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A. Barbour

Publications and source records attributed to A. Barbour.

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Fresnel diffraction imaging of surface nanostructure using coherent resonant X-ray scattering

We investigated surface nanostructures on an antiferromagnet MnBi$_2$Te$_4$ using a novel imaging technique, direct (real)-space and real time coherent X-ray imaging (direct-CXI). This technique has provided new insights into antiferromagnetic textures, including the formation of anti-phase antiferromagnetic (AFM) domains and thermal dynamics of AFM domains and domain walls. While this method produces real-space images of AFM textures without requiring a complex imaging retrieval process, its underlying imaging mechanism has not been fully understood, limiting a deep understanding of AFM textures and the information they contain. By investigating the well-defined structural characteristics of the nanostructures fabricated on MnBi$_2$Te$_4$, we elucidate the imaging principle of this novel technique. We find that the observed images can be well explained by Fresnel diffraction integral. Using a simple model from classical optics, our calculations successfully reproduce the experimentally observed images of the nanostructures. This demonstrates that direct-CXI not only provides straightforward real-space imaging but also contains phase information through its Fresnel diffraction integral.

cond-mat.mtrl-sci

X-ray Fractional Orbital Angular Momentum from Coherent Magnetic Scattering

Artificial spin ice (ASI) based on a square lattice with a topological defect are known to generate orbital angular momentum (OAM) in diffracted X-ray beams. A previous investigation of ASI with even-charge topological defects showed both charge and magnetic X-ray scattering yield photon OAM, but these were confined to integer OAM values. However, the period of the square ASI's antiferromagnetic ground state is twice the period of the structural ground state, which should lead to fractional OAM from magnetic scattering when the topological defect has odd-charge. We employed photoemission electron microscopy to confirm that these ASIs order into antiferromagnetic ground states with protected superdomain walls that provide the phase discontinuity required for fractional OAM. Resonant, coherent X-ray scattering from ASIs with topological defects of charge 1 yields integer-valued X-ray OAM at structural charge peaks and fractional X-ray OAM at magnetic peaks. For thermally active ASIs, the fractional OAM beam exhibits fluctuations in the position of the phase discontinuity and thus dynamic rotation of the beam.

physics.optics

Capping effects on spin and charge excitations in parent and superconducting Nd1-xSrxNiO2

Superconductivity in infinite layer nickelates Nd1-xSrxNiO2 has so far been achieved only in thin films raising questions on the role of substrates and interfaces. Given the challenges associated with their synthesis it is imperative to identify their intrinsic properties. We use Resonant Inelastic X-ray Scattering (RIXS) to investigate the influence of the SrTiO3 capping layer on the excitations of Nd1-xSrxNiO2 (x = 0 and 0.2). Spin excitations are observed in parent and 20% doped Nd1-xSrxNiO2 regardless of capping, proving that magnetism is intrinsic to infinite-layer nickelates and appears in a significant fraction of their phase diagram. In parent and superconducting Nd1-xSrxNiO2, the spin excitations are slightly hardened in capped samples compared to the non-capped ones. Additionally, a weaker Ni - Nd charge transfer peak at ~ 0.6 eV suggests that the hybridization between Ni 3d and Nd 5d orbitals is reduced in capped samples. From our data, capping induces only minimal differences in Nd1-xSrxNiO2 and we phenomenologically discuss these differences based on the reconstruction of the SrTiO3 - NdNiO2 interface and other mechanisms such as crystalline disorder.

cond-mat.supr-con

Comment on newly found Charge Density Waves in infinite layer Nickelates

Recent works[1-3] reported evidence for charge density waves (CDWs) in infinite layer nickelates (112 structure) based on resonant diffraction at the Ni $L_3$ edge measured at fixed scattering angle. We have found that a measurement with fixed momentum transfer, rather than scattering angle, does not show a resonance effect. We have also observed that a nearby structural Bragg peak from the substrate appears due to third harmonic content of the incident beam, and spreads intensity down to the region of the attributed CDW order. This was further confirmed by testing a bare substrate. We suggest procedures to confirm an effective resonant enhancement of a diffraction peak.

cond-mat.supr-con

Nature of the charge-density wave excitations in cuprates

The discovery of charge-density wave (CDW)-related effects in the resonant inelastic x-ray scattering (RIXS) spectra of cuprates holds the tantalizing promise of clarifying the interactions that stabilize the electronic order. Here, we report a comprehensive RIXS study of La2-xSrxCuO4 (LSCO) finding that CDW effects persist up to a remarkably high doping level of x = 0.21 before disappearing at x = 0.25. The inelastic excitation spectra remain essentially unchanged with doping despite crossing a topological transition in the Fermi surface. This indicates that the spectra contain little or no direct coupling to electronic excitations near the Fermi surface, rather they are dominated by the resonant cross-section for phonons and CDW-induced phonon-softening. We interpret our results in terms of a CDW that is generated by strong correlations and a phonon response that is driven by the CDW-induced modification of the lattice.

cond-mat.supr-con

Enhanced electron-phonon coupling for charge-density-wave formation in La$_{1.8-x}$Eu$_{0.2}$Sr$_{x}$CuO$_{4+δ}$

Charge density wave (CDW) correlations are prevalent in all copper-oxide superconductors. While CDWs in conventional metals are driven by coupling between lattice vibrations and electrons, the role of the electron-phonon coupling (EPC) in cuprate CDWs is strongly debated. Using Cu $L_3$ edge resonant inelastic x-ray scattering (RIXS), we study the CDW and Cu-O bond-stretching phonons in the stripe-ordered cuprate La$_{1.8-x}$Eu$_{0.2}$Sr$_{x}$CuO$_{4+δ}$. We investigate the interplay between charge order and EPC as a function of doping and temperature, and find that the EPC is enhanced in a narrow momentum region around the CDW wave vector. By detuning the incident photon energy from the absorption resonance, we extract an EPC matrix element at the CDW wave vector of $M\simeq$ 0.36 eV, which decreases to $M\simeq$ 0.30 eV at high temperature in the absence of the CDW. Our results suggest a feedback mechanism in which the CDW enhances the EPC which, in turn, further stabilizes the CDW.

cond-mat.supr-con

Imaging antiferromagnetic antiphase domain boundaries using magnetic Bragg diffraction phase contrast

Manipulating magnetic domains is essential for many technological applications. Recent breakthroughs in Antiferromagnetic Spintronics brought up novel concepts for electronic device development. Imaging antiferromagnetic domains is of key importance to this field. Unfortunately, some of the basic domain types, such as antiphase domains, cannot be imaged by conventional techniques. Herein, we present a new domain projection imaging technique based on the localization of domain boundaries by resonant magnetic diffraction of coherent x rays. Contrast arises from reduction of the scattered intensity at the domain boundaries due to destructive interference effects. We demonstrate this approach by imaging antiphase domains in a collinear antiferromagnet Fe2Mo3O8, and observe evidence of domain wall interaction with a structural defect. This technique does not involve any numerical algorithms. It is fast, sensitive, produces large-scale images in a single-exposure measurement, and is applicable to a variety of magnetic domain types.

cond-mat.mes-hall

Dynamics of Au (001) Surface in Electrolytes: In-Situ Coherent X-ray Scattering and Scanning Tunneling Microscopy

We studied dynamics of Au (001) surface in situ in 0.1 M HClO4 electrolyte solution using both coherent x-ray scattering and scanning tunneling microscopy (STM). The surface of Au (001) is known to reconstruct at cathodic potentials; the reconstruction lifts at anodic potentials. In our in-situ STM experiments, the measurements focus on time-dependent progressions of surface morphology during slow potential sweep. In our in-situ coherent x-ray scattering measurements, we demonstrate that the equilibrium surface dynamics are directly measurable and the measured dynamics are consistent with morphological evolution of the STM images. These experiments represent the first successful application of coherent x-ray scattering to the study of electrochemical interfaces in situ.

cond-mat.mtrl-sci

Persistent Oscillations of X-ray Speckles: Pt (001) Step Flow

We have performed coherent x-ray scattering experiments on the hexagonally reconstructed Pt (001) surface to study the temperature-dependent surface dynamics. By correlating speckle patterns collected at the (001) anti-Bragg position we are able to measure surface dynamics when the averaged incoherent x-ray scattering appears static. In the temperature range above the rotational epitaxy transition and below the roughening transition (1750 K - 1830 K), we have observed well-defined oscillatory autocorrelations of speckles that persist for tens of minutes, in addition to the expected thermal decorrelation. The observed oscillations indicate surface dynamics due to "step-flow" motion. This is shown with a simple model in which the phase of the scattered x-rays from the steps within the illumination area is retained in the coherent x-ray scattering. This demonstrates a possibility that x-ray speckles can be used to monitor the real-space real-time evolution of surfaces in addition to the traditional decorrelation measurements.

cond-mat.mtrl-sci