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A. Ansaldo

Publications and source records attributed to A. Ansaldo.

2 recordsLinked to original sources

Enhancing triboelectric nanogenerators power conversion efficiency with few-layers graphene flexible electrodes

The development of portable and wearable electronics requiring only few tens of microwatts to operate fosters the search for low power energy sources. Moreover, the fast-growing demand for new sustainable energy has raised the interest in energy harvesters able to convert mechanical energy into electrical power. Triboelectric nanogenerators (TENGs) can provide such green power supply. Recent developments in TENGs technology show that they can be used in different applications ranging from wearable self-powered sensors to wind and sea wave energy harvesting. In spite of the wide number of TENGs developed so far, an in depth understanding of their working principle is still missing. In this work, we highlight the fundamental role played by the interface between the triboelectric material and the electrode collector in contributing to the TENG's power generation. We show that by simply replacing the 'standard' gold electrodes with flexible few layer graphene electrodes in TENGs operating in vertical contact mode, a 26-fold increase in power density is achieved. Here, we elucidate the main mechanism at the base of such boost in power output, describing guidelines for the combination of electrode and triboelectric materials to optimize the mechanical energy conversion efficiency in TENGs.

cond-mat.mtrl-sci

Graphene-based electron transport layers in perovskite solar cells: a step-up for an efficient carrier collection

The electron transport layer (ETL) plays a fundamental role in perovskite solar cells. Recently, graphene-based ETLs have been proved to be good candidate for scalable fabrication processes and to achieve higher carrier injection with respect to most commonly used ETLs. In this work we experimentally study the effects of different graphene-based ETLs in sensitized MAPI solar cells. By means of time-integrated and picosecond time-resolved photoluminescence techniques, the carrier recombination dynamics in MAPI films embedded in different ETLs is investigated. Using graphene doped mesoporous TiO2 (G+mTiO2) with the addition of a lithium-neutralized graphene oxide (GO-Li) interlayer as ETL, we find that the carrier collection efficiency is increased by about a factor two with respect to standard mTiO2. Taking advantage of the absorption coefficient dispersion, we probe the MAPI layer morphology, along the thickness, finding that the MAPI embedded in the ETL composed by G+mTiO2 plus GO-Li brings to a very good crystalline quality of the MAPI layer with a trap density about one order of magnitude lower than that found with the other ETLs. In addition, this ETL freezes MAPI at the tetragonal phase, regardless of the temperature. Graphene-based ETLs can open the way to significant improvement of perovskite solar cells.

cond-mat.mtrl-sci