arXiv subjects

A. López-Sepulcre

Publications and source records attributed to A. López-Sepulcre.

At least 37 records · Page 2Linked to original sources

arXiv2021

ORion Alma New GEneration Survey (ORANGES) I. Dust continuum and free-free emission of OMC-2/3 filament protostars

The spectral energy distribution (SED) in the millimetre (mm) to centimetre (cm) range is a useful tool for characterising the dust in protostellar envelopes as well as free-free emission from the protostar and outflow. While many studies have been carried out towards low- and high-mass protostars, little exists so far about solar-type protostars in high-mass star-forming regions, which are likely to be representatives of the conditions where the Solar System was born. We focus here on the OMC-2/3 solar-type protostars, which are bounded by nearby HII regions and which are, therefore, potentially affected by the high-UV illumination. We aim to understand whether the small-scale structure ($\leq$1000 au) and the evolutionary status of these solar-type protostars are affected by the nearby HII regions, as is the case for the large-scale ($\leq$10$^4$ au) gas chemical composition. We used ALMA in the 1.3 mm band (246.2 GHz) to image the continuum of 16 OMC-2/3 solar-type protostars, with an angular resolution of 0.25$''$ (100 au). We completed our data with archival data from the VANDAM survey of Orion Protostars at 333 and 32.9 GHz, respectively, to construct the dust SED, extract several dust parameters and to assess whether free-free emission is contaminating their dust SED in the cm range. From the mm to cm range dust SED, we found low dust emissivity spectral indexes ($β< 1$) for the majority of our source sample and free-free emission towards only 5 of the 16 sample sources. We were also able to confirm or correct the evolutionary status of the source sample. Finally, we did not find any dependence of the source dust parameters on their location in the OMC-2/3 filament. Our results show that the small-scale dust properties of the OMC-2/3 protostars are not affected by the high- UV illumination from the nearby HII regions.

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arXiv2021

HII regions and high-mass starless clump candidates II. Fragmentation and induced star formation at ~0.025 pc scale: An ALMA continuum study

The ionization feedback from HII regions modifies the properties of high-mass starless clumps (HMSCs, of several hundred to a few thousand solar masses with a size of ~0.1-1 pc), such as temperature and turbulence, on the clump scale. The question of whether the presence of HII regions modifies the core-scale fragmentation and star formation in HMSCs remains to be explored. We aim to investigate the difference of 0.025 pc-scale fragmentation between candidate HMSCs that are strongly impacted by HII regions and less disturbed ones. We also search for evidence of mass shaping and induced star formation in the impacted HMSCs. Using the ALMA 1.3 mm continuum with a resolution of ~1.3", we imaged eight candidate HMSCs, including four impacted by HII regions and another four situated in the quiet environment. The less-impacted HMSCs are selected on the basis of their similar mass and distance compared to the impacted ones to avoid any possible bias linked to these parameters. A total of 51 cores were detected in eight clumps, with three to nine cores for each clump. Within our limited sample, we did not find a clear difference in the ~0.025 pc-scale fragmentation between impacted and non-impacted HMSCs, even though HII regions seem to affect the spatial distribution of the fragmented cores. Both types of HMSCs present a thermal fragmentation with two-level hierarchical features at the clump thermal Jeans length ${λ_{J, clump}^{th}}$ and 0.3${λ_{J, clump}^{th}}$. The ALMA emission morphology of the impacted HMSCs AGAL010.214-00.306 and AGAL018.931-00.029 sheds light on the capacities of HII regions to shape gas and dust in their surroundings and possibly to trigger star formation at ~0.025 pc-scale in HMSCs. Future ALMA surveys covering a large number of impacted HMSCs with high turbulence are needed to confirm the trend of fragmentation indicated in this study.

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arXiv2020

FAUST I. The hot corino at the heart of the prototypical Class I protostar L1551 IRS5

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which, therefore, represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA Large Program FAUST. We detected several lines from methanol and its isopotologues ($^{13}$CH$_{\rm 3}$OH and CH$_{\rm 2}$DOH), methyl formate and ethanol. Lines are bright toward the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines non-LTE analysis constrains the gas temperature ($\sim$100 K), density ($\geq$1.5$\times$10$^{8}$ cm$^{-3}$), and emitting size ($\sim$10 au in radius). All CH$_{\rm 3}$OH and $^{13}$CH$_{\rm 3}$OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on the present work, little chemical evolution from Class 0 to I hot corinos occurs.

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arXiv2020

Seeds of Life in Space (SOLIS). X. Interstellar Complex Organic Molecules in the NGC 1333 IRAS 4A outflows

Aims: A unique environment to study how interstellar Complex Organic Molecules (iCOMs) can be formed is the shocked gas along low-mass protostellar outflows, as the dust mantles composition is sputtered into the gas phase. The chemical richness in these environments has been so far studied only in the L1157 blue shifted outflow. Methods: To understand if the L1157-B1 case is unique, we imaged the NGC 1333 IRAS 4A outflows using the NOEMA (NOrthern Extended Millimeter Array) interferometer as part of the IRAM SOLIS (Seeds Of Life in Space) Large Program and compared the observations with the GRAINOBLE+ gas phase astrochemical model. Results: Several iCOMs were detected in the IRAS 4A outflows: methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), formamide (NH$_2$CHO) and dimethyl ether (CH$_3$OCH$_3$), all sampling upper excitation energy up to $\sim$30 K. We found a significant chemical differentiation between the IRAS 4A1 outflow, showing a richer molecular content, and the IRAS 4A2 one. The CH$_3$OH/CH$_3$CHO abundance ratio is lower by a factor $\sim$4 in the former; furthermore the ratio in both outflows is lower by a factor $\sim$10 with respect to hot corinos values. Conclusions: After L1157-B1, IRAS 4A outflow is now the second outflow to show an evident chemical complexity. Given that CH$_3$OH is a grain surface species, GRAINOBLE+ reproduced our observations assuming acetaldehyde formation in gas phase by the reaction of ethyl radical (CH$_3$CH$_2$) with atomic oxygen. Moreover, the chemical differentiation between the two outflows suggests that the IRAS 4A1 outflow is likely younger than the IRAS 4A2 one. Further investigation is needed to constrain the age of the outflow and observations of even younger shocks are necessary and future spectroscopic studies on CH$_3$CH$_2$ are needed to be able to observe this species and provide strong constraints on the CH$_3$CHO formation.

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arXiv2020

Seeds of Life in Space (SOLIS) VIII. SiO isotopic fractionation and a new insight in the shocks of L1157-B1

L1157-B1 is one of the outflow shocked regions along the blue-shifted outflow driven by the Class 0 protostar L1157-mm, and is an ideal laboratory to study the material ejected from the grains in very short timescales, i.e. its chemical composition is representative of the composition of the grains. We imaged $^{28}$SiO, $^{29}$SiO and $^{30}$SiO J = 2-1 emission towards L1157-B1 and B0 with the NOrthern Extended Millimeter Array (NOEMA) interferometer as part of the Seeds of Life in Space (SOLIS) large project. We present here a study of the isotopic fractionation of SiO towards L1157-B1. Furthermore, we use the high spectral resolution observations on the main isotopologue, $^{28}$SiO, to study the jet impact on the dense gas. We present here also single-dish observations obtained with the IRAM 30m telescope and Herschel-HIFI. We carried out a non-LTE analysis using a Large Velocity Gradient (LVG) code to model the single-dish observations. From our observations we can show that (i) the (2-1) transition of the main isotopologue is optically thick in L1157-B1 even at high velocities, and (ii) the [$^{29}$SiO/$^{30}$SiO] ratio is constant across the source, and consistent with the solar value of 1.5. We report the first isotopic fractionation maps of SiO in a shocked region and show the absence of a mass dependent fractionation in $^{29}$Si and $^{30}$Si across L1157-B1. A high-velocity bullet in $^{28}$SiO has been identified, showing the signature of a jet impacting on the dense gas. With the dataset presented in this paper, both interferometric and single-dish, we were able to study in great detail the gas shocked at the B1a position and its surrounding gas.

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arXiv2020

Hunting for hot corinos and WCCC sources in the OMC-2/3 filament

Context: Solar-like protostars are known to be chemically rich, but it is not yet clear how much their chemical composition can vary and why. So far, two chemically distinct types of Solar-like protostars have been identified: hot corinos, which are enriched in interstellar Complex Organic Molecules (iCOMs), such as methanol (CH$_3$OH) or dimethyl ether (CH$_3$OCH$_3$), and Warm Carbon Chain Chemistry (WCCC) objects, which are enriched in carbon chain molecules, such as butadiynyl (C$_4$H) or ethynyl radical (CCH). However, none of these have been studied so far in environments similar to that in which our Sun was born, that is, one that is close to massive stars. Aims: In this work, we search for hot corinos and WCCC objects in the closest analogue to the Sun's birth environment, the Orion Molecular Cloud 2/3 (OMC-2/3) filament located in the Orion A molecular cloud. Methods: We obtained single-dish observations of CCH and CH$_3$OH line emission towards nine Solar-like protostars in this region. As in other, similar studies of late, we used the [CCH]/[CH$_3$OH] abundance ratio in order to determine the chemical nature of our protostar sample. Results: Unexpectedly, we found that the observed methanol and ethynyl radical emission (over a few thousands au scale) does not seem to originate from the protostars but rather from the parental cloud and its photo-dissociation region, illuminated by the OB stars of the region. Conclusions: Our results strongly suggest that caution should be taken before using [CCH]/[CH$_3$OH] from single-dish observations as an indicator of the protostellar chemical nature and that there is a need for other tracers or high angular resolution observations for probing the inner protostellar layers.

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arXiv2020

Seeds of Life in Space (SOLIS).VII. Discovery of a cold dense methanol blob toward the L1521F VeLLO system

The SOLIS (Seeds Of Life In Space) IRAM/NOEMA Large Program aims at studying a set of crucial complex organic molecules in a sample of sources, with well-known physical structure, covering the various phases of Solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the Very Low Luminosity Object (VeLLO) called L1521F. This type of source is important to study to make the link between prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Two frequency windows (81.6-82.6 GHz and 96.65-97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. Only 2 transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (~7'' corresponding to ~1000au) toward the NE of the L1521F protostar. The CS 2-1 transition is also detected within the WideX bandwidth. Consistently, with what has been found in prestellar cores, the methanol emission appears ~1000au away from the dust peak. The location of the methanol blob coincides with one of the filaments previously reported in the literature. The Tex of the gas inferred from methanol is (10$\pm$2) K, while the H2 gas density (estimated from the detected CS 2-1 emission and previous CS 5-4 ALMA obs.) is a factor >25 higher than the density in the surrounding environment (n(H2) >10$^{7}$ cm$^{-3}$). From its compactness, low excitation temperature and high gas density, we suggest that the methanol emission detected with NOEMA is either a cold and dense shock-induced blob, recently formed ($\leq$ few hundred years) by infalling gas or a cold and dense fragment that may have just been formed as a result of the intense gas dynamics found within the L1521F VeLLO system.

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arXiv2020

Seeds of Life in Space (SOLIS) V. Methanol and acetaldehyde in the protostellar jet-driven shocks L1157-B0 and B1

Aim: In the past, observations of protostellar shocks have been able to set constraints on the formation route of formamide (NH2CHO), exploiting its observed spatial distribution and comparison with astrochemical model predictions. In this work, we follow the same strategy to study the case of acetaldehyde (CH3CHO). Method: To this end, we used the data obtained with the IRAM-NOEMA interferometer in the framework of the Large Program SOLIS to image the B0 and B1 shocks along the L1157 blueshifted outflow in methanol (CH3OH) and acetaldehyde line emission. Results: We imaged six CH3OH and eight CH3CHO lines which cover upper level energies up to 30 K. Both species trace the B0 molecular cavity as well as the northern B1 portion, i.e. the regions where the youngest shocks (1000 yr) occurred. The CH$_3$OH and CH$_3$CHO emission peaks towards the B1b clump, where we measured the following column densities and relative abundances: 1.3 x 10^16 cm-2 and 6.5 x 10-6 (methanol), and 7 x 10^13 cm-2 and 3.5 x 10-8 (acetaldehyde). We carried out a non-LTE LVG analysis of the observed CH3OH line: the average kinetic temperature and density of the emitting gas are Tkin = 90 K and nH2 = 4 x 10^5 cm-3, respectively. The CH3OH and CH3CHO abundance ratio towards B1b is 190, varying by less than a factor 3 throughout the whole B0-B1 structure. Conclusions: The comparison of astrochemical model predictions with the observed methanol and acetaldehyde spatial distribution does not allow to distinguish whether acetaldehyde is formed on the grain mantles or rather on the gas-phase, as its gas-phase formation, dominated by the reaction of ethyl radical (CH3CH2) with atomic oxygen, is very fast. Observations of acetaldehyde in younger shocks, e.g. 10^2 yr old, or/and of the ethyl radical, whose frequencies are not presently available, are necessary to settle the issue.

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arXiv2019

Molecules in the CepE-mm jet: evidence for shock-driven photochemistry?

The chemical composition of protostellar jets and its origin are still badly understood. More observational constraints are needed to make progress. With that objective, we have carried out a systematic search for molecular species in the jet of Cep E-mm, a template for intermediate-mass Class 0 protostars, associated with a luminous, high-velocity outflow. We made use of an unbiased spectral line survey in the range 72-350 GHz obtained with the IRAM 30m telescope, complementary observations of the CO $J$=3-2 transition with the JCMT, and observations at 1" angular resolution of the CO $J$=2-1 transition with the IRAM Plateau de Bure interferometer. In addition to CO, we have detected rotational transitions from SiO, SO, H$_2$CO, CS, HCO$^{+}$ and HCN. A strong chemical differentiation is observed in the southern and northern lobes of the jet. Radiative transfer analysis in the Large Velocity Gradient approximation yields typical molecular abundances of the order of $10^{-8}$ for all molecular species other than CO. Overall, the jets exhibit an unusual chemical composition, as CS, SO and H$_2$CO are found to be the most abundant species, with a typical abundance of (3-4)$\times 10^{-8}$. The transverse size of the CO jet emission estimated from interferometric observations is about 1000 au, suggesting that we are detecting emission from a turbulent layer of gas entrained by the jet in its propagation and not the jet itself. We propose that some molecular species could be the signatures of the specific photochemistry driven by the UV radiation field generated in the turbulent envelope.

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arXiv2018

The census of interstellar complex organic molecules in the Class I hot corino of SVS13-A

We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an high-sensitivity unbiased spectral survey at the 1mm, 2mm and 3mm IRAM bands. We detected five iCOMs: acetaldehyde (CH$_3$CHO), methyl formate (HCOOCH$_3$), dimethyl ether (CH$_3$OCH$_3$), ethanol (CH$_3$CH$_2$OH) and formamide (NH$_2$CHO). In addition we searched for other iCOMs and ketene (H$_2$CCO), formic acid (HCOOH) and methoxy (CH$_3$O), whose only ketene was detected. The numerous detected lines, from 5 to 37 depending on the species, cover a large upper level energy range, between 15 and 254 K. This allowed us to carry out a rotational diagram analysis and derive rotational temperatures between 35 and 110 K, and column densities between $3\times 10^{15}$ and $1\times 10^{17}$ cm$^{-2}$ on the 0."3 size previously determined by interferometric observations of glycolaldehyde. These new observations clearly demonstrate the presence of a rich chemistry in the hot corino towards SVS13-A. The measured iCOMs abundances were compared to other Class 0 and I hot corinos, as well as comets, previously published in the literature. We find evidence that (i) SVS13-A is as chemically rich as younger Class 0 protostars, and (ii) the iCOMs relative abundances do not substantially evolve during the protostellar phase.

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arXiv2018

First Hot Corino detected around an Isolated Intermediate-Mass Protostar: Cep\,E-mm

Intermediate-mass (IM) protostars provide a bridge between the low- and high-mass protostars. Despite their relevance, little is known about their chemical diversity. We want to investigate the molecular richness towards the envelope of IM protostars and to compare their properties with other sources. We have selected the isolated IM Class 0 protostar CepE-mm to carry out an unbiased molecular survey with the IRAM 30m telescope between 72 and 350 GHz with an angular resolution lying in the range 7-34". These data were complemented with NOEMA observations of the spectral bands 85.9 - 89.6 GHz and 216.8 - 220.4 GHz at an angular resolution of 2.3 and 1.4", respectively. 30m spectra show bright emission of O- and N-bearing COMs. We identify three components in the spectral signature: an extremely broad line component associated with the outflowing gas, a narrow line component associated with the cold envelope, and a broad line component tracing the hot corino. NOEMA observations reveal CepE-mm as a binary protostellar system CepE-A and B, separated by 1.7". CepE-A dominates the core continuum emission and powers the high-velocity jet associated with HH377. Our interferometric maps show that COMs arises from a region of 0.7" size around CepE-A. Rotational temperatures were found to lie in the range 20-40 K with column densities ranging from a few 10^15 cm-2 for O-bearing species, down to a few 10^14 cm-2 for N-bearing species. Molecular abundances are similar to those measured towards other low- and intermediate-mass protostars. High-mass hot cores are significantly less abundant in methanol and N-bearing species are more abundant by 3 orders of magnitude.CepE-mm reveals itself as a binary protostellar system with a strong chemical differentiation. The brightest component of the binary is associated with a hot corino. Its properties are similar to those of low-mass hot corinos.

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arXiv2018

SOLIS IV. Hydrocarbons in the OMC-2 FIR 4 region, a probe of energetic particle irradiation of the region

We report new interferometric images of cyclopropenylidene, c-C$_3$H$_2$, towards the young protocluster OMC-2 FIR\,4. The observations were performed at 82 and 85 GHz with the NOrthern Extended Millimeter Array (NOEMA) as part of the project Seeds Of Life In Space (SOLIS). In addition, IRAM-30m data observations were used to investigate the physical structure of OMC-2 FIR\,4. We find that the c-C$_3$H$_2$ gas emits from the same region where previous SOLIS observations showed bright HC$_5$N emission. From a non-LTE analysis of the IRAM-30m data, the c-C$_3$H$_2$ gas has an average temperature of $\sim$40K, a H$_2$ density of $\sim$3$\times$10$^{5}$~cm$^{-3}$, and a c-C$_3$H$_2$ abundance relative to H$_2$ of ($7\pm1$)$\times$10$^{-12}$. In addition, the NOEMA observations provide no sign of significant c-C$_3$H$_2$ excitation temperature gradients across the region (about 3-4 beams), with T$_{ex}$ in the range 8$\pm$3 up to 16$\pm$7K. We thus infer that our observations are inconsistent with a physical interaction of the OMC-2 FIR\,4 envelope with the outflow arising from OMC-2 FIR\,3, as claimed by previous studies. The comparison of the measured c-C$_3$H$_2$ abundance with the predictions from an astrochemical PDR model indicates that OMC-2 FIR\,4 is irradiated by a FUV field $\sim$1000 times larger than the interstellar one, and by a flux of ionising particles $\sim$4000 times larger than the canonical value of $1\times10^{-17}$~s$^{-1}$ from the Galaxy cosmic rays, which is consistent with our previous HC$_5$N observations. This provides an important and independent confirmation of other studies that one or more sources inside the OMC-2 FIR\,4 region emit energetic ($\geq10$~MeV) particles.

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arXiv2018

Astrochemical evolution along star formation: Overview of the IRAM Large Program ASAI

Evidence is mounting that the small bodies of our Solar System, such as comets and asteroids, have at least partially inherited their chemical composition from the first phases of the Solar System formation. It then appears that the molecular complexity of these small bodies is most likely related to the earliest stages of star formation. It is therefore important to characterize and to understand how the chemical evolution changes with solar-type protostellar evolution. We present here the Large Program "Astrochemical Surveys At IRAM" (ASAI). Its goal is to carry out unbiased millimeter line surveys between 80 and 272 GHz of a sample of ten template sources, which fully cover the first stages of the formation process of solar-type stars, from prestellar cores to the late protostellar phase. In this article, we present an overview of the surveys and results obtained from the analysis of the 3 mm band observations. The number of detected main isotopic species barely varies with the evolutionary stage and is found to be very similar to that of massive star-forming regions. The molecular content in O- and C- bearing species allows us to define two chemical classes of envelopes, whose composition is dominated by either a) a rich content in O-rich complex organic molecules, associated with hot corino sources, or b) a rich content in hydrocarbons, typical of Warm Carbon Chain Chemistry sources. Overall, a high chemical richness is found to be present already in the initial phases of solar-type star formation.

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arXiv2018

Deuterium and $^{15}$N fractionation in N$_2$H$^+$ during the formation of a Sun-like star

Although chemical models predict that the deuterium fractionation in N$_2$H$^+$ is a good evolutionary tracer in the star formation process, the fractionation of nitrogen is still a poorly understood process. Recent models have questioned the similar evolutionary trend expected for the two fractionation mechanisms in N$_2$H$^+$, based on a classical scenario in which ion-neutral reactions occurring in cold gas should have caused an enhancement of the abundance of N$_2$D$^+$, $^{15}$NNH$^+$, and N$^{15}$NH$^+$. In the framework of the ASAI IRAM-30m large program, we have investigated the fractionation of deuterium and $^{15}$N in N$_2$H$^+$ in the best known representatives of the different evolutionary stages of the Sun-like star formation process. The goal is to ultimately confirm (or deny) the classical "ion-neutral reactions" scenario that predicts a similar trend for D and $^{15}$N fractionation. We do not find any evolutionary trend of the $^{14}$N/$^{15}$N ratio from both the $^{15}$NNH$^+$ and N$^{15}$NH$^+$ isotopologues. Therefore, our findings confirm that, during the formation of a Sun-like star, the core evolution is irrelevant in the fractionation of $^{15}$N. The independence of the $^{14}$N/$^{15}$N ratio with time, found also in high-mass star-forming cores, indicates that the enrichment in $^{15}$N revealed in comets and protoplanetary disks is unlikely to happen at core scales. Nevertheless, we have firmly confirmed the evolutionary trend expected for the H/D ratio, with the N$_2$H$^+$/N$_2$D$^+$ ratio decreasing before the pre-stellar core phase, and increasing monotonically during the protostellar phase. We have also confirmed clearly that the two fractionation mechanisms are not related.

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arXiv2017

Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation

Context: Modern versions of the Miller-Urey experiment claim that formamide (NH$_2$CHO) could be the starting point for the formation of metabolic and genetic macromolecules. Intriguingly, formamide is indeed observed in regions forming Solar-type stars as well as in external galaxies. Aims: How NH$_2$CHO is formed has been a puzzle for decades: our goal is to contribute to the hotly debated question of whether formamide is mostly formed via gas-phase or grain surface chemistry. Methods: We used the NOEMA interferometer to image NH$_2$CHO towards the L1157-B1 blue-shifted shock, a well known interstellar laboratory, to study how the components of dust mantles and cores released into the gas phase triggers the formation of formamide. Results: We report the first spatially resolved image (size $\sim$ 9", $\sim$ 2300 AU) of formamide emission in a shocked region around a Sun-like protostar: the line profiles are blueshifted and have a FWHM $\simeq$ 5 km s$^{-1}$. A column density of $N_{\rm NH_2CHO}$ = 8 $\times$ 10$^{12}$ cm$^{-1}$, and an abundance (with respect to H-nuclei) of 4 $\times$ 10$^{-9}$ are derived. We show a spatial segregation of formamide with respect to other organic species. Our observations, coupled with a chemical modelling analysis, indicate that the formamide observed in L1157-B1 is formed by gas-phase chemical process, and not on grain surfaces as previously suggested. Conclusions: The SOLIS interferometric observations of formamide provide direct evidence that this potentially crucial brick of life is efficiently formed in the gas-phase around Sun-like protostars.

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arXiv2017

Complex organics in IRAS 4A revisited with ALMA and PdBI: Striking contrast between two neighbouring protostellar cores

We used the Atacama Large (sub-)Millimeter Array (ALMA) and the IRAM Plateau de Bure Interferometer (PdBI) to image, with an angular resolution of 0.5$''$ (120 au) and 1$''$ (235 au), respectively, the emission from 11 different organic molecules in the protostellar binary NGC1333 IRAS 4A. We clearly disentangled A1 and A2, the two protostellar cores present. For the first time, we were able to derive the column densities and fractional abundances simultaneously for the two objects, allowing us to analyse the chemical differences between them. Molecular emission from organic molecules is concentrated exclusively in A2 even though A1 is the strongest continuum emitter. The protostellar core A2 displays typical hot corino abundances and its deconvolved size is 70 au. In contrast, the upper limits we placed on molecular abundances for A1 are extremely low, lying about one order of magnitude below prestellar values. The difference in the amount of organic molecules present in A1 and A2 ranges between one and two orders of magnitude. Our results suggest that the optical depth of dust emission at these wavelengths is unlikely to be sufficiently high to completely hide a hot corino in A1 similar in size to that in A2. Thus, the significant contrast in molecular richness found between the two sources is most probably real. We estimate that the size of a hypothetical hot corino in A1 should be less than 12 au. Our results favour a scenario in which the protostar in A2 is either more massive and/or subject to a higher accretion rate than A1, as a result of inhomogeneous fragmentation of the parental molecular clump. This naturally explains the smaller current envelope mass in A2 with respect to A1 along with its molecular richness.

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arXiv2015

Shedding light on the formation of the pre-biotic molecule formamide with ASAI

Formamide (NH2CHO) has been proposed as a pre-biotic precursor with a key role in the emergence of life on Earth. While this molecule has been observed in space, most of its detections correspond to high-mass star-forming regions. Motivated by this lack of investigation in the low-mass regime, we searched for formamide, as well as isocyanic acid (HNCO), in 10 low- and intermediate-mass pre-stellar and protostellar objects. The present work is part of the IRAM Large Programme ASAI (Astrochemical Surveys At IRAM), which makes use of unbiased broadband spectral surveys at millimetre wavelengths. We detected HNCO in all the sources and NH2CHO in five of them. We derived their abundances and analysed them together with those reported in the literature for high-mass sources. For those sources with formamide detection, we found a tight and almost linear correlation between HNCO and NH2CHO abundances, with their ratio being roughly constant -between 3 and 10- across 6 orders of magnitude in luminosity. This suggests the two species are chemically related. The sources without formamide detection, which are also the coldest and devoid of hot corinos, fall well off the correlation, displaying a much larger amount of HNCO relative to NH2CHO. Our results suggest that, while HNCO can be formed in the gas phase during the cold stages of star formation, NH2CHO forms most efficiently on the mantles of dust grains at these temperatures, where it remains frozen until the temperature rises enough to sublimate the icy grain mantles. We propose hydrogenation of HNCO as a likely formation route leading to NH2CHO.

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arXiv2014

Complex organic molecules in protostellar environments in the SKA era

Molecular complexity builds up at each step of the Sun-like star formation process, starting from simple molecules and ending up in large polyatomic species. Complex organic molecules (COMs; such as methyl formate, HCOOCH$_3$, dymethyl ether, CH$_3$OCH$_3$, formamide, NH$_2$CHO, or glycoaldehyde, HCOCH$_2$OH) are formed in all the components of the star formation recipe (e.g. pre-stellar cores, hot-corinos, circumstellar disks, shocks induced by fast jets), due to ice grain mantle sublimation or sputtering as well as gas-phase reactions. Understanding in great detail the involved processes is likely the only way to predict the ultimate molecular complexity reached in the ISM, as the detection of large molecules is increasingly more difficult with the increase of the number of atoms constituting them. Thanks to the recent spectacular progress of astronomical observations, due to the Herschel (sub-mm and IR), IRAM and SMA (mm and sub-mm), and NRAO (cm) telescopes, an enormous activity is being developed in the field of Astrochemistry, extending from astronomical observatories to chemical laboratories. We are involved in several observational projects providing unbiased spectral surveys (in the 80-300 and 500-2000 GHz ranges) with unprecedented sensitivity of templates of dense cores and protostars. Forests of COM lines have been detected. In this chapter we will focus on the chemistry of both cold prestellar cores and hot shocked regions, (i) reviewing results and open questions provided by mm-FIR observations, and (ii) showing the need of carrying on the observations of COMs at lower frequencies, where SKA will operate. We will also emphasize the importance of analysing the spectra by the light of the experimental studies performed by our team, who is investigating the chemical effects induced by ionising radiation bombarding astrophysically relevant ices.

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