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A. G. G. M. Tielens

Publications and source records attributed to A. G. G. M. Tielens.

At least 55 records · Page 3Linked to original sources

Tracing PAH Size in Prominent Nearby Mid-Infrared Environments

We present observations from the First Light Infrared TEst CAMera (FLITECAM) on board the Stratospheric Observatory for Infrared Astronomy (SOFIA), the Spitzer Infrared Array Camera (IRAC) and the Spitzer Infrared Spectrograph (IRS) SH mode in three well-known Photodissocation Regions (PDRs), the reflection nebulae (RNe) NGC 7023 and NGC 2023 and to the southeast of the Orion Bar, which are well suited to probe emission from Polycyclic Aromatic Hydrocarbon molecules (PAHs). We investigate the spatial behaviour of the FLITECAM 3.3 um filter as a proxy for the 3.3 um PAH band, the integrated 11.2 um PAH band, and the IRAC 8.0 um filter as a proxy for the sum of the 7.7 and 8.6 um PAH bands. The resulting ratios of 11.2/3.3 and IRAC 8.0/11.2 provide an approximate measure of the average PAH size and PAH ionization respectively. In both RNe, we find that the relative PAH ionization and the average PAH size increases with decreasing distance to the illuminating source. The average PAH sizes derived for NGC 2023 are greater than those found for NGC 7023 at all points. Both results indicate that PAH size is dependent on the radiation field intensity. These results provide additional evidence of a rich carbon-based chemistry driven by the photo-chemical evolution of the omnipresent PAH molecules within the interstellar medium. In contrast, we did not detect a significant variation in the average PAH size found in the region southeast of the Orion Bar and report a peculiar PAH ionization radial profile.

astro-ph.GA↗

[CII] $158\,μ\mathrm{m}$ line emission from Orion A. I. A template for extragalactic studies?

The [CII] $158\,μ\mathrm{m}$ fine-structure line is one of the dominant coolants of the neutral interstellar medium. It is hence one of the brightest far-infrared emission lines and can be observed not only in star-forming regions throughout the Galaxy, but also in the diffuse interstellar medium and in distant galaxies. [CII] line emission has been suggested to be a powerful tracer of star-formation. We aim to understand the origin of [CII] emission and its relation to other tracers of interstellar gas and dust. This includes a study of the heating efficiency of interstellar gas as traced by the [CII] line to test models of gas heating. We make use of a one-square-degree map of velocity-resolved [CII] line emission towards the Orion Nebula complex, including M43 and NGC 1977. The [CII] intensity is tightly correlated with PAH emission in the IRAC $8\,μ\mathrm{m}$ band and far-infrared emission from warm dust. The correlation between [CII] and CO(2-1) is affected by the detailed geometry of the region. We find particularly low [CII]-over-FIR intensity ratios towards large columns of (warm and cold) dust, which suggest the interpretation of the "[CII] deficit" in terms of a "FIR excess". A slight decrease in the FIR line-over-continuum intensity ratio can be attributed to a decreased heating efficiency of the gas. We find that, at the mapped spatial scales, predictions of the star-formation rate from [CII] emission underestimate the star-formation rate calculated from YSO counts in the Orion Nebula complex by an order of magnitude. [CII] emission from the Orion Nebula complex arises dominantly in the cloud surfaces, many viewed in edge-on geometry. [CII] emission from extended faint cloud surfaces may contribute significantly to the total [CII] emission on galactic scales.

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SOFIA FEEDBACK survey: exploring the dynamics of the stellar wind driven shell of RCW 49

We unveil the stellar wind driven shell of the luminous massive star-forming region of RCW 49 using SOFIA FEEDBACK observations of the [CII] 158 $μ$m line. The complementary dataset of the $^{12}$CO and $^{13}$CO J = 3 - 2 transitions is observed by the APEX telescope and probes the dense gas toward RCW 49. Using the spatial and spectral resolution provided by the SOFIA and APEX telescopes, we disentangle the shell from a complex set of individual components of gas centered around RCW 49. We find that the shell of radius ~ 6 pc is expanding at a velocity of 13 km s$^{-1}$ toward the observer. Comparing our observed data with the ancillary data at X-Ray, infrared, sub-millimeter and radio wavelengths, we investigate the morphology of the region. The shell has a well defined eastern arc, while the western side is blown open and is venting plasma further into the west. Though the stellar cluster, which is ~ 2 Myr old gave rise to the shell, it only gained momentum relatively recently as we calculate the shell's expansion lifetime ~ 0.27 Myr, making the Wolf-Rayet star WR20a a likely candidate responsible for the shell's re-acceleration.

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IR photofragmentation of the Phenyl Cation: Spectroscopy and Fragmentation Pathways

We present the gas-phase infrared spectra of the phenyl cation, phenylium, in its perprotio C$_6$H$_5^+$ and perdeutero C$_6$D$_5^+$ forms, in the 260-1925 cm$^{-1}$ (5.2-38 $μ$m) spectral range, and investigate the observed photofragmentation. The spectral and fragmentation data were obtained using Infrared Multiple Photon Dissociation (IRMPD) spectroscopy within a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FTICR MS) located inside the cavity of the free electron laser FELICE (Free Electron Laser for Intra-Cavity Experiments). The $^1$A$_1$ singlet nature of the phenylium ion is ascertained by comparison of the observed IR spectrum with DFT calculations, using both harmonic and anharmonic frequency calculations. To investigate the observed loss of predominantly [2C,nH] (n=2-4) fragments, we explored the potential energy surface (PES) to unravel possible isomerization and fragmentation reaction pathways. The lowest energy pathways toward fragmentation include direct H elimination, and a combination of facile ring-opening mechanisms ($\leq2.4$ eV), followed by elimination of H or CCH$_2$. Energetically, all H-loss channels found are more easily accessible than CCH$_2$-loss. Calculations of the vibrational density of states for the various intermediates show that at high internal energies, ring opening is the thermodynamically the most advantageous, eliminating direct H-loss as a competing process. The observed loss of primarily [2C,2H] can be explained through entropy calculations that show favored loss of [2C,2H] at higher internal energies.

physics.chem-ph↗

FEEDBACK: a SOFIA Legacy Program to Study Stellar Feedback in Regions of Massive Star Formation

FEEDBACK is a SOFIA legacy program dedicated to study the interaction of massive stars with their environment. It performs a survey of 11 galactic high mass star forming regions in the 158 $μ$m (1.9 THz) line of CII and the 63 $μ$m (4.7 THz) line of OI. We employ the 14 pixel LFA and 7 pixel HFA upGREAT instrument to spectrally resolve (0.24 MHz) these FIR structure lines. With an observing time of 96h, we will cover $\sim$6700 arcmin$^2$ at 14.1$''$ angular resolution for the CII line and 6.3$''$ for the OI line. The observations started in spring 2019 (Cycle 7). Our aim is to understand the dynamics in regions dominated by different feedback processes from massive stars such as stellar winds, thermal expansion, and radiation pressure, and to quantify the mechanical energy injection and radiative heating efficiency. The CII line provides the kinematics of the gas and is one of the dominant cooling lines of gas for low to moderate densities and UV fields. The OI line traces warm and high-density gas, excited in photodissociations regions with a strong UV field or by shocks. The source sample spans a broad range in stellar characteristics from single OB stars, to small groups of O stars, to rich young stellar clusters, to ministarburst complexes. It contains well-known targets such as Aquila, the Cygnus X region, M16, M17, NGC7538, NGC6334, Vela, and W43 as well as a selection of HII region bubbles, namely RCW49, RCW79, and RCW120. These CII maps, together with the less explored OI 63 $μ$m line, provide an outstanding database for the community. They will be made publically available and will trigger further studies and follow-up observations.

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Expanding bubbles in Orion A: [CII] observations of M42, M43, and NGC 1977

The Orion Molecular Cloud is the nearest massive-star forming region. Massive stars have profound effects on their environment due to their strong radiation fields and stellar winds. Velocity-resolved observations of the [CII] $158\,μ\mathrm{m}$ fine-structure line allow us to study the kinematics of UV-illuminated gas. Here, we present a square-degree-sized map of [CII] emission from the Orion Nebula complex obtained by the upGREAT instrument onboard SOFIA, covering the entire Orion Nebula (M42) plus M43 and the nebulae NGC 1973, 1975, and 1977. We compare the stellar characteristics of these three regions with the kinematics of the expanding bubbles surrounding them. The bubble blown by the O7V star $θ^1$ Ori C in the Orion Nebula expands rapidly, at $13\,\mathrm{km\,s^{-1}}$. Simple analytical models reproduce the characteristics of the hot interior gas and the neutral shell of this wind-blown bubble and give us an estimate of the expansion time of $0.2\,\mathrm{Myr}$. M43 with the B0.5V star NU Ori also exhibits an expanding bubble structure, with an expansion velocity of $6\,\mathrm{km\,s^{-1}}$. Comparison with analytical models for the pressure-driven expansion of H\,{\sc ii} regions gives an age estimate of $0.02\,\mathrm{Myr}$. The bubble surrounding NGC 1973, 1975, and 1977 with the central B1V star 42 Orionis expands at $1.5\,\mathrm{km\,s^{-1}}$, likely due to the over-pressurized ionized gas as in the case of M43. We derive an age of $0.4\,\mathrm{Myr}$ for this structure. We conclude that the bubble of the Orion Nebula is driven by the mechanical energy input by the strong stellar wind from $θ^1$ Ori C, while the bubbles associated with M43 and NGC 1977 are caused by the thermal expansion of the gas ionized by their central later-type massive stars.

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Molecular globules in the Veil bubble of Orion. IRAM 30m 12CO, 13CO, and C18O 2-1 expanded maps of Orion A

Strong winds and ultraviolet (UV) radiation from O-type stars disrupt and ionize their molecular core birthplaces, sweeping up material into parsec-size shells. Owing to dissociation by starlight, the thinnest shells are expected to host low molecular abundances and therefore little star formation. Here, we expand previous maps taken with the IRAM 30m telescope and present square-degree 12CO and 13CO (J=2-1) maps of the wind-driven "Veil bubble'' that surrounds the Trapezium cluster and its natal Orion molecular core (OMC). Although widespread and extended CO emission is largely absent from the Veil, we show that several CO "globules'' exist and are embedded in the [CII]158um-bright shell that confines the bubble. This includes the first detection of quiescent CO at negative LSR velocities in Orion. Given the harsh UV irradiation conditions in this translucent material, the detection of CO globules is surprising. These globules are small (R=7,100 AU), not massive (M=0.3M_Sun), and are moderately dense: n_ H=4x10^4 cm^-3 (median values). They are confined by the external pressure of the shell, P_ext/k~10^7 cm^-3 K, and are likely magnetically supported. They are either transient objects formed by instabilities or have detached from pre-existing molecular structures, sculpted by the passing shock associated with the expanding shell and by UV radiation from the Trapezium. Some represent the first stages in the formation of small pillars, others of isolated small globules. Although their masses do not suggest they will form stars, one globule matches the position of a known YSO. The lack of extended CO in the "Veil shell'' demonstrates that feedback from massive stars expels, agitates, and reprocesses most of the disrupted molecular cloud gas, thereby limiting the star-formation rate in the region. The presence of globules is a result of this feedback.

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The H$_2$O Spectrum of the Massive Protostar AFGL 2136 IRS 1 from 2 to 13 $μ$m at High Resolution: Probing the Circumstellar Disk

We have observed the massive protostar AFGL 2136 IRS 1 in multiple wavelength windows in the near-to-mid-infrared at high ($\sim3$ km s$^{-1}$) spectral resolution using VLT+CRIRES, SOFIA+EXES, and Gemini North+TEXES. There is an abundance of H$_2$O absorption lines from the $ν_1$ and $ν_3$ vibrational bands at 2.7 $μ$m, from the $ν_2$ vibrational band at 6.1 $μ$m, and from pure rotational transitions near 10-13 $μ$m. Analysis of state-specific column densities derived from the resolved absorption features reveals that an isothermal absorbing slab model is incapable of explaining the relative depths of different absorption features. In particular, the strongest absorption features are much weaker than expected, indicating optical depth effects resulting from the absorbing gas being well-mixed with the warm dust that serves as the "background" continuum source at all observed wavelengths. The velocity at which the strongest H$_2$O absorption occurs coincides with the velocity centroid along the minor axis of the compact disk in Keplerian rotation recently observed in H$_2$O emission with ALMA. We postulate that the warm regions of this dust disk dominate the continuum emission at near-to-mid infrared wavelengths, and that H$_2$O and several other molecules observed in absorption are probing this disk. Absorption line profiles are not symmetric, possibly indicating that the warm dust in the disk that produces the infrared continuum has a non-uniform distribution similar to the substructure observed in 1.3 mm continuum emission.

astro-ph.SR↗

Breakdown products of gaseous polycyclic aromatic hydrocarbons investigated with infrared ion spectroscopy

We report on a common fragment ion formed during the electron-ionization-induced fragmentation of three different three-ring polycyclic aromatic hydrocarbons (PAHs), fluorene (C$_{13}$H$_{10}$), 9,10-dihydrophenanthrene (C$_{14}$H$_{12}$), and 9,10-dihydroanthracene (C$_{14}$H$_{12}$). The infrared spectra of the mass-isolated product ions with $m/z=165$ were obtained in a Fourier transform ion cyclotron resonance mass spectrometer whose cell was placed inside the optical cavity of an infrared free-electron laser, thus providing the high photon fluence required for efficient infrared multiple-photon dissociation. The infrared spectra of the $m/z=165$ species generated from the three different precursors were found to be similar, suggesting the formation of a single C$_{13}$H$_{9}^+$ isomer. Theoretical calculations using density functional theory (DFT) revealed the fragment's identity as the closed-shell fluorenyl cation. Decomposition pathways from each parent precursor to the fluorenyl ion are proposed on the basis of DFT calculations. The identification of a single fragmentation product from three different PAHs supports the notion of the existence of common decomposition pathways of PAHs in general and can aid in understanding the fragmentation chemistry of astronomical PAH species.

astro-ph.GA↗

Impact of X-rays on CO emission from high-z galaxies

We study the impact of active galactic nuclei (AGN) on the CO Spectral Line Energy Distribution (SLED) of high-$z$ galaxies. In particular, we want to assess if the CO SLED can be used as a probe of AGN activity. To this purpose, we develop a semi-analytical model that takes into account the radiative transfer and the clumpy structure of giant molecular clouds where the CO lines are excited, their distribution in the galaxy disk, and the torus obscuration of the AGN radiation. We study the joint effect on the CO SLED excitation of (i) the X-ray luminosity from the AGN ($L_{X}$), (ii) the size of the molecular disk, (iii) the inclination angle ($Ω$) of the torus with respect to the molecular disk, and (iv) the GMC mean density. We also discuss the possibility of an enhanced Cosmic Ray Ionization Rate (CRIR). We find that the X-ray Dominated Region (XDR) generated by the AGN in every case enhances the CO SLED for $J>5$, with increasing excitation of high-$J$ CO lines for increasing X-ray luminosity. Because high-$z$ galaxies are compact, the XDR region typically encloses the whole disk, thus its effect can be more important with respect to lower redshift objects. The impact of the XDR can be disentangled from an enhanced CRIR either if $L_X>10^{44} \rm \,erg\, s^{-1}$, or if $Ω\geq 60^{\circ}$. We finally provide predictions on the CO(7-6)/[CII] and CO(17-16)/[CII] ratios as a function of $L_X$, which can be relevant for ALMA follow up of galaxies and quasars previously detected in [CII].

astro-ph.GA↗

Searching for the largest bound atoms in space

(abridged) Radio recombination lines (RRLs) at frequencies $ν$ < 250 MHz trace the cold, diffuse phase of the ISM. Next generation low frequency interferometers, such as LOFAR, MWA and the future SKA, with unprecedented sensitivity, resolution, and large fractional bandwidths, are enabling the exploration of the extragalactic RRL universe. We observed the radio quasar 3C 190 (z~1.2) with the LOFAR HBA. In reducing this data for spectroscopic analysis, we have placed special emphasis on bandpass calibration. We devised cross-correlation techniques to significantly identify the presence of RRLs in a low frequency spectrum. We demonstrate the utility of this method by applying it to existing low-frequency spectra of Cassiopeia A and M 82, and to the new observations of 3C 190. RRLs have been detected in the foreground of 3C 190 at z = 1.12355 (assuming a carbon origin), owing to the first detection of RRLs outside of the local universe (first reported in Emig et al. 2019). Towards the Galactic supernova remnant Cas A, we uncover three new detections: (1) C$ε$-transitions ($Δ$n = 5) for the first time at low radio frequencies, (2) H$α$-transitions at 64 MHz with a FWHM of 3.1 km/s, the most narrow and one of the lowest frequency detections of hydrogen to date, and (3) C$α$ at v$_{LSR}$ = 0 km/s in the frequency range 55-78 MHz for the first time. Additionally we recover C$α$, C$β$, C$γ$, and C$δ$ from the -47 km/s and -38 km/s components. In the nearby starburst galaxy, M 82, we do not find a significant feature. Our current searches for RRLs in LOFAR observations are limited to narrow (< 100 km/s) features, owing to the relatively small number of channels available for continuum estimation. Future strategies making use of larger contiguous frequency coverage would aid calibration to deeper sensitivities and broader features.

astro-ph.IM↗

Origin of hydrogen fluoride emission in the Orion Bar: An excellent tracer for CO-dark H2 gas clouds

The hydrogen fluoride (HF) molecule is seen in absorption in the interstellar medium (ISM) along many lines of sight. Surprisingly, it is observed in emission toward the Orion Bar, which is an interface between the ionized region around the Orion Trapezium stars and the Orion molecular cloud. We aim to understand the origin of HF emission in the Orion Bar by comparing its spatial distribution with other tracers. We examine three mechanisms to explain the HF emission: thermal excitation, radiative dust pumping, and chemical pumping. We used a Herschel/HIFI strip map of the HF J = 1-0 line, covering 0.5' by 1.5' that is oriented perpendicular to the Orion Bar. We used the RADEX non-local thermodynamic equilibrium (non-LTE) code to construct the HF column density map. We use the Meudon PDR code to explain the morphology of HF. The bulk of the HF emission at 10 km s^-1 emerges from the CO-dark molecular gas that separates the ionization front from the molecular gas that is deeper in the Orion Bar. The excitation of HF is caused mainly by collisions with H2 at a density of 10^5 cm^-3 together with a small contribution of electrons in the interclump gas of the Orion Bar. Infrared pumping and chemical pumping are not important. We conclude that the HF J = 1-0 line traces CO-dark molecular gas. Similarly, bright photodissociation regions associated with massive star formation may be responsible for the HF emission observed toward active galactic nuclei.

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The aromatic Universe

The rich molecular structures of polycyclic aromatic hydrocarbons -- essentially planar flakes of fused benzene rings -- and their fullerene cousins are revealed through their vibrational and electronic spectra.

astro-ph.GA↗

Anharmonicity in the mid-infrared spectra of polycyclic aromatic hydrocarbons: Molecular beam spectroscopy and calculations

Aims. In this work we determine the effects of anharmonicity on the mid-infrared spectra of the linear polycyclic aromatic hydrocarbons (PAHs) naphthalene, anthracene, tetracene and pentacene recorded using the free electron laser FELIX. Methods. Comparison of experimental spectra obtained under supersonic jet conditions with theoretically predicted spectra was used to show if anharmonicity explicitly needs to be taken into account. Results. Anharmonic spectra obtained using second-order vibrational perturbation theory agree on average within 0.5% of the experimental frequencies. Importantly, they confirm the presence of combination bands with appreciable intensity in the 5-6 $μ$m region. These combination bands contain a significant fraction of the IR absorption, which scales linearly with the size of the PAH. Detection and assignment of the combination bands are a preliminary indication of the accuracy of far-IR modes in our anharmonic theoretical spectra. Detailed analysis of the periphery-sensitive CH out-of-plane band of naphthalene reveals that there is still room for improvement of the VPT2 approach. In addition, the implications of our findings for the analysis of the aromatic infrared bands are discussed.

astro-ph.GA↗

X-ray extinction from interstellar dust: Prospects of observing carbon, sulfur and other trace elements

We present a study on the prospects of observing carbon, sulfur, and other lower abundance elements (namely Al, Ca, Ti and Ni) present in the interstellar medium using future X-ray instruments. We focus in particular on the detection and characterization of interstellar dust along the lines of sight. We compare the simulated data with different sets of dust aggregates, either obtained from past literature or measured by us using the SOLEIL-LUCIA synchrotron beamline. Extinction by interstellar grains induces modulations of a given photolelectric edge, which can be in principle traced back to the chemistry of the absorbing grains. We simulated data of instruments with characteristics of resolution and sensitivity of the current Athena, XRISM and Arcus concepts. In the relatively near future, the depletion and abundances of the elements under study will be determined with confidence. In the case of carbon and sulfur, the characterization of the chemistry of the absorbing dust will be also determined, depending on the dominant compound. For aluminum and calcium, despite the large depletion in the interstellar medium and the prominent dust absorption, in many cases the edge feature may not be changing significantly with the change of chemistry in the Al$^-$ or Ca$^-$ bearing compounds. The exinction signature of large grains may be detected and modeled, allowing a test on different grain size distributions for these elements. The low cosmic abundance of Ti and Ni will not allow us a detailed study of the edge features.

astro-ph.GA↗

Dust absorption and scattering in the silicon K-edge

The composition and properties of interstellar silicate dust are not well understood. In X-rays, interstellar dust can be studied in detail by making use of the fine structure features in the Si K-edge. The features in the Si K-edge offer a range of possibilities to study silicon-bearing dust, such as investigating the crystallinity, abundance, and the chemical composition along a given line of sight. We present newly acquired laboratory measurements of the silicon K-edge of several silicate-compounds that complement our measurements from our earlier pilot study. The resulting dust extinction profiles serve as templates for the interstellar extinction that we observe. The extinction profiles were used to model the interstellar dust in the dense environments of the Galaxy. The laboratory measurements, taken at the Soleil synchrotron facility in Paris, were adapted for astrophysical data analysis and implemented in the SPEX spectral fitting program. The models were used to fit the spectra of nine low-mass X-ray binaries located in the Galactic center neighborhood in order to determine the dust properties along those lines of sight. Most lines of sight can be fit well by amorphous olivine. We also established upper limits on the amount of crystalline material that the modeling allows. We obtained values of the total silicon abundance, silicon dust abundance, and depletion along each of the sightlines. We find a possible gradient of $0.06\pm0.02$ dex/kpc for the total silicon abundance versus the Galactocentric distance. We do not find a relation between the depletion and the extinction along the line of sight.

astro-ph.GA↗

Carbon radio recombination lines from gigahertz to megahertz frequencies towards Orion A

Context. The combined use of carbon radio recombination lines (CRRLs) and the 158 $μ$m-[CII] line is a powerful tool for the study of the energetics and physical conditions (e.g., temperature and density) of photodissociation regions (PDRs). However, there are few observational studies that exploit this synergy. Aims. Here we explore the relation between CRRLs and the 158 $μ$m-[CII] line in light of new observations and models. Methods. We present new and existing observations of CRRLs in the frequency range 0.15--230 GHz with ALMA, VLA, the GBT, Effelsberg 100m, and LOFAR towards Orion~A (M42). We complement these observations with SOFIA observations of the 158 $μ$m-[CII] line. We studied two PDRs: the foreground atomic gas, known as the Veil, and the dense PDR between the HII region and the background molecular cloud. Results. In the Veil we are able to determine the gas temperature and electron density, which we use to measure the ionization parameter and the photoelectric heating efficiency. In the dense PDR, we are able to identify a layered PDR structure at the surface of the molecular cloud to the south of the Trapezium cluster. There we find that the radio lines trace the colder portion of the ionized carbon layer, the C$^{+}$/C/CO interface. By modeling the emission of the $158$~$μ$m-[CII] line and CRRLs as arising from a PDR we derive a thermal pressure $>5\times10^{7}$ K cm$^{-3}$ and a radiation field $G_{0}\approx10^{5}$ close to the Trapezium. Conclusions. This work provides additional observational support for the use of CRRLs and the 158 $μ$m-[CII] line as complementary tools to study dense and diffuse PDRs, and highlights the usefulness of CRRLs as probes of the C$^{+}$/C/CO interface.

astro-ph.GA↗

Direct estimation of electron density in the Orion Bar PDR from mm-wave carbon recombination lines

A significant fraction of the molecular gas in star-forming regions is irradiated by stellar UV photons. In these environments, the electron density (n_e) plays a critical role in the gas dynamics, chemistry, and collisional excitation of certain molecules. We determine n_e in the prototypical strongly irradiated photodissociation region (PDR), the Orion Bar, from the detection of new millimeter-wave carbon recombination lines (mmCRLs) and existing far-IR [13CII] hyperfine line observations. We detect 12 mmCRLs (including alpha, beta, and gamma transitions) observed with the IRAM 30m telescope, at ~25'' angular resolution, toward the H/H2 dissociation front (DF) of the Bar. We also present a mmCRL emission cut across the PDR. These lines trace the C+/C/CO gas transition layer. As the much lower frequency carbon radio recombination lines, mmCRLs arise from neutral PDR gas and not from ionized gas in the adjacent HII region. This is readily seen from their narrow line profiles (dv=2.6+/-0.4 km/s) and line peak LSR velocities (v_LSR=+10.7+/-0.2 km/s). Optically thin [13CII] hyperfine lines and molecular lines - emitted close to the DF by trace species such as reactive ions CO+ and HOC+ - show the same line profiles. We use non-LTE excitation models of [13CII] and mmCRLs and derive n_e = 60-100 cm^-3 and T_e = 500-600 K toward the DF. The inferred electron densities are high, up to an order of magnitude higher than previously thought. They provide a lower limit to the gas thermal pressure at the PDR edge without using molecular tracers. We obtain P_th > (2-4)x10^8 cm^-3 K assuming that the electron abundance is equal or lower than the gas-phase elemental abundance of carbon. Such elevated thermal pressures leave little room for magnetic pressure support and agree with a scenario in which the PDR photoevaporates.

astro-ph.GA↗