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A. I. Karakas

Publications and source records attributed to A. I. Karakas.

At least 19 recordsLinked to original sources

Direct measurement of $^{18}$F($α,p$)$^{21}$Ne cross sections with ANASEN

The $^{18}$F($α,p$)$^{21}$Ne reaction may impact Asymptotic Giant Branch nucleosynthesis and helium burning on accreting white dwarfs. This reaction has never been directly measured, and constraints from a previous time-inverse measurement leave large uncertainties in the reaction rate. We measured $^{18}$F($α,p$)$^{21}$Ne cross sections directly for the first time covering from $2 \leq E_{cm} \leq 4$ MeV. Combining these results with previous work and comparisons to statistical model calculations results in a substantial improvement in uncertainties in the reaction rate. Cross sections were measured in inverse kinematics at TRIUMF-ISAC using a radioactive $^{18}$F beam and ANASEN with an extended $^{4}$He gas target. Protons were detected in arrays of silicon-strip detectors with the measured trajectories and energies allowing reconstruction of the center-of-mass energy and final state in $^{21}$Ne populated. We found the total cross section is in good agreement with statistical calculations, though population of the second excited state in $^{21}$Ne is greater than predicted. This direct measurement is combined with the previous time-inverse measurement and a new reaction rate is calculated for 0.1--3 GK. The uncertainties in the $^{18}$F($α,p$)$^{21}$Ne reaction rate have been reduced to a sufficient level to allow robust predictions from AGB models. The new recommended rate leads to a 45\% increase in $^{19}$F production compared to the previous rate.

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The complex stellar system M 22: confirming abundance variations with high precision differential measurements

M 22 (NGC 6656) is a chemically complex globular cluster-like system reported to harbour heavy element abundance variations. However, the extent of these variations and the origin of this cluster is still debated. In this work, we investigate the chemical inhomogeneity of M 22 using differential line-by-line analysis of high-quality (R = 110,000, S/N = 300 per pixel at 514 nm) VLT/UVES spectra of six carefully chosen red giant branch stars. By achieving abundance uncertainties as low as ~0.01 dex (~2 per cent), this high-precision data validates the results of previous studies and reveals variations in Fe, Na, Si, Ca, Sc, Ti, Cr, Mn, Co, Ni, Zn, Y, Zr, La, Ce, Nd, Sm and Eu. Additionally, we can confirm that the cluster hosts two stellar populations with a spread of at least 0.24 dex in [Fe/H] and an average s-process abundance spread of 0.65 dex. In addition to global variations across the cluster, we also find non-negligible variations within each of the two populations, with the more metal-poor population hosting larger spreads in elements heavier than Fe than the metal-rich. We address previous works which do not identify anomalous abundances and relate our findings to our current dynamical understanding of the cluster. Given our results, we suggest that M 22 is either a nuclear star cluster, the product of two merged clusters, or an original building block of the Milky Way.

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The complex stellar system M 22: constraining the chemical enrichment from AGB stars using magnesium isotope ratios

The complex star cluster M 22 (NGC 6656) provides a unique opportunity for studying slow neutron-capture (s-process) nucleosynthesis at low metallicity due to its two stellar groups with distinct iron-peak and neutron-capture element abundances. Previous studies attribute these abundance differences to pollution from 3-6 solar-mass asymptotic giant branch (AGB) stars, which produce significant quantities of the neutron-rich Mg isotopes 25Mg and 26Mg. We report the first-ever measurements of Mg isotopic abundance ratios at [Fe/H] approximately -2 in a globular-cluster-like system using very high-resolution and high signal-to-noise spectra (R = 110000, S/N = 300 per pixel at 514 nm) from the VLT/UVES spectrograph for six stars, three in each s-process group. Despite the presence of star-to-star variations in 24Mg, 25Mg, and 26Mg, we find no correlation with heavy-element abundances, implying that the nucleosynthetic source of s-process enrichment must not influence Mg isotope ratios. Instead, a key result of this work is that we identify correlations between 26Mg/24Mg and some light elements. Using a custom suite of AGB nucleosynthesis yields tailored to the metallicity of M 22, we find that low-mass AGB stars of approximately 1-3 solar masses are capable of reproducing the observed s-process abundances of M 22 and that the absence of any difference in Mg isotope ratios between the two s-process groups precludes AGBs with masses above approximately 3 solar masses. This places tighter constraints on possible formation scenarios and suggests an age difference of at least approximately 280-480 Myr between the two populations that is independent of isochrone fitting.

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Magnesium isotope ratios in Milky Way and dwarf galaxy stars

Under the assumption of hierarchical galaxy formation, dwarf galaxies are the closest existing analogues to the high-redshift protogalaxies that merged to form the Milky Way. These low-mass systems serve as unique laboratories for studying nucleosynthetic channels, given that the chemical compositions of their stars play a pivotal role in constraining their chemical enrichment history. To date, stellar abundances in dwarf galaxies have focused almost exclusively on elemental abundance ratios. While important, elemental abundances omit critical information about the isotopic composition. Here, we compute the Mg isotopic ratios of six accreted dwarf galaxy stars (low-alpha) and seven Milky Way stars (high-alpha) using a set of high-resolution (65000 < R < 160000) and high signal-to-noise ratio (S/N > 250) optical spectra. We show, for the first time, that at a given [Fe/H], stars born in a dwarf galaxy differ in their Mg isotopic ratios from stars born in the Milky Way. However, when comparing isotopic ratios at a given [Mg/H] rather than [Fe/H], a powerful diagnostic emerges that suggests nucleosynthesis processes are consistent across different stellar environments. This universality of Mg isotopic abundances provides additional dimensionality for chemical evolution models and helps to constrain massive-star nucleosynthesis across cosmic time.

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Constraining intrinsic S-type AGB masses and third dredge-up using pulsation

The lowest mass at which the third dredge-up (TDU) occurs for thermally-pulsing asymptotic giant branch (TP-AGB) stars remains a key uncertainty in detailed stellar models. S-type AGB stars are an important constraint on this uncertainty as they have C/O ratios between 0.5 and 1, meaning they have only experienced up to a few episodes of TDU. AGB stars are also long-period variable stars, pulsating in low order radial pulsation modes. In this paper we estimate the initial masses of a large literature sample of intrinsic S-type AGB stars, by analysing their visual light curves, estimating their luminosities with Gaia DR3 parallax distances and finally comparing to a grid of detailed stellar models combined with linear pulsation models. We find that the initial mass distribution of intrinsic S-type stars peaks at 1.3 to 1.4 \Msun, depending on model assumptions. There also appear to be stars with initial masses down to 1 solar mass, which is in conflict with current detailed stellar models. Additionally, we find that though the mass estimates for semiregular variable stars pulsating in higher order radial modes are precise, the Mira variables pulsating in the fundamental mode present challenges observationally from uncertain parallax distances, and theoretically from the onset of increased mass-loss and the necessity of non-linear pulsation models.

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Impact of $\textit{T}$- and $ρ$-dependent decay rates and new (n,$γ$) cross sections on the $\textit{s}$ process in low-mass AGB stars

We study the impact of nuclear input related to weak-decay rates and neutron-capture reactions on predictions for the $s$ process in AGB stars. We provide the first database of surface abundances and stellar yields of the isotopes heavier than iron from the $Monash$ models. We run nucleosynthesis calculations with the $Monash$ post-processing code for 7 stellar structure evolution models of low-mass AGB stars with 3 different sets of nuclear input. The reference set has constant decay rates and represents the set used in the previous $Monash$ publications. The second set contains the temperature and density dependence of $β$ decays and electron captures based on the default rates of NETGEN. In the third set, we update 92 neutron-capture rates based on reevaluated experimental cross sections from the ASTRAL. We compare and discuss the predictions of each set relative to each other in terms of isotopic surface abundances and total stellar yields. We also compare results to isotopic ratios measured in presolar stardust SiC grains from AGB stars. The new sets of models resulted in a $\sim$66% solar $s$-process contribution to the $p$-nucleus $\mathrm{^{152}Gd}$, confirming that this isotope is predominantly made by the $s$ process. The nuclear input updates resulted in predictions for the $\mathrm{^{80}Kr/^{82}Kr}$ ratio in the He intershell and surface $\mathrm{^{64}Ni/^{58}Ni}, \mathrm{^{94}Mo/^{96}Mo}$ and $\mathrm{^{137}Ba/^{136}Ba}$ ratios more consistent with the corresponding ratios measured in stardust, however, the new predicted $\mathrm{^{138}Ba/^{136}Ba}$ ratios are higher than the typical values of the stardust SiC grain data. The W isotopic anomalies are in agreement with data from analysis of other meteoritic inclusions. We confirm that the production of $\mathrm{^{176}Lu}$ and $\mathrm{^{205}Pb}$ is affected by too large uncertainties in their decay rates from NETGEN.

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The metallicity variations along the chromosome maps: The Globular Cluster 47 Tucanae

The "chromosome maps" (ChMs) of globular clusters (GCs) have revealed that these ancient structures are not homogeneous in metallicity in various ways, and in different natures. The Type II GCs generally display larger variations, sometimes coupled with slow neutron capture (s) element enrichment on the ChMs redder sequences, which has been interpreted as due to multiple generations of stars. On the other hand, most GCs have inhomogeneous first populations (1P) in the form of large ranges in the Delta(F275W,F814W) values, pointing towards a not fully mixed pristine molecular cloud. We analyse the chemical composition the GC 47 Tucanae, which shows both inhomogeneous 1P stars and, although not formally a Type II GC, hosts a small number of stars distributed on a red side of the main stream of ChM stars. Our results suggest that 1P stars are not homogeneous in the overall metallicity, with variations of the order of ~0.10 dex in all the chemical species. The anomalous stars distributed on a redder sequence of the ChM, are further enriched in metals, but without any evidence for a significant enrichment in the s elements. Our three second population stars located on the normal component of the map, have metallicities similar to those of the metal-richer 1P group, suggesting that this population formed from these stars. Although three stars is a too-small sample to draw strong conclusions, the low spread in metals of these objects might point towards a formation in a fully mixed medium, possibly after a cooling flow phase.

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Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

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Barium stars as tracers of s-process nucleosynthesis in AGB stars I. 28 stars with independently derived AGB mass

Barium (Ba) stars are polluted by material enriched in the slow neutron capture (s-process) elements synthesised in the interior of their former asymptotic giant branch (AGB) companion star, which is now a white dwarf. We compare individual Ba star abundance patterns to AGB nucleosynthesis models to verify if the AGB model mass is compatible with independently derived AGB mass. We selected a sample of 28 Ba stars for which both self-consistent spectroscopic observation and analysis are available and stellar mass determinations, via positioning the star on the HR diagram and comparing with evolutionary tracks. For this sample stars we considered both previously and recently derived elemental abundances. Then, we performed a detailed comparison of these s-process elemental abundances to different AGB nucleosynthesis models from the Monash and the FRUITY theoretical data sets. We simplified the binary mass transfer by calculating dilution factors to match the [Ce/Fe] value of each star when using different AGB models, and we then compared the diluted model abundances to the complete Ba-star abundance pattern. Our comparison confirms that low mass, non-rotating AGB stellar models with 13C as the main neutron source are the polluters of the vast majority of the considered Ba stars. Out of the 28 stars, in 21 cases the models are in good agreement with both the determined abundances and the independently derived AGB mass, although in 16 cases higher observed abundances of Nb, Ru, Mo and/or Nd, Sm than predicted. For 3 stars we obtain a match to the abundances only by considering models with masses lower than those independently determined. Finally, 4 stars show much higher first s-process peak abundance values than the model predictions, which may represent the signature of a physical and/or nucleosynthetic process that is not represented in the set of models considered here.

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Galactic Chemical Evolution of Radioactive Isotopes with an s-process Contribution

Analysis of inclusions in primitive meteorites reveals that several short-lived radionuclides (SLRs) with half-lives $0.1-100$ Myr existed in the early Solar System (ESS). We investigate the ESS origin of $^{107}$Pd, $^{135}$Cs, and $^{182}$Hf, which are produced by $slow$ neutron captures (the $s$-process) in asymptotic giant branch (AGB) stars. We modelled the galactic abundances of these SLRs using the OMEGA+ galactic chemical evolution (GCE) code and two sets of mass- and metallicity-dependent AGB nucleosynthesis yields (Monash and FRUITY). Depending on the ratio of the mean life $τ$ of the SLR to the average length of time between the formation of AGB progenitor $γ$, we calculate timescales relevant for the birth of the Sun. If $τ/γ\gtrsim2$, we predict self-consistent isolation times between 9 and 26 Myr by decaying the GCE predicted $^{107}$Pd/$^{108}$Pd, $^{135}$Cs/$^{133}$Cs, and $^{182}$Hf/$^{180}$Hf ratios to their respective ESS ratios. The predicted $^{107}$Pd/$^{182}$Hf ratio indicates that our GCE models are missing $9-73\%$ of $^{107}$Pd and $^{108}$Pd in the ESS. This missing component may have come from AGB stars of higher metallicity than those that contributed to the ESS in our GCE code. If $τ/γ\lesssim0.3$, we calculate instead the time ($T_{\rm LE}$) from the last nucleosynthesis event that added the SLRs into the presolar matter to the formation of the oldest solids in the ESS. For the 2 M$_\odot$, $Z=0.01$ Monash model we find a self-consistent solution of $T_{\rm LE}=25.5$ Myr.

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Heavy elements in barium stars

New elemental abundances for the neutron-capture elements Sr, Nb, Mo, Ru, La, Sm, and Eu are presented for a large sample of 180 barium (Ba) giant stars, a class of chemically peculiar objects that exhibit in their spectra enhancements of the elements created by the $s$-process, as a consequence of mass transfer between the components of a binary system. The content of heavy elements in these stars, in fact, points to nucleosynthesis mechanisms that took place within a former asymptotic giant branch (AGB) companion, now an invisible white dwarf. From high-resolution ($R=48000$) spectra in the optical, we derived the abundances either by equivalent width measurements or synthetic spectra computations, and compared them with available data for field giant and dwarf stars in the same range of metallicity. A re-determination of La abundances resulted in [La/Fe] ratios up to 1.2 dex lower than values previously reported in literature. The program Ba stars show overabundance of neutron-capture elements, except for Eu, for which the observational data set behave similarly to field stars. Comparison to model predictions are satisfactory for second-to-first $s$-process peak ratios (e.g., [La/Sr]) and the ratios of the predominantly $r$-process element Eu to La. However, the observed [Nb,Mo,Ru/Sr] and [Ce,Nd,Sm/La] ratios show median values higher or at the upper limits of the ranges of the model predictions. This unexplained feature calls for new neutron capture models to be investigated.

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The GALAH Survey: Non-LTE departure coefficients for large spectroscopic surveys

Massive sets of stellar spectroscopic observations are rapidly becoming available and these can be used to determine the chemical composition and evolution of the Galaxy with unprecedented precision. One of the major challenges in this endeavour involves constructing realistic models of stellar spectra with which to reliably determine stellar abundances. At present, large stellar surveys commonly use simplified models that assume that the stellar atmospheres are approximately in local thermodynamic equilibrium (LTE). To test and ultimately relax this assumption, we have performed non-LTE calculations for $13$ different elements (H, Li, C, N, O, Na, Mg, Al, Si, K, Ca, Mn, and Ba), using recent model atoms that have physically-motivated descriptions for the inelastic collisions with neutral hydrogen, across a grid of $3756$ 1D MARCS model atmospheres that spans $3000\leq T_{\mathrm{eff}}/\mathrm{K}\leq8000$, $-0.5\leq\log{g/\mathrm{cm\,s^{-2}}}\leq5.5$, and $-5\leq\mathrm{[Fe/H]}\leq1$. We present the grids of departure coefficients that have been implemented into the GALAH DR3 analysis pipeline in order to complement the extant non-LTE grid for iron. We also present a detailed line-by-line re-analysis of $50126$ stars from GALAH DR3. We found that relaxing LTE can change the abundances by between $-0.7\,\mathrm{dex}$ and $+0.2\,\mathrm{dex}$ for different lines and stars. Taking departures from LTE into account can reduce the dispersion in the $\mathrm{[A/Fe]}$ versus $\mathrm{[Fe/H]}$ plane by up to $0.1\,\mathrm{dex}$, and it can remove spurious differences between the dwarfs and giants by up to $0.2\,\mathrm{dex}$. The resulting abundance slopes can thus be qualitatively different in non-LTE, possibly with important implications for the chemical evolution of our Galaxy.

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Exploring circumstellar effects on the lithium and calcium abundances in massive Galactic O-rich AGB stars

We previously explored the circumstellar effects on the Rb and Zr abundances in massive Galactic O-rich AGB stars. Here we are interested in the role of the extended atmosphere in the case of Li and Ca. Li is an important indicator of HBB while the total Ca in these stars could be affected by neutron captures. The Li abundances were previously studied with hydrostatic models, while the Ca abundances have been determined for the first time. We use a modified version of Turbospectrum and consider the presence of a gaseous circumstellar envelope and radial wind. The new Li abundances derived with the pseudo-dynamical models are very similar to those obtained from hydrostatic models (the average difference is 0.18 dex), with no difference for Ca. The Li and Ca content in these stars is only slightly affected by the presence of a circumstellar envelope. We also found that the Li I and Ca I line profiles are not very sensitive to variations of the model wind parameters. The new Li abundances confirm the Li-rich nature of the sample stars, supporting the activation of HBB in massive Galactic AGB stars. This is in good agreement with the theoretical predictions for solar metallicity AGB models from ATON, Monash, and NuGrid/MESA but is at odds with the FRUITY database, which predicts no HBB leading to the production of Li. Most sample stars display nearly solar Ca abundances that are consistent with the available s-process nucleosynthesis models for solar metallicity massive AGB stars, which predict overproduction of 46Ca relatively to the other Ca isotope and the creation of the radiactive isotope 41Ca but no change in the total Ca abundance. A minority of the stars seem to show a significant Ca depletion (by up to 1.0 dex). Possible explanations are offered to explain their apparent and unexpected Ca depletion.

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On the formation of neutron stars via accretion-induced collapse in binaries

We investigate evolutionary pathways leading to neutron star formation through the collapse of oxygen-neon white dwarf (ONe WD) stars in interacting binaries. We consider (1) non-dynamical mass transfer where an ONe WD approaches the Chandrasekhar mass leading to accretion-induced collapse (AIC) and (2) dynamical timescale merger-induced collapse (MIC) between an ONe WD and another WD. We present rates, delay times, and progenitor properties for two different treatments of common envelope evolution. We show that AIC neutron stars are formed via many different channels and the most dominant channel depends on the adopted common envelope physics. Most AIC and MIC neutron stars are born shortly after star formation, though some have delay times >10 Gyr. The shortest delay time (25-50 Myr) AIC neutron stars have stripped-envelope, compact, helium-burning star donors, though many prompt AIC neutron stars form via wind-accretion from an asymptotic giant branch star. The longest delay time AIC neutron stars, which may be observed as young milli-second pulsars among globular clusters, have a red giant or main sequence donor at the time of NS formation and will eventually evolve into NS + helium WD binaries. We discuss AIC & MIC binaries as potential gravitational wave sources for LISA. Neutron stars created via AIC undergo a LMXB phase, offering an electromagnetic counterpart for those shortest orbital period sources that LISA could identify. The formation of neutron stars from interacting WDs in binaries is likely to be a key mechanism for the production of LIGO/Virgo gravitational wave sources (NS-NS and BH-NS mergers) in globular clusters.

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An ALMA view of CS and SiS around oxygen-rich AGB stars

We aim to determine the distributions of molecular SiS and CS in the circumstellar envelopes of oxygen-rich asymptotic giant branch stars and how these distributions differ between stars that lose mass at different rates. In this study we analyse ALMA observations of SiS and CS emission lines for three oxygen-rich galactic AGB stars: IK Tau, with a moderately high mass-loss rate of $5\times10^{-6}$M$_\odot$ yr$^{-1}$, and W Hya and R Dor with low mass loss rates of $\sim1\times10^{-7}$M$_\odot$ yr$^{-1}$. These molecules are usually more abundant in carbon stars but the high sensitivity of ALMA allows us to detect their faint emission in the low mass-loss rate AGB stars. The high spatial resolution of ALMA also allows us to precisely determine the spatial distribution of these molecules in the circumstellar envelopes. We run radiative transfer models to calculate the molecular abundances and abundance distributions for each star. We find a spread of peak SiS abundances with $\sim10^{-8}$ for R Dor, $\sim10^{-7}$ for W Hya, and $\sim3\times10^{-6}$ for IK Tau relative to H$_2$. We find lower peak CS abundances of $\sim7\times10^{-9}$ for R Dor, $\sim7\times10^{-8}$ for W Hya and $\sim4\times10^{-7}$ for IK Tau, with some stratifications in the abundance distributions. For IK Tau we also calculate abundances for the detected isotopologues: C$^{34}$S, $^{29}$SiS, $^{30}$SiS, Si$^{33}$S, Si$^{34}$S, $^{29}$Si$^{34}$S, and $^{30}$Si$^{34}$S. Overall the isotopic ratios we derive for IK Tau suggest a lower metallicity than solar.

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The s process in AGB stars as constrained by a large sample of Barium stars

Context. Barium (Ba) stars are dwarf and giant stars enriched in elements heavier than iron produced by the slow neutron-capture process (s process). They belong to binary systems where the primary star evolved through the asymptotic giant branch (AGB) phase,during which it produced the s-process elements and transferred them onto the secondary, now observed as a Ba star. Aims. We compare the largest homogeneous set of Ba giant star observations of the s-process elements Y, Zr, La, Ce, and Nd with AGB nucleosynthesis models to reach a better understanding of the s process in AGB stars. Methods. By considering the light-s (ls: Y and Zr) heavy-s (hs: La, Ce, and Nd) and elements individually, we computed for the first time quantitative error bars for the different hs-element/ls-element abundance ratios, and for each of the sample stars. We compared these ratios to low-mass AGB nucleosynthesis models. We excluded La from our analysis because the strong La lines in some of the sample stars cause an overestimation and unreliable abundance determination, as compared to the other observed hs-type elements. Results. All the computed hs-type to ls-type element ratios show a clear trend of increasing with decreasing metallicity with a small spread (less than a factor of 3). This trend is predicted by low-mass AGB models where 13C is the main neutron source. The comparison with rotating AGB models indicates the need for the presence of an angular momentum transport mechanism that should not transport chemical species, but significantly reduce the rotational speed of the core in the advanced stellar evolutionary stages. This is an independent confirmation of asteroseismology observations of the slow down of core rotation in giant stars, and of rotational velocities of white dwarfs lower than predicted by models without an extra angular momentum transport mechanism.

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Do meteoritic silicon carbide grains originate from asymptotic giant branch stars of super-solar metallicity?

We compare literature data for the isotopic ratios of Zr, Sr, and Ba from analysis of single meteoritic stardust silicon carbide (SiC) grains to new predictions for the slow neutron-capture process (the s process) in metal-rich asymptotic giant branch (AGB) stars. The models have initial metallicities Z = 0.014 (solar) and Z = 0.03 (twice-solar) and initial masses 2 - 4.5 Msun, selected such as the condition C/O>1 for the formation of SiC is achieved. Because of the higher Fe abundance, the twice-solar metallicity models result in a lower number of total free neutrons released by the 13C(α,n)16O neutron source. Furthermore, the highest-mass (4 - 4.5 Msun) AGB stars of twice-solar metallicity present a milder activation of the 22Ne(α,n)25Mg neutron source than their solar metallicity counterparts, due to cooler temperatures resulting from the effect of higher opacities. They also have a lower amount of the 13C neutron source than the lower-mass models, following their smaller He-rich region. The combination of these different effects allows our AGB models of twice-solar metallicity to provide a match to the SiC data without the need to consider large variations in the features of the 13C neutron source nor neutron-capture processes different from the s process. This raises the question if the AGB parent stars of meteoritic SiC grains were in fact on average of twice-solar metallicity. The heavier-than-solar Si and Ti isotopic ratios in the same grains are in qualitative agreement with an origin in stars of super-solar metallicity because of the chemical evolution of the Galaxy. Further, the SiC dust mass ejected from C-rich AGB stars is predicted to significantly increase with increasing the metallicity.

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IFU spectroscopy of southern PN VI: The extraordinary chemo-dynamics of Hen 2-111

In this paper we present integral field spectroscopy of the extraordinary Type I bipolar planetary nebula Hen 2-111. In the lobes we map fast moving knots of material with [N II]$λ6584$/H$α$ ratios up to 12, and with radial velocities relative to systemic from -340 km/s up to +390 km/s. We find evidence of a bipolar ejection event at a velocity $\sim 600$ km/s from the central star (assumed to be a binary), which occurred about 8000yr ago. The fast moving material is chemically quite distinct from the lower velocity gas in the bipolar lobes., and displays very high N abundances. We show that the fast moving N-rich knots are not photoionised by the central star, and have constructed detailed shock models for the brightest knot. We find a pre-shock density $\sim 6$cm$^{-3}$, and a shock velocity $\sim150$ km/s. The shock is not fully radiative, being only $\sim 600$yr old. This shocked gas is partially H-burnt, with a helium abundance by mass exceeding that of hydrogen, and is interacting with partially H-burnt material ejected in an earlier episode of mass loss. We conclude that the high-velocity material and the bipolar shell must have originated during the late stages of evolution of a common-envelope phase in a close binary system.

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