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Álvaro Buendía

Publications and source records attributed to Álvaro Buendía.

6 recordsLinked to original sources

Exceptional point induced by hyperbolicity in an electrostatic spherical shell

Exceptional points (EPs) are non--Hermitian degeneracies at which both eigenvalues and eigenvectors coalesce, usually engineered through balanced gain and loss or non--reciprocity. In this work, we show that the radial electrostatic problem of an anisotropic core--shell nanoparticle realizes an EP without any of the alluded conditons. Written in the logarithmic radial coordinate, the problem is a Cauchy--Euler equation that maps onto a damped oscillator and, equivalently, onto a two-site Hatano--Nelson Hamiltonian, so that the non-Hermiticity is emulated in space rather than in time and the sole control parameter is the degree of dielectric anisotropy, $\varepsilon_t/\varepsilon_r$. The shell is passive, reciprocal, and lossless, yet it hosts an EP and a non--Hermitian phase transition governed by hyperbolicity alone. Beyond a hyperbolicity threshold the electric field inside the shell turns from monotonic decay into spatial oscillation, producing hotspots at intermediate radii which can be exploited to tailor fluorescence, strong coupling, sensing, or cloaking. More broadly, this establishes hyperbolic media as a platform to simulate non--Hermitian physics without gain, loss, or non--reciprocity.

cond-mat.mes-hall↗

Far-field radiation of bulk, edge and corner eigenmodes from a finite 2D Su-Schrieffer-Heeger plasmonic lattice

Subwavelength arrays of plasmonic nanoparticles allow us to control the behaviour of light at the nanoscale. Here, we develop an eigenmode analysis, employing a coupled electromagnetic dipole formalism, which permits us to isolate the contribution to the far-field radiation of each array mode. Specifically, we calculate the far-field radiation patterns by bulk, edge and corner out-of-plane eigenmodes in a finite 2D Su-Schrieffer-Heeger (SSH) array of plasmonic nanoparticles with out-of-plane dipolar resonances. The breaking of symmetries in multipartite unit cells is exploited to tailor the optical properties and far-field radiation of the resonant modes. We prove that the antisymmetric modes are darker and have higher Q-factors than their symmetric counterparts. Also, the out-of-plane nature of the dipolar resonances imposes that all bulk $Γ$-modes are dark, while corner and edge states need extra in-plane symmetries to cancel the far-field radiation; radiation patterns in turn become more complex and concentrated along the array plane with increasing array size.

cond-mat.mes-hall↗

Coupled electric dipole model for a Su-Schrieffer-Heeger chain of optically resonant coreshell nanoparticles

Coreshell nanoparticles can combine optical features of different materials in a single nanostructure, which makes them interesting for many applications from biomedicine to energy harvesting. On the other hand, periodic arrays of plasmonic nanoparticles can exhibit topological phenomena such as topological edge states. Here we study periodic chains of Si@Ag coreshell nanoparticles. For this task, we combine the hybridization of surface plasmonic modes in complex nanostructures with the coupled electric dipole formalism employed for modelling the scattering of light by periodic arrays of small plasmonic nanoparticles. We propose treating coreshell nanoparticle as several coupled electric dipoles instead of just one and show how this is a more appropriate framework to study arrays of coreshell nanoparticles, which allows to build a one-to-one connection between the resonant modes of the nanoparticles and the dispersion bands of the system. Within this formalism, we show that a Su-Schrieffer-Heeger (SSH) chain of coreshell Si@Ag nanoparticles host multiple topological edge states pinned at the resonant frequencies of the coreshell nanoparticles.

physics.optics↗

Long-range molecular energy transfer mediated by strong coupling to plasmonic topological edge states

Strong coupling between light and molecular matter is currently attracting interest both in chemistry and physics, in the fast-growing field of molecular polaritonics. The large near-field enhancement of the electric field of plasmonic surfaces and their high tunability make arrays of metallic nanoparticles an interesting platform to achieve and control strong coupling. Two dimensional plasmonic arrays with several nanoparticles per unit cell and crystalline symmetries can host topological edge and corner states. Here we explore the coupling of molecular materials to these edge states using a coupled-dipole framework including long-range interactions. We study both the weak and strong coupling regimes and demonstrate that coupling to topological edge states can be employed to enhance highly-directional long-range energy transfer between molecules.

cond-mat.mes-hall↗

Exploiting oriented field projectors to open topological gaps in plasmonic nanoparticle arrays

In the last years there have been multiple proposals in nanophotonics to mimic topological condensed matter systems. However, nanoparticles have degrees of freedom that atoms lack of, like dimensions or shape, which can be exploited to explore topology beyond electronics. Elongated nanoparticles can act like projectors of the electric field in the direction of the major axis. Then, by orienting them in an array the coupling between them can be tuned, allowing to open a gap in an otherwise gapless system. As a proof of the potential of the use of orientation of nanoparticles for topology, we study 1D chains of prolate spheroidal silver nanoparticles. We show that in these arrays spatial modulation of the polarization allows to open gaps, engineer hidden crystalline symmetries and to switch on/off or left/right edge states depending on the polarization of the incident electric field. This opens a path towards exploiting features of nanoparticles for topology to go beyond analogues of condensed matter systems.

physics.optics↗

Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers

The development of synthetic strategies to engineer π-conjugated polymers is of paramount importance in modern chemistry and materials science. Here we introduce a theoretical and experimental synthetic paradigm based on the search for specific vibrational modes through an appropriate tailoring of the π-conjugation of the precursors, in order to increase the attempt frequency of a chemical reaction. First, we on-surface design a 1D π-conjugated polymer with specific π-topology, which is based on bisanthene monomers linked by cumulene bridges that tune specific vibrational modes. In a second step, upon further annealing, such vibrational modes steer the two-fold cyclization reaction between adjacent bisanthene moieties, which gives rise to a long and free-defect pentalene-bridged conjugated ladder polymer featuring a low band gap. In addition, high resolution atomic force microscopy allows us to identify by atomistic insights the resonant form of the polymer, thus confirming the validity of the Glidewell and Lloyd's rules for aromaticity. This on-surface synthetic strategy may stimulate exploiting previously precluded reactions towards novel pi-conjugated polymers with specific structures and properties.

cond-mat.mes-hall↗