arXiv subjects

A. K. Dharmadhikari

Publications and source records attributed to A. K. Dharmadhikari.

15 recordsLinked to original sources

arXiv2013

Bond-selective fragmentation of water molecules with intense, ultrafast, carrier envelope phase stabilized laser pulses

Carrier envelope phase (CEP) stabilized pulses of intense 800 nm light of 5 fs duration are used to probe the dissociation dynamics of dications of isotopically-substituted water, HOD. HOD$^{2+}$ dissociates into either H$^+$ + OD$^+$ or D$^+$ + OH$^+$. The branching ratio for these two channels is CEP-dependent; the OD$^+$/OH$^+$ ratio (relative to that measured with CEP-unstabilized pulses) varies from 150% to over 300% at different CEP values, opening prospects of isotope-dependent control over molecular bond breakage. The kinetic energy released as HOD$^{2+}$ Coulomb explodes is also CEP-dependent. Formidable theoretical challenges are identified for proper insights into the overall dynamics which involve non-adiabatic field ionization from HOD to HOD$^+$ and, thence, to HOD$^{2+}$ via electron rescattering.

physics.atom-ph↗

arXiv2013

Carrier envelope phase effects in ultrafast, strong-field ionization dynamics of multielectron systems: Xe and CS$_2$

Carrier envelope phase (CEP) stabilized 5 fs and 22 fs pulses of intense 800 nm light are used to probe the strong-field ionization dynamics of multielectron entities, xenon and carbon disulfide. We compare ion yields obtained with and without CEP-stabilization: with 8-cycle (22 fs) pulses, Xe$^{6+}$ yields are suppressed (relative to Xe$^+$ yields) by between 30% and 50%, depending on phase, reflecting the phase dependence of non-sequential ionization and its contribution to the formation of higher charge states. On the other hand, ion yields for Xe$^{q+}$ ($q$=2-4) with CEP-stablized pulses are enhanced (by up to 50%) compared to those with CEP-unstabilized pulses. Such enhancment is particulary pronounced with 2-cycle (5 fs) pulses and is distinctly phase-dependent. Orbital shape and symmetry are found to have a bearing on the response of CS$_2$ to variations in optical field that are effected as CE phase is controllably altered, keeping the overall intensity constant. Molecular fragmentation is found to depend on field strength (not intensity); the observed relative enhancement of fragmentation when CEP-stabilized 2-cycle pulses are used is found to be at the expense of molecular ionization.

physics.atom-ph↗

arXiv2012

Intense 2-cycle laser pulses induce time-dependent bond-hardening in a polyatomic molecule

A time-dependent bond-hardening process is discovered in a polyatomic molecule (tetramethyl silane, TMS) using few-cycle pulses of intense 800 nm light. In conventional mass spectrometry, symmetrical molecules like TMS do not exhibit a prominent molecular ion (TMS$^+$) as unimolecular dissociation into [Si(CH$_3$)$_3]^+$ proceeds very fast. Under strong field and few-cycle conditions, this dissociation channel is defeated by time-dependent bond-hardening: a field-induced potential well is created in the TMS$^+$ potential energy curve that effectively traps a wavepacket. The time-dependence of this bond hardening process is verified using longer-duration ($\geq$ 100 fs) pulses; the relatively "slower" fall-off of optical field in such pulses allows the initially trapped wavepacket to leak out, thereby rendering TMS$^+$ unstable once again. Our results are significant as they demonstrate (i) optical generation of polyatomic ions that are normally inaccessible and (ii) optical control of dynamics in strong fields, with distinct advantages over weak-field control scenarios that demand a narrow bandwidth appropriate for a specified transition.

physics.atom-ph↗

arXiv2011

Laser-driven accelerated growth of dendritic patterns

We report a scheme for very significantly accelerating growth of dendritic patterns in diverse liquids, making use of only a few hundred microwatts of laser power in the presence of an efficient absorber like carbon nanotubes (CNTs). The CNTs act as a heat source that drives dendritic growth; their anisotropy ensures a rich diversity of branched patterns. We rationalize the unprecedented speed of dendritic growth using a diffusion equation for the temperature field with an additional source term. Close to the heat source, the well-established microscopic solvability theory is seen to break down. Our method opens new vistas for experimental and theoretical studies of pattern formation in liquids.

cond-mat.mtrl-sci↗

arXiv2011

Effect of intense, ultrashort laser pulses on DNA plasmids in their native state: strand breakages induced by {\it in-situ} electrons and radicals

Single strand breaks are induced in DNA plasmids, pBR322 and pUC19, in aqueous media exposed to strong fields generated using ultrashort laser pulses (820 nm wavelength, 45 fs pulse duration, 1 kHz repetition rate) at intensities of 1-12 TW cm$^{-2}$. The strong fields generate, {\it in situ}, electrons and radicals that induce transformation of supercoiled DNA into relaxed DNA, the extent of which is quantified. Introduction of electron and radical scavengers inhibits DNA damage; results indicate that OH radicals are the primary (but not sole) cause of DNA damage.

physics.bio-ph↗

arXiv2008

Strong fields induce ultrafast rearrangement of H-atoms in H$_2$O

H-atoms in H$_2$O are rearranged by strong optical fields generated by intense, 10 fs laser pulses to form H$_2^+$, against prevailing wisdom that strong fields inevitably lead to multiple molecular ionization and the subsequent Coulomb explosion into fragments. This atomic rearrangement is shown to occur within a single 10 fs pulse. Comparison with results obtained with $\sim$300-attosecond long strong fields generated using fast Si$^{8+}$ ions helps establish thresholds for field strength and time required for such rearrangements. Quantum-chemical calculations reveal that H$_2^+$ originates in the $^1$A state of H$_2$O$^{2+}$ when the O-H bond elongates to 1.15 a.u. and the H-O-H angle becomes 120$^o$. Bond formation on the ultrafast timescale of molecular vibrations (10 fs for H$_2^+$) has hitherto not been reported.

physics.chem-ph↗

arXiv2007

Control of the Onset of Filamentation in Condensed Media

Propagation of intense, ultrashort laser pulses through condensed media like crystals of BaF$_2$ and sapphire results in the formation of filaments. We demonstrate that the onset of filamentation may be controlled by rotating the plane of polarization of incident light. We directly visualize filamentation in BaF_2 via six-photon absorption-induced fluorescence and, concomitantly, by probing the spectral and spatial properties of white light that is generated.

physics.optics↗

arXiv2006

All-optical Control of the Propagation of Intense Laser Light in Condensed Media

We experimentally demonstrate optical control of filamentation that occurs during propagation of intense, ultrashort laser pulses through crystals like barium fluoride and sapphire. Control is exercised by rotating the plane of polarization of the incident laser radiation and is demonstrated by directly visualizing filamentation in the bulk via six-photon absorption-induced fluorescence and, concomitantly, by probing the spectral and spatial properties of white light that is generated.

physics.plasm-ph↗

arXiv2006

Multiple optical traps from a single laser beam using a mechanical element

The use of a wire mesh facilitates creation of multiple optical traps for manipulation of small micron or sub-micron particles. Such an array of optical traps can be easily controlled. The trap that is formed in this manner is a continuous trap; it obviates the need to time share a laser beam among a set of positions, as is presently done in conventional multiple traps.

physics.optics↗

arXiv2005

Euler buckling in red blood cells: An optically driven biological micromotor

We investigate the physics of an optically-driven micromotor of biological origin. A single, live red blood cell, when placed in an optical trap folds into a rod-like shape. If the trapping laser beam is circularly polarized, the folded RBC rotates. A model based on the concept of buckling instabilities captures the folding phenomenon; the rotation of the cell is simply understood using the Poincarè sphere. Our model predicts that (i) at a critical intensity of the trapping beam the RBC shape undergoes large fluctuations and (ii) the torque is proportional to the intensity of the laser beam. These predictions have been tested experimentally. We suggest a possible mechanism for emergence of birefringent properties in the RBC in the folded state.

physics.bio-ph↗

arXiv2004

Laser Generated Magnetic Pulses: Hot Electron Propagation in Conducting and Dielectric Material

We report experimental evidence of electrostatic inhibition of fast electrons, generated in a highly resistive material upon irradiation with an intense ultra-short ($10^{16} W/cm^{2}$, $100 fmsec$) laser pulse. The experiment involves measurement of temporal evolution of self-generated magnetic pulses using pump-probe polarimetry. A comparison is made between the temporal behaviour of magnetic pulses generated with Aluminum and Glass targets. It is found that in contrast to Aluminium, self-generated magnetic pulse decays much faster in glass. This is attributed to the absence of return shielding currents in glass, which results in build up of electrostatic field, which in turn inhibits the movement of fast electrons. Fitting of experimental measurements using a one dimensional model, yields estimate of conductivity of Aluminium and glass, and penetration depth of hot electrons in these materials.

physics.plasm-ph↗

arXiv2003

All-optical switching with bacteriorhodopsin

All-optical, mirrorless switching and bistability is demonstrated with bacteriorhodopsin (bR). A low-power, 532 nm laser beam modulates the transmission of a cw laser beam at 635 nm that corresponds to peak absorption of the O-excited state in the bR photocycle. The switch has features like a NOT-gate; its switching contrast depends on the pulse width and average power of the modulating laser. The phase of the switching characteristics can be controlled by varying the pulse width and frequency of the modulating laser. Simulations based on a rate equation approach considering a six-state model of the bR photocycle successfully reproduce the experimental results.

physics.optics↗

arXiv2002

Amplified Spontaneous Emission enhanced Forward Stimulated Raman Scattering in dye solutions

We study forward stimulated Raman emission from weakly fluorescent dye 4'-diethylamino-N-methyl-4-stilbazolium tosylate (DEST) in 1,2,dichloroethane solution excited by a 28 ps, 532 nm Nd: YAG laser. Neat 1, 2, dichloroethane emits the first Stokes line at 631 nm with a spectral width of 1.6 nm corresponding to a Raman shift of 2956 per cm. We observe reduction of spectral width with the addition of DEST in 1, 2, dichloroethane solution. The single pass conversion efficiency for forward Raman emission is as high as 20 percent in a 1 cm path length sample. The pulse duration of forward stimulated Raman emission measured by a third order autocorrelation technique is 10 ps in neat 1, 2, dichloroethane, whereas it is nearly 3 ps for 0.04 mM of DEST solution.

physics.optics↗

arXiv2002

Evolution of Electrical Resistivity, Thermal Conductivity, and Temperature of a solid under the action of Intense Ultrashort Laser pulse

The dynamical properties of Cu in a regime relevant to femtosecond micro machining are obtained on picosecond time scales using pump-probe reflectivity study for 100fs, 1015 W cm-2 laser pulses. The electrical resistivity is obtained by solving Helmoltz equations. The dissipation mechanisms and scaling laws are obtained in high and low temperature limits. The 'resistivity saturation' effect in an unexplored regime intermediate to hot plasma and cold solid is studied in detail. The temperature evolution and thermal conductivity is obtained in the temporal range 0 to 30ps after the interaction of laser pulse with solid Cu.

physics.plasm-ph↗

arXiv2002

Laser-Generated Ultrashort Multi-Megagauss Magnetic Pulses in Plasmas

We demonstrate ultrashort (6 ps), multi-Megagauss (27 MG) magnetic pulses generated upon interaction of an intense laser pulse (10^{16} Wcm^-2, 100 fs) with a solid target. The temporal evolution of these giant fields generated near the high density critical layer is obtained with the highest resolution reported so far. Particle-in-cell simulations and phenomenological modeling is used to explain the results. The first direct observations of anomalously rapid damping of plasma shielding currents produced in response to the hot electron currents penetrating the bulk plasma are presented.

physics.plasm-ph↗