arXiv subjects

A. Coutens

Publications and source records attributed to A. Coutens.

At least 19 recordsLinked to original sources

arXiv2024

The rotation-tunneling spectrum of 3-hydroxypropenal and confirmation of its detection toward IRAS 16293$-$2422 B

3-Hydroxypropenal (HOCHCHCHO) is the lower energy tautomer of malonaldehyde which displays a complex rotation-tunneling spectrum. It was detected tentatively toward the solar-type protostar IRAS 16293$-$2422 B with ALMA in the framework of the Protostellar Interferometric Line Survey (PILS). Several transitions, however, had large residuals, preventing not only their detection, but also the excitation temperature of the species from being determined unambiguously. We want to extend the existing rotational line list of 3-hydroxypropenal to shed more light on the recent observational results and to facilitate additional radio astronomical searches for this molecule. We analyzed the rotation-tunneling spectrum of 3-hydroxypropenal in the frequency regions between 150 and 330 GHz and between 400 and 660 GHz. Transitions were searched for in the PILS observations of IRAS 16293$-$2422. Local thermodynamic equilibrium (LTE) models were carried out and compared to the observations to constrain the excitation temperature. Additional transitions were searched for in other ALMA archival data of the same source to confirm the presence of 3-hydroxypropenal. More than 11500 transitions were assigned in the course of our investigation with quantum numbers $2 \le J \le 100$, $K_a \le 59$, and $K_c \le 97$, resulting in a greatly improved set of spectroscopic parameters. The comparison between the LTE models and the observations yields an excitation temperature of 125 K with a column density $N = 1.0 \times 10^{15}$ cm$^{-2}$ for this species. We identified seven additional lines of 3-hydroxypropenal that show a good agreement with the model in the ALMA archive data. The calculated rotation-tunneling spectrum of 3-hydroxypropenal has sufficient accuracy for radio astronomical searches. The detection of 3-hydroxypropenal toward IRAS 16293$-$2422 B is now secure.

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arXiv2024

Chemical inventory of the envelope of the Class I protostar L1551 IRS 5

Episodic accretion in protostars leads to luminosity outbursts that end up heating their surroundings. This rise in temperature pushes the snow lines back, enabling the desorption of chemical species from dust grain surfaces, which may significantly alter the chemical history of the accreting envelope. However, a limited number of extensive chemical surveys of eruptive young stars have been performed thus far. In the present study, we carry out a large spectral survey of the binary Class I protostar L1551 IRS 5, known to be a FUor-like object, in the 3mm and 2mm bands with the IRAM-30m telescope. As a result, we detected more than 400 molecular lines. The source displays a great chemical richness with the detection of 75 species, including isotopologues. Among these species, there are 13 hydrocarbons, 25 N-bearing species, 30 O-bearing species, 15 S-bearing species, 12 deuterated molecules, and a total of 10 complex organic molecules (l-C4H2, CH3CCH, CH2DCCH, CH3CHO, CH3CN, CH3OCH3, CH3OCHO, CH3OH, CH2DOH, and HC5N). With the help of local thermodynamic equilibrium (LTE) and non-LTE models, we determined the column densities of most molecules as well as excitation and kinetic temperatures. While most of those molecules trace the cold envelope (< 20 K), the OCS and CH3OH emission arise from the warm (> 100 K) innermost (< 2'' ) regions. We compared the chemical inventory of L1551 IRS 5 and its column density ratios, including isotopic ratios, with other protostellar sources. A broad chemical diversity is seen among Class I objects. More observations with both single-dish telescopes and interferometers are needed to characterize the diversity in a larger sample of protostars, while more astrochemical models would help explain this diversity, in addition to the impact of luminosity outbursts on the chemistry of protostellar envelopes.

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arXiv2022

Millimetre-wave spectroscopy of 2-hydroxyprop-2-enal and an astronomical search with ALMA

The molecule studied in this work, 2-hydroxyprop-2-enal, is among the candidates to be searched for in the interstellar medium (ISM), as it is a dehydration product of C3 sugars and contains structural motifs typical for some interstellar molecules. The aim of this work is to deepen knowledge about the millimetre-wave spectrum of 2-hydroxyprop-2-enal in the region enabling its search towards astronomical objects. We target the solar-type protostar IRAS16293-2422 and star-forming region Sagittarius (Sgr) B2(N). The rotational spectrum of 2-hydroxyprop-2-enal was measured and analysed in the frequency regions of 128-166 GHz and 285-329 GHz. The interstellar exploration towards IRAS16293-2422 was based on the Atacama Large Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric Line Survey. We also used the imaging spectral line survey ReMoCA performed with ALMA toward Sgr B2(N). We modelled the astronomical spectra under the assumption of local thermodynamic equilibrium. We provide analysis of hundreds of rotational transitions of 2-hydroxyprop-2-enal in the ground state and the lowest lying excited vibrational state. We report its nondetection towards IRAS16293 B. The 2-hydroxyprop-2-enal/3-hydroxypropenal abundance ratio is estimated to be less-than or similar to 0.9-1.3 in agreement with the predicted value of 1.4. We also report the nondetection of 2-hydroxyprop-2-enal toward the hot molecular core Sgr B2(N1). We did not detect the related aldehydes 2-hydroxypropanal and 3-hydroxypropenal either. We find that these three molecules are at least 9, 4, and 10 times less abundant than acetaldehyde in this source, respectively. Despite the nondetections, the results of this work represent a significant improvement on previous investigations in the microwave region and meets the requirements for further searches of this molecule in the ISM.

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arXiv2022

Confirmation of the outflow in L1451-mm: SiO line and CH$_3$OH maser detections

The observational counterparts of theoretically predicted first hydrostatic cores (FHSC) have been searched for in the interstellar medium for nearly two decades now. Distinguishing them from other types of more evolved but still embedded objects remains a challenge because these objects have a short lifetime, are small, and embedded in a dense cocoon. One possible lead to finding them is the characterization of the outflows that are launched by these objects. We observed the L1451-mm FHSC candidate with the NOEMA interferometer in order to study the emission of several molecules. A nonlocal thermodynamic equilibrium analysis of the CH$_3$OH detected lines was performed to retrieve the physical conditions of the emitting region around the central source, together with the CH$_3$OH, SiO, CS, and H$_2$CO column densities. Of the targeted molecules, we detected lines of c-C$_3$H$_2$, CH$_3$OH, CS, C$^{34}$S, SO, DCN, DCO$^+$, H$_2$CO, HC$_3$N, HDCO, and SiO. One of the methanol lines appears to be a maser line. The detection of this class I maser and the SiO line in L1451-mm support the presence of a low-velocity and compact outflow. The excitation conditions of the thermal lines of methanol are also compatible with shocks (H$_2$ density of $\sim 3\times 10^6$~cm$^{-3}$ and a temperature higher than 40~K). Although these low-velocity outflows are theoretically predicted by some models of FHSC, these models also predict the shock temperature to be below 20~K, that is, not evaporating methanol. In addition, the predicted velocities would not erode the grains and release silicon in the gas phase. We therefore conclude that these new observations favor the hypothesis that L1451-mm would be at a very early protostellar stage, launching an outflow nearly on the plane of the sky with a higher velocity than is observed.

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arXiv2022

The ALMA-PILS survey: First tentative detection of 3-hydroxypropenal (HOCHCHCHO) in the interstellar medium and chemical modeling of the C$_3$H$_4$O$_2$ isomers

Characterizing the molecular composition of solar-type protostars is useful for improving our understanding of the physico-chemical conditions under which the Sun and its planets formed. In this work, we analyzed the Atacama Large Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric Line Survey (PILS), an unbiased spectral survey of the solar-type protostar IRAS~16293--2422, and we tentatively detected 3-hydroxypropenal (HOCHCHCHO) for the first time in the interstellar medium towards source B. Based on the observed line intensities and assuming local thermodynamic equilibrium, its column density is constrained to be $\sim$10$^{15}$ cm$^{-2}$, corresponding to an abundance of 10$^{-4}$ relative to methanol, CH$_3$OH. Additional spectroscopic studies are needed to constrain the excitation temperature of this molecule. We included HOCHCHCHO and five of its isomers in the chemical network presented in Manigand et al. (2021) and we predicted their chemical evolution with the Nautilus code. The model reproduces the abundance of HOCHCHCHO within the uncertainties. This species is mainly formed through the grain surface reaction CH$_2$CHO + HCO $\rightarrow$ HCOCH$_2$CHO, followed by the tautomerization of HCOCH$_2$CHO into HOCHCHCHO. Two isomers, CH$_3$COCHO and CH$_2$COHCHO, are predicted to be even more abundant than HOCHCHCHO. Spectroscopic studies of these molecules are essential in searching for them in IRAS~16293--2422 and other astrophysical sources.

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arXiv2021

An unbiased NOEMA 2.6 to 4 mm survey of the GG Tau ring: First detection of CCS in a protoplanetary disk

Molecular line surveys are among the main tools to probe the structure and physical conditions in protoplanetary disks (PPDs), the birthplace of planets. The large radial and vertical temperature as well as density gradients in these PPDs lead to a complex chemical composition, making chemistry an important step to understand the variety of planetary systems. We aimed to study the chemical content of the protoplanetary disk surrounding GG Tau A, a well-known triple T Tauri system. We used NOEMA with the new correlator PolyFix to observe rotational lines at 2.6 to 4 mm from a few dozen molecules. We analysed the data with a radiative transfer code to derive molecular densities and the abundance relative to $^{13}$CO, which we compare to those of the TMC1 cloud and LkCa15 disk. We report the first detection of CCS in PPDs. We also marginally detect OCS and find 16 other molecules in the GG Tauri outer disk. Ten of them had been found previously, while seven others ($^{13}$CN, N$_2$H$^+$, HNC, DNC, HC$_3$N, CCS, and C$^{34}$S) are new detections in this disk. The analysis confirms that sulphur chemistry is not yet properly understood. The D/H ratio, derived from DCO$^{+}$/HCO$^{+}$, DCN/HCN, and DNC/HNC ratios, points towards a low temperature chemistry. The detection of the rare species CCS confirms that GG Tau is a good laboratory to study the protoplanetary disk chemistry, thanks to its large disk size and mass.

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arXiv2021

ALMA observations of doubly deuterated water: Inheritance of water from the prestellar environment

Establishing the origin of the water D/H ratio in the Solar System is central to our understanding of the chemical trail of water during the star and planet formation process. Recent modeling suggests that comparisons of the D$_2$O/HDO and HDO/H$_2$O ratios are a powerful way to trace the chemical evolution of water and, in particular, determine whether the D/H ratio is inherited from the molecular cloud or established locally. We seek to determine the D$_2$O column density and derive the D$_2$O/HDO ratios in the warm region toward the low-mass Class 0 sources B335 and L483. The results are compared with astrochemical models and previous observations to determine their implications for the chemical evolution of water. We present ALMA observations of the D$_2$O transition at 316.8 GHz toward B335 and L483 at $<$0.5" ($<$ 100 au) resolution, probing the inner warm envelope gas. The column densities of D$_2$O, HDO, and H$_{2}^{18}$O are determined by synthetic spectrum modeling and direct Gaussian fitting, under the assumption of a single excitation temperature and similar spatial extent for the three water isotopologs. D$_2$O is detected toward both sources in the inner warm envelope. The derived D$_2$O/HDO ratios is $(1.0\pm0.2)\times10^{-2}$ for L483 and $(1.4\pm0.1)\times10^{-2}$ for B335. The high D$_2$O/HDO ratios are a strong indication of chemical inheritance of water from the prestellar phase down to the inner warm envelope. This implies that the local cloud conditions in the prestellar phase, such as temperatures and timescales, determine the water chemistry at later stages and could provide a source of chemical differentiation in young systems. In addition, the observed D$_2$O/H$_2$O ratios support an observed dichotomy in the deuterium fractionation of water toward isolated and clustered protostars, namely, a higher D/H ratio toward isolated sources

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arXiv2020

The prebiotic molecular inventory of Serpens SMM1 I. An investigation of the isomers CH$_{3}$NCO and HOCH$_{2}$CN

Methyl isocyanate (CH$_{3}$NCO) and glycolonitrile (HOCH$_{2}$CN) are isomers and prebiotic molecules that are involved in the formation of peptide structures and the nucleobase adenine, respectively. ALMA observations of the intermediate-mass Class 0 protostar Serpens SMM1-a and ALMA-PILS data of the low-mass Class 0 protostar IRAS~16293B are used. Spectra are analysed with the CASSIS line analysis software package in order to identify and characterise molecules. CH$_{3}$NCO, HOCH$_{2}$CN, and various other molecules are detected towards SMM1-a. HOCH$_{2}$CN is identified in the PILS data towards IRAS~16293B in a spectrum extracted at a half-beam offset position from the peak continuum. CH$_{3}$NCO and HOCH$_{2}$CN are equally abundant in SMM1-a at [X]/[CH$_{3}$OH] of 5.3$\times$10$^{-4}$ and 6.2$\times$10$^{-4}$, respectively. A comparison between SMM1-a and IRAS~16293B shows that HOCH$_{2}$CN and HNCO are more abundant in the former source, but CH$_{3}$NCO abundances do not differ significantly. Data from other sources are used to show that the [CH$_{3}$NCO]/[HNCO] ratio is similar in all these sources within $\sim$10\%. The new detections of CH$_{3}$NCO and HOCH$_{2}$CN are additional evidence for a large interstellar reservoir of prebiotic molecules that can contribute to the formation of biomolecules on terrestrial planets. A plausible formation pathway for HOCH$_{2}$CN is the thermal Strecker-like reaction of CN$^{-}$ with H$_{2}$CO. The similar [CH$_{3}$NCO]/[HNCO] ratios indicate that these two species either are chemically related or their formation is affected by physical conditions in the same way. The relatively high abundances of HOCH$_{2}$CN and HNCO in SMM1-a may be explained by a prolonged stage of relatively warm ice mantles, where thermal and energetic processing of HCN in the ice results in the efficient formation of both species.

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arXiv2020

Chemical evolution during the formation of a protoplanetary disk

(Abridged) The aim of this study is to investigate the chemical evolution from the prestellar phase to the formation of the disk, and to determine the impact that the chemical composition of the cold and dense core has on the final composition of the disk. We performed 3D nonideal magneto-hydrodynamic (MHD) simulations of a dense core collapse using the adaptive-mesh-refinement RAMSES code. For each particle ending in the young rotationally supported disk, we ran chemical simulations with the three-phase gas-grain chemistry code Nautilus. Two different sets of initial abundances, which are characteristic of cold cores, were considered. The final distributions of the abundances of common species were compared to each other, as well as with the initial abundances of the cold core. We find that the spatial distributions of molecules reflect their sensitivity to the temperature distribution. The main carriers of the chemical elements in the disk are usually the same as the ones in the cold core, except for the S-bearing species, where HS is replaced by H$_2$S$_3$, and the P-bearing species, where atomic P leads to the formation of PO, PN, HCP, and CP. However, the abundances of less abundant species change over time. This is especially the case for "large" complex organic molecules (COMs) such as CH$_3$CHO, CH$_3$NH$_2$, CH$_3$OCH$_3$, and HCOOCH$_3$ which see their abundances significantly increase during the collapse. These COMs often present similar abundances in the disk despite significantly different abundances in the cold core. In contrast, the abundances of many radicals decrease with time. A significant number of species still show the same abundances in the cold core and the disk, which indicates efficient formation of these molecules in the cold core. This includes H$_2$O, H$_2$CO, HNCO, and "small" COMs such as CH$_3$OH, CH$_3$CN, and NH$_2$CHO.

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arXiv2020

The ALMA-PILS survey: First detection of the unsaturated 3-carbon molecules Propenal (C$_2$H$_3$CHO) and Propylene (C$_3$H$_6$) towards IRAS 16293$-$2422 B

Complex organic molecules with three carbon atoms are found in the earliest stages of star formation. In particular, propenal (C$_2$H$_3$CHO) is a species of interest due to its implication in the formation of more complex species and even biotic molecules. This study aims to search for the presence of C$_2$H$_3$CHO and other three-carbon species such as propylene (C$_3$H$_6$) in the hot corino region of the low-mass protostellar binary IRAS 16293--2422 to understand their formation pathways. We use ALMA observations in Band 6 and 7 from various surveys to search for the presence of C$_3$H$_6$ and C$_2$H$_3$CHO towards the protostar IRAS 16293--2422 B (IRAS 16293B). We report the detection of both C$_3$H$_6$ and C$_2$H$_3$CHO towards IRAS 16293B, however, no unblended lines were found towards the other component of the binary system, IRAS 16293A. We derive column density upper limits for C$_3$H$_8$, HCCCHO, n-C$_3$H$_7$OH, i-C$_3$H$_7$OH, C$_3$O, and cis-HC(O)CHO towards IRAS 16293B. We then use a three-phase chemical model to simulate the formation of these species in a typical prestellar environment followed by its hydrodynamical collapse until the birth of the central protostar. Different formation paths, such as successive hydrogenation and radical-radical additions on grain surfaces, are tested and compared to the observational results. The simulations reproduce the abundances within one order of magnitude from those observed towards IRAS 16293B, with the best agreement found for a rate of $10^{-12}$ cm$^3$ s$^{-1}$ for the gas-phase reaction C$_3$ + O $\rightarrow$ C$_2$ + CO. Successive hydrogenations of C$_3$, HC(O)CHO, and CH$_3$OCHO on grain surfaces are a major and crucial formation route of complex organics molecules, whereas both successive hydrogenation pathways and radical-radical addition reactions contribute to the formation of C$_2$H$_5$CHO.

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arXiv2020

The ALMA-PILS survey: Inventory of complex organic molecules towards IRAS 16293-2422 A

Complex organic molecules (COM) are detected in many sources in the warm inner regions of envelopes surrounding deeply embedded protostars. Exactly how these COM form remains an open question. This study aims to constrain the formation of complex organic molecules through comparisons of their abundances towards the Class 0 protostellar binary IRAS 16293-2422 (IRAS16293). We utilised observations from the ALMA Protostellar Interferometric Line Survey of IRAS16293. The species identification and the rotational temperature and column density estimation were derived by fitting the extracted spectra towards IRAS16293 A and IRAS16293 B with synthetic spectra. The majority of the work in this paper pertains to the analysis of IRAS16293 A for a comparison with the results from the other binary component, which have already been published. We detect 15 different COM, as well as 16 isotopologues towards the most luminous companion protostar IRAS16293 A. Tentative detections of an additional 11 isotopologues are reported. We also searched for and report on the first detections of CH3OCH2OH and t-C2H5OCH3 towards IRAS16293 B and the follow-up detection of CH2DCHO and CH3CDO. Twenty-four lines of CHD2OH are also identified. The comparison between the two protostars of the binary system shows significant differences in abundance for some of the species, which are partially correlated to their spatial distribution. The spatial distribution is consistent with the sublimation temperature of the species; those with higher expected sublimation temperatures are located in the most compact region of the hot corino towards IRAS16293 A. This spatial differentiation is not resolved in IRAS16293 B and will require observations at a higher angular resolution. In parallel, the list of identified CHD2OH lines shows the need of accurate spectroscopic data including their line strength.

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arXiv2019

The ALMA-PILS survey: propyne (CH$_3$CCH) in IRAS 16293$-$2422

Context. Propyne (CH$_3$CCH) has been detected in a variety of environments, from Galactic star-forming regions to extragalactic sources. Such molecules are excellent tracers of the physical conditions in star-forming regions. Aims. This study explores the emission of CH$_3$CCH in the low-mass protostellar binary, IRAS 16293$-$2422, examining the spatial scales traced by this molecule, as well as its formation and destruction pathways. Methods. ALMA observations from the Protostellar Interferometric Line Survey (PILS) are used to determine the abundances and excitation temperatures of CH$_3$CCH towards both protostars, exploring spatial scales from 70 to 2400 au. The three-phase chemical kinetics model MAGICKAL is also used, to explore the chemical reactions of this molecule. Results. CH$_3$CCH is detected towards both IRAS 16293A and IRAS 16293B and is found to trace the hot corino component around each source in the PILS dataset. Eighteen transitions above 3$σ$ are detected, enabling robust excitation temperatures and column densities to be determined in each source. In IRAS 16293A, an excitation temperature of 90 K and a column density of 7.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. In IRAS 16293B, an excitation temperature of 100 K and 6.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. The chemical modelling finds that in order to reproduce the observed abundances, both gas-phase and grain-surface reactions are needed. Conclusions. CH$_3$CCH is a molecule whose brightness and abundance in many different regions can be utilised to provide a benchmark of molecular variation with the physical properties of star-forming regions. It is essential when making such comparisons, that the abundances are determined with a good understanding of the spatial scale of the emitting region, to ensure that accurate abundances are derived.

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arXiv2019

ALMA observations of water deuteration: A physical diagnostic of the formation of protostars

The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of water during star formation and can constrain the origin of water in Solar System bodies. We determine the HDO/H$_2$O ratio in the inner warm gas toward three low-mass Class 0 protostars selected to be in isolated cores, i.e., not associated with any cloud complexes. Previous sources for which the HDO/H$_2$O ratio have been established were all part of larger star-forming complexes. Targeting these isolated protostars allows comparison of the water chemistry in isolated and clustered regions to determine the influence of local cloud environment. We present ALMA observations of the HDO $3_{1,2}$-$2_{2,1}$ and $2_{1,1}$-$2_{1,2}$ transitions at 225.897 GHz and 241.562 GHz along with the H$_2^{18}$O $3_{1,3}$-$2_{2,0}$ transition at 203.407 GHz. The high angular resolution (0\farcs3-1\farcs3) allow the study of the inner warm envelope gas. Model-independent estimates for the HDO/H$_2$O ratios are obtained and compared with previous determinations in the warm gas toward low-mass protostars. We detect the targeted water transitions toward the three sources with S/N > 5. We determine the HDO/H$_2$O ratio toward L483, B335 and BHR71-IRS1 to be ($2.2\pm0.4$)$\times 10^{-3}$, ($1.7\pm0.3$)$\times 10^{-3}$, and ($1.8\pm0.4$)$\times 10^{-3}$, respectively, assuming $T_\mathrm{ex} = 124$ K. The degree of water deuteration of these isolated protostars are a factor of 2-4 higher relative to Class 0 protostars that are members of known nearby clustered star-forming regions. The results indicate that the water deuterium fractionation is influenced by the local cloud environment. This effect can be explained by variations in either collapse timescales or temperatures, which depends on local cloud dynamics and could provide a new method to decipher the history of young stars.

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arXiv2019

VLA cm-wave survey of young stellar objects in the Oph A cluster: constraining extreme UV- and X-ray-driven disk photo-evaporation -- A pathfinder for Square Kilometre Array studies

Observations of young stellar objects (YSOs) in centimeter bands can probe the continuum emission from growing dust grains, ionized winds, and magnetospheric activity, which are intimately connected to the evolution of protoplanetary disks and the formation of planets. We have carried out sensitive continuum observations toward the Ophiuchus A star-forming region using the Karl G. Jansky Very Large Array (VLA) at 10 GHz over a field-of-view of 6$'$ with a spatial resolution of $θ_{maj}$ $\times$ $θ_{min}$ $\sim$ 0.4$''$ $\times$ 0.2$''$. We achieved a 5 $μ$Jy beam$^{-1}$ root-mean-square noise level at the center of our mosaic field of view. Among the eighteen sources we detected, sixteen are YSOs (three Class 0, five Class I, six Class II, and two Class III) and two are extragalactic candidates. We find that thermal dust emission generally contributes less that 30% of the emission at 10 GHz. The radio emission is dominated by other types of emission such as gyro-synchrotron radiation from active magnetospheres, free-free emission from thermal jets, free-free emission from the outflowing photo-evaporated disk material, and/or synchrotron emission from accelerated cosmic-rays in jet or protostellar surface shocks. These different types of emission could not be clearly disentangled. Our non-detections towards Class II/III disks suggest that extreme UV-driven photoevaporation is insufficient to explain the disk dispersal, assuming that the contribution of UV photoevaporating stellar winds to radio flux does not evolve with time. The sensitivity of our data cannot exclude photoevaporation due to X-ray photons as an efficient mechanism for disk dispersal. Deeper surveys with the Square Kilometre Array will be able to provide strong constraints on disk photoevaporation.

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arXiv2019

The ALMA-PILS survey: Gas dynamics in IRAS 16293$-$2422 and the connection between its two protostars

[Abridged] The majority of stars form in binary or higher order systems. The Class 0 protostellar system IRAS16293-2422 contains two protostars, 'A' and 'B', separated by ~600 au and embedded in a single, 10^4 au scale envelope. Their relative evolutionary stages have been debated. We aim to study the relation and interplay between the two protostars A and B at spatial scales of 60 to ~1000 au. We selected molecular gas line transitions of CO, H2CO, HCN, CS, SiO, and CCH from the ALMA-PILS spectral imaging survey (329-363 GHz) and used them as tracers of kinematics, density, and temperature in the IRAS16293-2422 system. The angular resolution of the PILS data set allows us to study these quantities at a resolution of 0.5 arcsec (60 au [..]). Line-of-sight velocity maps of both optically thick and optically thin molecular lines reveal: (i) new manifestations of previously known outflows emanating from protostar A; (ii) a kinematically quiescent bridge of dust and gas spanning between the two protostars, with an inferred density between 4 10^4 and 3 10^7 cm^-3; and (iii) a separate, straight filament seemingly connected to protostar B seen only in CCH, with a flat kinematic signature. Signs of various outflows, all emanating from source A, are evidence of high-density and warmer gas; none of them coincide spatially and kinematically with the bridge. We hypothesize that the bridge arc is a remnant of filamentary substructure in the protostellar envelope material from which protostellar sources A and B have formed. One particular morphological structure appears to be due to outflowing gas impacting the quiescent bridge material. The continuing lack of clear outflow signatures unambiguously associated to protostar B and the vertically extended shape derived for its disk-like structure lead us to conclude that source B may be in an earlier evolutionary stage than source A.

astro-ph.GA↗

arXiv2019

Laboratory spectroscopic study of the $^{15}$N isotopomers of cyanamide, H$_2$NCN, and a search for them toward IRAS 16293$-$2422 B

Cyanamide is one of the few interstellar molecules containing two chemically different N atoms. It was detected recently toward the solar-type protostar IRAS 16293-2422 B together with H$_2$N$^{13}$CN and HDNCN in the course of the Atacama Large Millemeter/submillimeter Array (ALMA) Protostellar Interferometric Line Survey (PILS). The detection of the 15N isotopomers or the determination of upper limits to their column densities was hampered by the lack of accurate laboratory data at the frequencies of the survey. We wanted to determine spectroscopic parameters of the $^{15}$N isotopomers of cyanamide that are accurate enough for predictions well into the submillimeter region and to search for them in the PILS data. We investigated the laboratory rotational spectra of H$_2^{15}$NCN and H$_2$NC$^{15}$N in the selected region between 192 and 507~GHz employing a cyanamide sample in natural isotopic composition. Additionally, we recorded transitions of H$_2$N$^{13}$CN. We obtained new or improved spectroscopic parameters for the three isotopic species. Neither of the $^{15}$N isotopomers of cyanamide were detected unambiguously in the PILS data. Two relatively clean lines can be tentatively assigned to H$_2^{15}$NCN. If confirmed, their column densities would imply a low $^{14}$N/$^{15}$N ratio for cyanamide toward this source. The resulting line lists should be accurate enough for observations up to about 1 THz. More sensitive observations, potentially at different frequencies, may eventually lead to the astronomical detection of these isotopic species.

astro-ph.SR↗

arXiv2019

The ALMA-PILS survey: First detection of nitrous acid (HONO) in the interstellar medium

Nitrogen oxides are thought to play a significant role as a nitrogen reservoir and to potentially participate in the formation of more complex species. Until now, only NO, N$_2$O and HNO have been detected in the interstellar medium. We report the first interstellar detection of nitrous acid (HONO). Twelve lines were identified towards component B of the low-mass protostellar binary IRAS~16293--2422 with the Atacama Large Millimeter/submillimeter Array, at the position where NO and N$_2$O have previously been seen. A local thermodynamic equilibrium model was used to derive the column density ($\sim$ 9 $\times$ 10$^{14}$ cm$^{-2}$ in a 0.5'' beam) and excitation temperature ($\sim$ 100 K) of this molecule. HNO, NO$_2$, NO$^+$, and HNO$_3$ were also searched for in the data, but not detected. We simulated the HONO formation using an updated version of the chemical code Nautilus and compared the results with the observations. The chemical model is able to reproduce satisfactorily the HONO, N$_2$O, and NO$_2$ abundances, but not the NO, HNO, and NH$_2$OH abundances. This could be due to some thermal desorption mechanisms being destructive and therefore limiting the amount of HNO and NH$_2$OH present in the gas phase. Other options are UV photodestruction of these species in ices or missing reactions potentially relevant at protostellar temperatures.

astro-ph.SR↗

arXiv2018

The ALMA-PILS survey: The first detection of doubly-deuterated methyl formate (CHD2OCHO) in the ISM

Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in regions of star formation. In particular, the abundances of deuterated species are very sensitive to the physical conditions in the environment where they form. Due to the low temperatures in regions of star formation, these isotopologues are enhanced to significant levels, making detections of multiply-deuterated species possible. However, for complex organic species, only the multiply-deuterated variants of methanol and methyl cyanide have been reported so far. The aim of this paper is to initiate the characterisation of multiply-deuterated variants of complex organic species with the first detection of doubly-deuterated methyl formate, CHD2OCHO. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) of the protostellar binary IRAS 16293-2422, in the spectral range of 329.1 GHz to 362.9 GHz. We report the first detection of doubly-deuterated methyl formate CHD2OCHO in the ISM. The D/H ratio of CHD2OCHO is found to be 2-3 times higher than the D/H ratio of CH2DOCHO for both sources, similar to the results for formaldehyde from the same dataset. The observations are compared to a gas-grain chemical network coupled to a dynamical physical model, tracing the evolution of a molecular cloud until the end of the Class 0 protostellar stage. The overall D/H ratio enhancements found in the observations are of the same order of magnitude as the predictions from the model for the early stages of Class 0 protostars. However, the higher D/H ratio of CHD2OCHO compared to the D/H ratio of CH2DOCHO is still not predicted by the model. This suggests that a mechanism is enhancing the D/H ratio of singly- and doubly-deuterated methyl formate that is not in the model, e.g. mechanisms for H-D substitutions.

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