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A V Turbiner

Publications and source records attributed to A V Turbiner.

4 recordsLinked to original sources

Potential Energy Curves of Hydrogenic Halides HX(F,Cl,Br) and i-DMFT Method

A comparison of the {\it ab initio} calculations using the i-DMFT Method by Di Liu et al. (2025) with benchmark potential curves for three HX(F,Cl,Br) halides shows their inaccuracy in the domain around equilibrium - they do not reproduce quantitatively the results of the Born-Oppenheimer approximation - and also they predict a qualitatively wrong behavior in the Van der Waals region of large distances, thus, contradict the multipole expansion.

physics.chem-ph↗

Wolfes model aka $G_2/I_6$-rational integrable model: $g^{(2)}, g^{(3)}$ hidden algebras and quartic polynomial algebra of integrals

One-dimensional 3-body Wolfes model with 2- and 3-body interactions also known as $G_2/I_6$-rational integrable model of the Hamiltonian reduction is exactly-solvable and superintegrable. Its Hamiltonian $H$ and two integrals ${\cal I}_{1}, {\cal I}_{2}$, which can be written as algebraic differential operators in two variables (with polynomial coefficients) of the 2nd and 6th orders, respectively, are represented as non-linear combinations of $g^{(2)}$ or $g^{(3)}$ (hidden) algebra generators in a minimal manner. By using a specially designed MAPLE-18 code to deal with algebraic operators it is found that $(H, {\cal I}_1, {\cal I}_2, {\cal I}_{12} \equiv [{\cal I}_1, {\cal I}_2])$ are the four generating elements of the {\it quartic} polynomial algebra of integrals. This algebra is embedded into the universal enveloping algebra $g^{(3)}$. In turn, 3-body/$A_2$-rational Calogero model is characterized by cubic polynomial algebra of integrals, it is mentioned briefly.

math-ph↗

Radial Anharmonic Oscillator: Perturbation Theory, New Semiclassical Expansion, Approximating Eigenfunctions. II. Quartic and Sextic Anharmonicity Cases

In our previous paper I (del Valle--Turbiner, Int. J. Mod. Phys. A34, 1950143, 2019) it was developed the formalism to study the general $D$-dimensional radial anharmonic oscillator with potential $V(r)= \frac{1}{g^2}\,\hat{V}(gr)$. It was based on the Perturbation Theory (PT) in powers of $g$ (weak coupling regime) and in inverse, fractional powers of $g$ (strong coupling regime) in both $r$-space and in $(gr)$-space, respectively. As the result it was introduced - the Approximant - a locally-accurate uniform compact approximation of a wave function. If taken as a trial function in variational calculations it has led to variational energies of unprecedented accuracy for cubic anharmonic oscillator. In this paper the formalism is applied to both quartic and sextic, spherically-symmetric radial anharmonic oscillators with two term potentials $V(r)= r^2 + g^{2(m-1)}\, r^{2m}, m=2,3$, respectively. It is shown that a two-parametric Approximant for quartic oscillator and a five-parametric one for sextic oscillator for the first four eigenstates used to calculate the variational energy are accurate in 8-12 figures for any $D=1,2,3\ldots $ and $g \geq 0$, while the relative deviation of the Approximant from the exact eigenfunction is less than $10^{-6}$ for any $r \geq 0$.

quant-ph↗

Radial Anharmonic Oscillator: Perturbation Theory, New Semiclassical Expansion, Approximating Eigenfunctions. I. Generalities, Cubic Anharmonicity Case

For the general $D$-dimensional radial anharmonic oscillator with potential $V(r)= \frac{1}{g^2}\,\hat{V}(gr)$ the Perturbation Theory (PT) in powers of coupling constant $g$ (weak coupling regime) and in inverse, fractional powers of $g$ (strong coupling regime) is developed constructively in $r$-space and in $(gr)$ space, respectively. The Riccati-Bloch (RB) equation and Generalized Bloch (GB) equation are introduced as ones which govern dynamics in coordinate $r$-space and in $(gr)$-space, respectively, exploring the logarithmic derivative of wavefunction $y$. It is shown that PT in powers of $g$ developed in RB equation leads to Taylor expansion of $y$ at small $r$ while being developed in GB equation leads to a new form of semiclassical expansion at large $(g r)$: it coincides with loop expansion in path integral formalism. In complementary way PT for large $g$ developed in RB equation leads to an expansion of $y$ at large $r$ and developed in GB equation leads to an expansion at small $(g r)$. Interpolating all four expansions for $y$ leads to a compact function (called the {\it Approximant}), which should uniformly approximate the exact eigenfunction at $r \in [0, \infty)$ for any coupling constant $g \geq 0$ and dimension $D > 0$. Free parameters of the Approximant are fixed by taking it as a trial function in variational calculus. As a concrete application the low-lying states of the cubic anharmonic oscillator $V=r^2+gr^3$ are considered. It is shown that the relative deviation of the Approximant from the exact ground state eigenfunction is $\lesssim 10^{-4}$ for $r \in [0, \infty)$ for coupling constant $g \geq 0$ and dimension $D=1,2,\ldots$. In turn, the variational energies of the low-lying states are obtained with unprecedented accuracy 7-8 s.d. for $g \geq 0$ and $D=1,2,\ldots$.

quant-ph↗