in comets, allowing their cosmic abundances to be almost recovered.

astro-ph.GA↗

arXiv2023

The GUAPOS project: G31.41+0.31 Unbiased ALMA sPectral Observational Survey. IV. Phosphorus-bearing molecules and their relation with shock tracers

The astrochemistry of the important biogenic element phosphorus (P) is still poorly understood, but observational evidence indicates that P-bearing molecules are likely associated with shocks. We study P-bearing molecules, as well as some shock tracers, towards one of the chemically richest hot molecular core, G31.41+0.31, in the framework of the project "G31.41+0.31 Unbiased ALMA sPectral Observational Survey" (GUAPOS), observed with the Atacama Large Millimeter Array (ALMA). We have observed the molecules PN, PO, SO, SO2, SiO, and SiS, through their rotational lines in the spectral range 84.05-115.91 GHz, covered by the GUAPOS project. PN is clearly detected while PO is tentatively detected. The PN emission arises from two regions southwest of the hot core peak, "1" and "2", and is undetected or tentatively detected towards the hot core peak. the PN and SiO lines are very similar both in spatial emission morphology and spectral shape. Region "1" is in part overlapping with the hot core and it is warmer than region "2", which is well separated from the hot core and located along the outflows identified in previous studies. The column density ratio SiO/PN remains constant in regions "1" and "2", while SO/PN, SiS/PN, and SO2/PN decrease by about an order of magnitude from region "1" to region "2", indicating that SiO and PN have a common origin even in regions with different physical conditions. Our study firmly confirms previous observational evidence that PN emission is tightly associated with SiO and it is likely a product of shock-chemistry, as the lack of a clear detection of PN towards the hot-core allows to rule out relevant formation pathways in hot gas. We propose the PN emitting region "2" as a new astrophysical laboratory for shock-chemistry studies

astro-ph.GA↗

arXiv2023

The GUAPOS project:III. Characterization of the O- and N-bearing complex organic molecules content and search for chemical differentiation

The G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS) project targets the hot molecular core (HMC) G31.41+0.31 (G31), to unveil the complex chemistry of one of the most chemically rich high-mass star-forming regions outside the Galactic Center (GC). In the third paper of the project, we present a study of nine O-bearing (CH$_3$OH, $^{13}$CH$_3$OH, CH$_3^{18}$OH, CH$_3$CHO, CH$_3$OCH$_3$, CH$_3$COCH$_3$ , C$_2$H$_5$OH, aGg'-(CH$_2$OH)$_2$, and gGg'-(CH$_2$OH)$_2$) and six N-bearing (CH$_3$CN, $^{13}$CH$_3$CN, CH$_3^{13}$CN, C$_2$H$_3$CN, C$_2$H$_5$CN, and C$_2$H$_5^{13}$CN) complex organic molecules toward G31. The aim of this work is to characterize the abundances in one of the most chemically-rich hot molecular cores outside the GC and to search for a possible chemical segregation between O-bearing and N-bearing species in G31, which hosts four compact sources as seen with higher angular resolution data. Observations were carried out with the interferometer ALMA and covered the entire Band 3 from 84 to 116 GHz ($\sim 32$ GHz bandwidth) with an angular resolution of $1.2''$ ($\sim4400\,\mathrm{au}$). The spectrum has been analyzed with the tool SLIM of MADCUBA to determine the physical parameters of the emitting gas. Moreover, we have analyzed the morphology of the emission of the molecular species. We have compared the abundances w.r.t methanol of COMs in G31 with other twenty-seven sources, including other hot molecular cores inside and outside the Galactic Center, hot corinos, shocked regions, envelopes around young stellar objects, and quiescent molecular clouds, and with chemical models. Different species peak at slightly different positions, and this, together with the different central velocities of the lines obtained from the spectral fitting, point to chemical differentiation of selected O-bearing species.

astro-ph.GA↗

arXiv2023

The CARMENES search for exoplanets around M dwarfs. Line-by-line sensitivity to activity in M dwarfs

Radial velocities (RVs) measured from high-resolution stellar spectra are routinely used to detect and characterise orbiting exoplanet companions. The different lines present in stellar spectra are created by several species, which are non-uniformly affected by stellar variability features such as spots or faculae. Stellar variability distorts the shape of the spectral absorption lines from which precise RVs are measured, posing one of the main problems in the study of exoplanets. In this work we aim to study how the spectral lines present in M dwarfs are independently impacted by stellar activity. We used CARMENES optical spectra of six active early- and mid-type M dwarfs to compute line-by-line RVs and study their correlation with several well-studied proxies of stellar activity. We are able to classify spectral lines based on their sensitivity to activity in five M dwarfs displaying high levels of stellar activity. We further used this line classification to compute RVs with activity-sensitive lines and less sensitive lines, enhancing or mitigating stellar activity effects in the RV time series. For specific sets of the least activity-sensitive lines, the RV scatter decreases by ~ 2 to 5 times the initial one, depending on the star. Finally, we compare these lines in the different stars analysed, finding the sensitivity to activity to vary from star to star. Despite the high density of lines and blends present in M dwarf stellar spectra, we find that a line-by-line approach is able to deliver precise RVs. Line-by-line RVs are also sensitive to stellar activity effects, and they allow for an accurate selection of activity-insensitive lines to mitigate activity effects in RV. However, we find stellar activity effects to vary in the same insensitive lines from star to star.

astro-ph.SR↗

arXiv2022

The CARMENES search for exoplanets around M dwarfs. Variability on long timescales as seen in chromospheric indicators

It is clearly established that the Sun has an 11-year cycle that is caused by its internal magnetic field. This cycle is also observed in a sample of M dwarfs. In the framework of exoplanet detection or atmospheric characterisation of exoplanets, the activity status of the host star plays a crucial role, and inactive states are preferable for such studies. This means that it is important to know the activity cycles of these stars. We study systematic long-term variability in a sample of 211 M dwarfs observed with CARMENES, the high-resolution optical and near-infrared spectrograph at Calar Alto Observatory. In an automatic search using time series of different activity indicators, we identified 26 stars with linear or quadratic trends or with potentially cyclic behaviour. Additionally, we performed an independent search in archival R$^{\prime}_{\rm HK}$ data collected from different instruments whose time baselines were usually much longer. These data are available for a subset of 186 of our sample stars. Our search revealed 22 cycle candidates in the data. We found that the percentage of stars showing long-term variations drops dramatically to the latest M dwarfs. Moreover, we found that the pseudo-equivalent width (pEW) of the H$α$ and Ca ii infrared triplet more often triggers automatic detections of long-term variations than the TiO index, differential line width, chromatic index, or radial velocity. This is in line with our comparison of the median relative amplitudes of the different indicators. For stars that trigger our automatic detection, this leads to the highest amplitude variation in R$^{\prime}_{\rm HK}$, followed by pEW(H$α$), pEW(Ca ii IRT), and the TiO index.

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arXiv2021

The CARMENES search for exoplanets around M dwarfs. Diagnostic capabilities of strong K I lines for photosphere and chromosphere

There are several strong K I lines found in the spectra of M dwarfs, among them the doublet near 7700 AA and another doublet near 12 500 AA. We study these optical and near-infrared doublets in a sample of 324 M dwarfs, observed with CARMENES, the high-resolution optical and near-infrared spectrograph at Calar Alto, and investigate how well the lines can be used as photospheric and chromospheric diagnostics. Both doublets have a dominant photospheric component in inactive stars and can be used as tracers of effective temperature and gravity. For variability studies using the optical doublet, we concentrate on the red line component because this is less prone to artefacts from telluric correction in individual spectra. The optical doublet lines are sensitive to activity, especially for M dwarfs later than M5.0 V where the lines develop an emission core. For earlier type M dwarfs, the red component of the optical doublet lines is also correlated with H$α$ activity. We usually find positive correlation for stars with H$α$ in emission, while early-type M stars with H$α$ in absorption show anti-correlation. During flares, the optical doublet lines can exhibit strong fill-in or emission cores for our latest spectral types. On the other hand, the near-infrared doublet lines very rarely show correlation or anti-correlation to H$α$ and do not change line shape significantly even during the strongest observed flares. Nevertheless, the near-infrared doublet lines show notable resolved Zeeman splitting for about 20 active stars which allows to estimate the magnetic fields B.

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