arXiv subjects

A. F. Kemper

Publications and source records attributed to A. F. Kemper.

At least 19 recordsLinked to original sources

arXiv2026

Efficient Quantum Implementation of Dynamical Mean Field Theory for Correlated Materials

The accurate theoretical description of materials with strongly correlated electrons is a formidable challenge in condensed matter physics and computational chemistry. Dynamical Mean Field Theory (DMFT) is a successful approach that predicts behaviors of such systems by incorporating some of the correlated behavior using an impurity model, but it is limited by the need to calculate the impurity Green's function. This work proposes a framework for DMFT calculations on quantum computers, focusing on near-term applications. It leverages the structure of the impurity problem, combining a low-rank Gaussian subspace representation of the ground state and a compressed, short-depth quantum circuit that joins state preparation with time evolution to compute Green's functions. We demonstrate the convergence of the DMFT algorithm using the Gaussian subspace in a noise-free setting, and show the hardware viability of circuit compression by extracting the impurity Green's function on IBM quantum processors for a single impurity coupled to three bath orbitals (8 qubits, 1 ancilla). We discuss potential paths toward realizing this quantum computing use case in materials science.

quant-ph↗

arXiv2026

CaRBM: A Fixed-Depth Quantum Algorithm with Partial Correction for Thermal State Preparation

We introduce the CaRBM algorithm for fixed-depth thermal state preparation. Our algorithm is based on thermal state purification and uses the Restricted Boltzmann Machine (RBM) block-encoding scheme to implement the imaginary-time propagator $e^{-βH}$, which is implemented in the quantum circuit in a fixed-depth manner via Cartan decomposition. Our algorithm performs best at high temperatures, with the success probability of the block encoding decreasing as the temperature decreases. To increase the success probability, we have devised a correction scheme for the block-encoding that increases the temperature range our algorithm reliably probes. We demonstrate our algorithm by calculating the partition function zeros of the XXZ model and the phase diagram of the Gross-Neveu model, which is a model of strongly interacting relativistic fermions.

quant-ph↗

arXiv2025

Classical reservoir approach for efficient molecular ground state preparation

Ground state preparation is a central application of quantum algorithms for electronic structure. We introduce the classical reservoir approach, a low cost variational ansatz tailored to near-term hardware, requiring only nearest-neighbor interactions on a machine with square-lattice connectivity. Unlike traditional methods built from the classically efficient Hartree Fock theory, our ansatz operates in localized molecular orbitals to study previously unexplored regions of the variational parameter space. Numerical benchmarks demonstrate chemical accuracy across diverse systems and bond lengths; notably, significantly reduced circuit depths are attainable when relaxed error thresholds (e.g., tens of E_h) are permissible. We benchmark the method on hydrogen chains, N_2, O_2, CO, BeH_2, and H_2O, the latter corresponding to an effective 24 qubit calculation.

quant-ph↗

arXiv2025

RedCarD: A Quantum Assisted Algorithm for Fixed-Depth Unitary Synthesis via Cartan Decomposition

A critical step in developing circuits for quantum simulation is to synthesize a desired unitary operator using the circuit building blocks. Studying unitaries and their generators from the Lie algebraic perspective has given rise to several algorithms for synthesis based on a Cartan decomposition of the dynamical Lie algebra. For unitaries of the form $e^{-itH}$, such as time-independent Hamiltonian simulation, the resulting circuits have depth that does not depend on simulation time $t$. However, finding such circuits has a large classical overhead in the cost function evaluation and the high dimensional optimization problem. In this work, by further partitioning the dynamical Lie algebra, we break down the optimization problem into smaller independent subproblems. Moreover, the resulting algebraic structure allows us to easily shift the evaluation of the cost function to the quantum computer, further cutting the classical overhead of the algorithm. As an application of the new hybrid algorithm, we synthesize the time evolution unitary for the 4-site transverse field Ising model on several IBM devices and Quantinuum's H1-1 quantum computer.

quant-ph↗

arXiv2025

Hybrid continuous-discrete-variable quantum computing: a guide to utility

Quantum computing has traditionally centered around the discrete variable paradigm. A new direction is the inclusion of continuous variable modes and the consideration of a hybrid continuous-discrete approach to quantum computing. In this paper, we discuss some of the advantages of this modality, and lay out a number of potential applications that can make use of it; these include applications from physics, chemistry, and computer science. We also briefly overview some of the algorithmic and software considerations for this new paradigm.

quant-ph↗

arXiv2025

Probing Bound State Relaxation Dynamics in Systems Out-of-Equilibrium on Quantum Computers

Pump-probe spectroscopy is a powerful tool for probing response dynamics of quantum many-body systems in and out-of-equilibrium. Quantum computers have proved useful in simulating such experiments by exciting the system, evolving, and then measuring observables to first order, all in one setting. Here, we use this approach to investigate the mixed-field Ising model, where the longitudinal field plays the role of a confining potential that prohibits the spread of the excitations, spinons, or domain walls into space. We study the discrete bound states that arise from such a setting and their evolution under different quench dynamics by initially pumping the chain out of equilibrium and then probing various non-equal time correlation functions. Finally, we study false vacuum decay, where initially one expects unhindered propagation of the ground state, or true vacuum, bubbles into the lattice, but instead sees the emergence of Bloch oscillations that are directly the reason for the long-lived oscillations in this finite-size model. Our work sets the stage for simulating systems out-of-equilibrium on classical and quantum computers using pump-probe experiments without needing ancillary qubits.

quant-ph↗

arXiv2025

Hidden local adiabatic ramp in the modulated time evolution and the quantum approximate optimization algorithm

Adiabatic state preparation provides an analytical solution for generating the ground state of a target Hamiltonian, starting from an easily prepared ground state of the initial Hamiltonian. While effective for time-dependent Hamiltonians with an energy gap to the first coupled excited state, the process becomes exceedingly slow as the gap narrows. Rather than strictly following the adiabatic theorem, a more robust approach allows controlled diabatic excitations during the evolution and numerically optimizes the path to eliminate these excitations by the end. In this work, this is achieved via modulated time evolution, using a time dependent oscillating field lambda(t) to modulate the Hamiltonian, in conjunction with a transverse field B(t) whose optimized shape closely resembles a local adiabatic ramp. Beyond modulated time evolution, the quantum approximate optimization algorithm (QAOA), which also employs a transverse field defined as beta(t) over gamma(t), exhibits a shape similar to the local adiabatic ramp. This resemblance offers a more intuitive and physically motivated way to understand the QAOA algorithm through the lens of time evolution.

quant-ph↗

arXiv2025

Efficient Fermi-Hubbard model ground-state preparation by coupling to a classical reservoir in the instantaneous-response limit

Preparing the ground state of the Fermi-Hubbard model is challenging, in part due to the exponentially large Hilbert space, which complicates efficiently finding a path from an initial state to the ground state using the variational principle. In this work, we propose an approach for ground state preparation of interacting models by involving a classical reservoir, simplified to the instantaneous-response limit, which can be described using a Hamiltonian formalism. The resulting time evolution operator consist of spin-adapted nearest-neighbor hopping and on-site interaction terms similar to those in the Hubbard model, without expanding the Hilbert space. We can engineer the coupling to rapidly drive the system from an initial product state to its interacting ground state by numerically minimizing the final state energy. This ansatz closely resembles the Hamiltonian variational ansatz, offering a fresh perspective on it.

quant-ph↗

arXiv2025

Algebraic Compression of Free Fermionic Quantum Circuits: Particle Creation, Arbitrary Lattices and Controlled Evolution

Recently we developed a local and constructive algorithm based on Lie algebraic methods for compressing Trotterized evolution under Hamiltonians that can be mapped to free fermions. The compression algorithm yields a circuit which scales linearly in the number of qubits, has a depth independent of evolution time and compresses time-dependent Hamiltonians. The algorithm is limited to simple nearest-neighbor spin interactions and fermionic hopping. In this work, we extend our methods to compress evolution with long-range fermionic hopping, thereby enabling the embedding of arbitrary lattices onto a chain of qubits for fermion models. Moreover, we show that controlled time evolution, as well as fermion creation and annihilation operators can also be compressed. We demonstrate our results by adiabatically preparing the ground state for a half-filled fermionic chain, simulating a $4 \times 4$ tight binding model on ibmq washington, and calculating the topological Zak phase on a Quantinuum H1-1 trapped-ion quantum computer. With these new developments, our results enable the simulation of a wider range of models of interest and the efficient compression of subcircuits.

quant-ph↗

arXiv2025

Observing two-electron interactions with correlation-ARPES

Identifying and studying the underlying two-electron interactions that give rise to emergent phenomena is a key step in developing a holistic understanding of quantum materials. This step is hindered by the lack of an experiment that can directly interrogate the interactions and the specific quasiparticles involved in the interaction simultaneously. We introduce correlation-ARPES (C-ARPES) as a new experimental method that overcomes this difficulty and directly measures the interactions between specific, chosen quasiparticles by measuring the correlations between two electrons photoemitted from the same pulse (but not the same photon). We illustrate how this technique can extract the underlying interactions, and demonstrate this with an example of phonon-mediated electron-electron interactions, such as those that give rise to charge density waves through the Kohn anomaly mechanism.

cond-mat.str-el↗

arXiv2025

Cheaper and more noise-resilient quantum state preparation using eigenvector continuation

Subspace methods are powerful, noise-resilient methods that can effectively prepare ground states on quantum computers. The challenge is to get a subspace with a small condition number that spans the states of interest using minimal quantum resources. In this work, we will use eigenvector continuation (EC) to build a subspace from the low-lying states of a set of Hamiltonians. The basis vectors are prepared using truncated versions of standard state preparation methods such as imaginary time evolution (ITE), adiabatic state preparation (ASP), and variational quantum eigensolver (VQE). By using these truncated methods combined with eigenvector continuation, we can directly improve upon them, obtaining more accurate ground state energies at a reduced cost. We use several spin systems to demonstrate convergence even when methods like ITE and ASP fail, such as ASP in the presence of level crossings and ITE with vanishing energy gaps. We also showcase the noise resilience of this approach beyond the gains already made by having shallower quantum circuits. Our findings suggest that eigenvector continuation can be used to improve existing state preparation methods in the near term.

quant-ph↗

arXiv2024

Robust measurements of $n$-point correlation functions of driven-dissipative quantum systems on a digital quantum computer

We propose and demonstrate a unified hierarchical method to measure $n$-point correlation functions that can be applied to driven, dissipative, or otherwise open or non-equilibrium quantum systems. In this method, the time evolution of the system is repeatedly interrupted by interacting an ancilla qubit with the system through a controlled operation, and measuring the ancilla immediately afterwards. We discuss the robustness of this method as compared to other ancilla-based interferometric techniques (such as the Hadamard test), and highlight its advantages for near-term quantum simulations of open quantum systems. We implement the method on a quantum computer in order to measure single-particle Green's functions of a driven-dissipative fermionic system. This work shows that dynamical correlation functions for driven-dissipative systems can be robustly measured with near-term quantum computers.

quant-ph↗

arXiv2023

Robust measurement of wave function topology on NISQ quantum computers

Topological quantum phases of quantum materials are defined through their topological invariants. These topological invariants are quantities that characterize the global geometrical properties of the quantum wave functions and thus are immune to local noise. Here, we present a strategy to measure topological invariants on quantum computers. We show that our strategy can be easily integrated with the variational quantum eigensolver (VQE) so that the topological properties of generic quantum many-body states can be characterized on current quantum hardware. We demonstrate the robust nature of the method by measuring topological invariants for both non-interacting and interacting models, and map out interacting quantum phase diagrams on quantum simulators and IBM quantum hardware.

quant-ph↗

arXiv2023

Low-energy quasi-circular electron correlations with charge order wavelength in $\textrm{Bi}_2\textrm{Sr}_2\textrm{Ca}\textrm{Cu}_2\textrm{O}_{8+δ}$

In the study of dynamic charge order correlations in the cuprates, most high energy-resolution resonant inelastic x-ray scattering (RIXS) measurements have focused on momenta along the high-symmetry directions of the copper oxide plane. However, electron scattering along other in-plane directions should not be neglected as they may contain information relevant, for example, to the origin of charge order correlations or to our understanding of the isotropic scattering responsible for strange metal behavior in cuprates. We report high-resolution resonant inelastic x-ray scattering (RIXS) experiments that reveal the presence of dynamic electron correlations over the $q_x$-$q_y$ scattering plane in underdoped $\textrm{Bi}_2\textrm{Sr}_2\textrm{Ca}\textrm{Cu}_2\textrm{O}_{8+δ}$ with $T_c=54$ K. We use the softening of the RIXS-measured bond stretching phonon line as a marker for the presence of charge-order-related dynamic electron correlations. The experiments show that these dynamic correlations exist at energies below approximately $70$ meV and are centered around a quasi-circular manifold in the $q_x$-$q_y$ scattering plane with radius equal to the magnitude of the charge order wave vector, $q_{CO}$. We also demonstrate how this phonon-tracking procedure provides the necessary experimental precision to rule out fluctuations of short-range directional charge order (i.e. centered around $[q_x=\pm q_{CO}, q_y=0]$ and $[q_x=0, q_y=\pm q_{CO}]$) as the origin of the observed correlations.

cond-mat.str-el↗

arXiv2022

Subspace Diagonalization on Quantum Computers using Eigenvector Continuation

Quantum subspace diagonalization (QSD) methods are quantum-classical hybrid methods, commonly used to find ground and excited state energies by projecting the Hamiltonian to a smaller subspace. In applying these, the choice of subspace basis is critical from the perspectives of basis completeness and efficiency of implementation on quantum computers. In this work, we present Eigenvector Continuation (EC) as a QSD method, where low-energy states of the Hamiltonian at different points in parameter space are chosen as the subspace basis. This unique choice enables rapid evaluation of low-energy spectra, including ground and nearby excited states, with minimal hardware effort. As a particular advantage, EC is able to capture the spectrum across ground state crossovers corresponding to different symmetry sectors of the problem. We demonstrate this method for interacting spin models and molecules.

quant-ph↗

arXiv2022

Enhanced charge density wave coherence in a light-quenched, high-temperature superconductor

Superconductivity and charge density waves (CDW) are competitive, yet coexisting orders in cuprate superconductors. To understand their microscopic interdependence, a probe capable of discerning their interaction on its natural length and time scales is necessary. We use ultrafast resonant soft x-ray scattering to track the transient evolution of CDW correlations in YBa$_{2}$Cu$_{3}$O$_{6+x}$ following the quench of superconductivity by an infrared laser pulse. We observe a non-thermal response of the CDW order characterized by a near doubling of the correlation length within $\approx$ 1 picosecond of the superconducting quench. Our results are consistent with a model in which the interaction between superconductivity and CDW manifests inhomogeneously through disruption of spatial coherence, with superconductivity playing the dominant role in stabilizing CDW topological defects, such as discommensurations.

cond-mat.supr-con↗

arXiv2021

Relaxation timescales and electron-phonon coupling in optically-pumped YBa$_2$Cu$_3$O$_{6+x}$ revealed by time-resolved Raman scattering

Time resolved measurements provide a new way to disentangle complex interactions in quantum materials due to their different timescales. We used pump-probe Raman scattering to investigate the apical oxygen vibration in YBa$_2$Cu$_3$O$_{6+x}$ under nonequilibrium conditions. Time-dependence of the phonon population demonstrated strong electron-phonon coupling. Most importantly, the phonon shifts to a higher energy due to transient smearing of the Fermi surface in a remarkable agreement with diagrammatic theory. We also discuss new insights into photoinduced superconductivity reported at lower doping that follow from these results.

cond-mat.supr-con↗

arXiv2021

Quantum fluctuations of charge order induce phonon softening in a superconducting cuprate

Quantum phase transitions play an important role in shaping the phase diagram of high-temperature cuprate superconductors. These cuprates possess intertwined orders which interact strongly with superconductivity. However, the evidence for the quantum critical point associated with the charge order in the superconducting phase remains elusive. Here we show the short-range charge orders and the spectral signature of the quantum fluctuations in La$_{2-x}$Sr$_x$CuO$_4$ (LSCO) near the optimal doping using high-resolution resonant inelastic X-ray scattering. On performing calculations through a diagrammatic framework, we discovered that the charge correlations significantly soften several branches of phonons. These results elucidate the role of charge order in the LSCO compound, providing evidence for quantum critical scaling and discommensurations associated with charge order.

cond-mat.supr-con↗