arXiv subjects
Publications and source records attributed to A. Kovalenko.
This paper presents a novel method for measuring the Poynting vector characteristics of monochromatic electromagnetic waves. We outline a specific design for such a meter and provide experimental data to validate the approach. For testing purposes, we utilized vortex beams with both linear and circular polarization.
This review examines multiscale modelling approaches for cellulose nanocrystals (CNCs) and lignocellulosic plant cell walls, with a focus on hemicellulose and lignin interactions in aqueous environments. The three-dimensional reference interaction site model with the Kovalenko-Hirata closure (3D-RISM-KH) is highlighted as a powerful molecular solvation theory applied in nanochemistry and biomolecular simulations. The method has been successfully employed to investigate hemicellulose hydrogels, the influence of hemicellulose composition on nanoscale forces in primary cell walls, and lignin-lignin and lignin-hemicellulose interactions. Findings indicate that these interactions are predominantly hydrophobic and entropy-driven, arising from water exclusion effects. Insights gained through this modeling framework deepen the understanding of molecular-scale forces in plant cell walls and inform strategies for biomass valorization, including genetic engineering and pretreatment technologies aimed at enhancing cellulose extraction and utilization.
Applications of 3D-RISM-KH molecular solvation theory range from solvation energy of small molecules to phase behavior of polymers and biomolecules. It predicts the molecular mechanisms of chemical and biomolecular systems. Replica RISM-KH-VM molecular solvation theory predicts and explains the structure, thermodynamics, and electrochemistry of electrolyte solutions sorbed in a nanoporous material. It was tested on nanoporous carbon supercapacitors with aqueous electrolyte and nanoporous electrosorption cells. The mechanisms in these systems are steered by the electric double layer potential drop across the Stern layer at the nanopores surface and the Gouy-Chapman layer averaged over the nanoporous material, the osmotic term due to the ionic concentrations difference in the two nanoporous electrodes and in the electrolyte solution outside, and the solvation chemical potentials of sorbed ions averaged over the nanoporous material. The latter strongly depends on chemical specificity of ions, solvent, surface functional groups, and steric effects for solvated ions confined in nanopores.
The efficient detection of light from trapped ions in free space is paramount for most of their applications. We propose a scheme to enhance the photon collection from linear ion strings. It employs the constructive interference of light scattered from ions along the axial direction in linear Paul traps. The coherent enhancement of photon collection is numerically optimized for a range of feasible spatial angles and realistic ion positions in a single harmonic Coulomb potential. Despite the large mutual distance of scatterers on the order of many wavelengths of scattered light, presented experimental tests confirm the feasibility of enhancements by a factor of $3.05 \pm 0.09$ with a crystal of nine $^{40}$Ca$^+$ ions. Further significant improvements using different ion species, which allow for suppression of the sensitivity to the residual thermal motion, are predicted. The proposed collection geometry is intrinsic to diverse linear ion trap designs and the methodology can be directly applied to an observation of scattering from ion crystals prepared in collective electronic excitations.
Quantum coherence between energy eigenstates of harmonic oscillators is essential for quantum physics. Even the most elementary binary superpositions of the ground and the higher eigenstate are highly required for quantum sensing, thermodynamics, and computing. We derive upper bounds for quantum coherences achieved by classical and Gaussian states and operations and, subsequently, obtain a hierarchy of the thresholds for the off-diagonal elements necessary to reach genuine quantum non-Gaussian coherences. We experimentally demonstrate unambiguous observation of quantum non-Gaussian coherences in mechanical vibrations of a single calcium ion up to the superposition of zero and six phonons. The analysis of the robustness with respect to pure dephasing in a motional Ramsey experiment demonstrates the feasibility of their storage for up to more than 20 ms for superpositions with a large energy difference of participating number states. The presented observations prove that atomic oscillations go deeply into a diverse area of discrete quantum non-Gaussian coherent phenomena critical for their applications.
While the spontaneous emission from independent emitters provides spatially uncorrelated photons - a typical manifestation of quantum randomness, the interference of the coherent scattering leads to a well-defined intensity pattern - a feature described by linear optics. We here demonstrate experimentally how the interplay between the two mechanisms in large systems of quantum emitters leads to spatial variations of photon correlations. The implementation with trapped ion crystals in free space allows us to observe the anti-correlation between photon rates and variance of the photon number distributions in chains of up to 18 ions. For smaller crystals of four ions, the transition from a sub-Poissonian to a super-Poissonian variance of the photon number in the scattered light is reported. For higher numbers of scatterers, the photon statistics still display a strong deviation from the fully incoherent scattering case. Our results illustrate how the interference of coherent scattering, combined with spontaneous emission, provides a control mechanism for the light statistics.
The optical interference constitutes a paramount resource in modern physics. At the scale of individual atoms and photons, it is a diverse concept that causes different coherent phenomena. We present the experimental characterization of both coherent and statistical properties of light emitted from ensembles of trapped ions increasing with a number of contributing phase-incoherent independent atomic particles ranging from a single to up to several hundreds. It conclusively demonstrates how super-Poissonian quantum statistics non-trivially arises purely from the finite number of indistinguishable single-photon emitters in the limit of a single detection mode. The achieved new optical emission regime in which these independent atoms contribute coherently to the super-Poissonian statistics provides a new perspective on the emergence of optical coherence at the atomic scale and constitutes a unique toolbox for its generation and control at the most microscopic level.
From superconductors to atomic nuclei, strongly-interacting many-body systems are ubiquitous in nature. Measuring the microscopic structure of such systems is a formidable challenge, often met by particle knockout scattering experiments. While such measurements are fundamental for mapping the structure of atomic nuclei, their interpretation is often challenged by quantum mechanical initial- and final-state interactions (ISI/FSI) of the incoming and scattered particles. Here we overcome this fundamental limitation by measuring the quasi-free scattering of 48 GeV/c 12C ions from hydrogen. The distribution of single protons is studied by detecting two protons at large angles in coincidence with an intact 11B nucleus. The 11B detection is shown to select the transparent part of the reaction and exclude the otherwise large ISI/FSI that would break the 11B apart. By further detecting residual 10B and 10Be nuclei, we also identified short-range correlated (SRC) nucleon-nucleon pairs, and provide direct experimental evidence for the separation of the pair wave-function from that of the residual many-body nuclear system. All measured reactions are well described by theoretical calculations that do not contain ISI/FSI distortions. Our results thus showcase a new ability to study the short-distance structure of short-lived radioactive atomic nuclei at the forthcoming FAIR and FRIB facilities. These studies will be pivotal for developing a ground-breaking microscopic understanding of the structure and properties of nuclei far from stability and the formation of visible matter in the universe.
This release includes data and information necessary to perform independent analyses of the COHERENT result presented in Akimov et al., arXiv:1708.01294 [nucl-ex]. Data is shared in a binned, text-based format, including both "signal" and "background" regions, so that counts and associated uncertainties can be quantitatively calculated for the purpose of separate analyses. This document describes the included information and its format, offering some guidance on use of the data. Accompanying code examples show basic interaction with the data using Python.
The primary goal of the COHERENT collaboration is to measure and study coherent elastic neutrino-nucleus scattering (CEvNS) using the high-power, few-tens-of-MeV, pulsed source of neutrinos provided by the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). The COHERENT collaboration reported the first detection of CEvNS [Akimov:2017ade] using a CsI[Na] detector. At present the collaboration is deploying four detector technologies: a CsI[Na] scintillating crystal, p-type point-contact germanium detectors, single-phase liquid argon, and NaI[Tl] crystals. All detectors are located in the neutron-quiet basement of the SNS target building at distances 20-30 m from the SNS neutrino source. The simultaneous measurement in all four COHERENT detector subsystems will test the $N^2$ dependence of the cross section and search for new physics. In addition, COHERENT is measuring neutrino-induced neutrons from charged- and neutral-current neutrino interactions on nuclei in shielding materials, which represent a non-negligible background for CEvNS as well as being of intrinsic interest. The Collaboration is planning as well to look for charged-current interactions of relevance to supernova and weak-interaction physics. This document describes concisely the COHERENT physics motivations, sensitivity, and next plans for measurements at the SNS to be accomplished on a few-year timescale.
Belarusian State University is currently developing the educational and research web portal of nuclear knowledge BelNET (Belarusian Nuclear Education and Training Portal). In the future, this specialized electronic portal could grow into a national portal of nuclear knowledge. The concept, structure and taxonomy of BelNET portal are developed. The requirements and conditions for its functioning are analyzed. The information model and architecture of the portal, as well as algorithms and methods of software are realized. At present, BelNET software implemented all the basic functions of this portal, including the ability to remotely (via the Internet) open content editing, sorting, filtering, etc. Filling the BelNET by knowledge is at the beginning.
Integral equation theory of molecular liquids based on statistical mechanics is quite promising as an essential part of multiscale methodology for chemical and biomolecular nanosystems in solution. Beginning with a molecular interaction potential force field, it uses diagrammatic analysis of the solvation free energy to derive integral equations for correlation functions between molecules in solution in the statistical-mechanical ensemble. The infinite chain of coupled integral equations for many-body correlation functions is reduced to a tractable form for 2- or 3-body correlations by applying the so-called closure relations. Solving these equations produces the solvation structure with accuracy comparable to molecular simulations that have converged but has a critical advantage of readily treating the effects and processes spanning over a large space and slow time scales, by far not feasible for explicit solvent molecular simulations. One of the versions of this formalism, the three-dimensional reference interaction site model (3D-RISM) integral equation complemented with the Kovalenko-Hirata (KH) closure approximation, yields the solvation structure in terms of 3D maps of correlation functions, including density distributions, of solvent interaction sites around a solute (supra)molecule with full consistent account for the effects of chemical functionalities of all species in the solution. The solvation free energy and the subsequent thermodynamics are then obtained at once as a simple integral of the 3D correlation functions by performing thermodynamic integration analytically.
The COHERENT collaboration's primary objective is to measure coherent elastic neutrino-nucleus scattering (CEvNS) using the unique, high-quality source of tens-of-MeV neutrinos provided by the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). In spite of its large cross section, the CEvNS process has never been observed, due to tiny energies of the resulting nuclear recoils which are out of reach for standard neutrino detectors. The measurement of CEvNS has now become feasible, thanks to the development of ultra-sensitive technology for rare decay and weakly-interacting massive particle (dark matter) searches. The CEvNS cross section is cleanly predicted in the standard model; hence its measurement provides a standard model test. It is relevant for supernova physics and supernova-neutrino detection, and enables validation of dark-matter detector background and detector-response models. In the long term, precision measurement of CEvNS will address questions of nuclear structure. COHERENT will deploy multiple detector technologies in a phased approach: a 14-kg CsI[Na] scintillating crystal, 15 kg of p-type point-contact germanium detectors, and 100 kg of liquid xenon in a two-phase time projection chamber. Following an extensive background measurement campaign, a location in the SNS basement has proven to be neutron-quiet and suitable for deployment of the COHERENT detector suite. The simultaneous deployment of the three COHERENT detector subsystems will test the $N^2$ dependence of the cross section and ensure an unambiguous discovery of CEvNS. This document describes concisely the COHERENT physics motivations, sensitivity and plans for measurements at the SNS to be accomplished on a four-year timescale.
A unique test of general relativity is possible with the space radio telescope RadioAstron. The ultra-stable on-board hydrogen maser frequency standard and the highly eccentric orbit make RadioAstron an ideal instrument for probing the gravitational redshift effect. Large gravitational potential variation, occurring on the time scale of $\sim$24 hr, causes large variation of the on-board H-maser clock rate, which can be detected via comparison with frequency standards installed at various ground radio astronomical observatories. The experiment requires specific on-board hardware operating modes and support from ground radio telescopes capable of tracking the spacecraft continuously and equipped with 8.4 or 15 GHz receivers. Our preliminary estimates show that $\sim$30 hr of the space radio telescope's observational time are required to reach $\sim 2\times10^{-5}$ accuracy in the test, which would constitute a factor of 10 improvement over the currently achieved best result.
Ultrafast laser excited hot electrons can transport energy supersonically far from the region where they are initially produced. We show that this ultrafast energy transport is responsible of the emission of coherent acoustic phonons deeply beneath the free surface of a copper metal sample. In particular we demonstrate that enough energy carried by these hot electrons over a distance as large as 220nm at room temperature in copper can be converted into coherent acoustic phonons. In order to demonstrate this effect, several configurations of time-resolved optical experiments of time of flight of coherent acoustic phonons and of hot electrons have been performed.
EXO-200 uses 468 large area avalanche photodiodes (LAAPDs) for detection of scintillation light in an ultra-low-background liquid xenon (LXe) detector. We describe initial measurements of dark noise, gain and response to xenon scintillation light of LAAPDs at temperatures from room temperature to 169K - the temperature of liquid xenon. We also describe the individual characterization of more than 800 LAAPDs for selective installation in the EXO-200 detector.
The Enriched Xenon Observatory (EXO) will search for double beta decays of 136Xe. We report the results of a systematic study of trace concentrations of radioactive impurities in a wide range of raw materials and finished parts considered for use in the construction of EXO-200, the first stage of the EXO experimental program. Analysis techniques employed, and described here, include direct gamma counting, alpha counting, neutron activation analysis, and high-sensitivity mass spectrometry.
We present details of the technical design and manufacture of the ZEPLIN-III dark matter experiment. ZEPLIN-III is a two-phase xenon detector which measures both the scintillation light and the ionisation charge generated in the liquid by interacting particles and radiation. The instrument design is driven by both the physics requirements and by the technology requirements surrounding the use of liquid xenon. These include considerations of key performance parameters, such as the efficiency of scintillation light collection, restrictions placed on the use of materials to control the inherent radioactivity levels, attainment of high vacuum levels and chemical contamination control. The successful solution has involved a number of novel design and manufacturing features which will be of specific use to future generations of direct dark matter search experiments as they struggle with similar and progressively more demanding requirements.